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[ CAS No. 18908-66-2 ] {[proInfo.proName]}

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Chemical Structure| 18908-66-2
Chemical Structure| 18908-66-2
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Mathias A. Perone ; Rusty L. Blanski ; Kellsie G. Knoerzer , et al. DOI:

Abstract: During the investigation of room temperature (RTILs) produced from tri(2-ethylhexyl)phosphine, it was discovered that the common core tri(n-octyl)phosphine was also significantly underreported. This void in the literature prompted an investigation to explore the influence of branched versus linear substituents’ influence on physical properties. To facilitate a thorough structure-property relationship study, 28 were prepared from tri(n-octyl)phosphine to compare against their branched counterparts. Thermal behavior was investigated by utilizing visual melting point determination, differential scanning calorimetry (DSC), and thermogravimetric analysis (TGA), with emphasis placed on the examination of physical states, phase transitions (including solid-solid), and degradation. Remarkably, all materials produced here are (mp < 100°C), with 16 of the 28 being liquids at room temperature. Standard analytical methods were utilized to assess the physical properties of the compounds, namely density, viscosity, surface tension, and solubility/miscibility. Structure-property relationships were assessed, particularly focusing on the differences in physical properties between the tri(n-octyl)phosphine and tri(2-ethylhexyl)phosphine cores.

Keywords: Room temperature ; phosphonium cation ; structure-property relationship ; thermal analysis ; physical properties ; branching

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Cena, Nicolas ; Blanski, Rusty L. ; Quintana, Ashlee S. , et al. DOI:

Abstract: First reported in 1966-1967, the compound tri(2-ethylhexyl)phosphine appears to be a hidden gem for ionic liquids Although this compound offers many potential intriguing properties that are inherent due to its branching and diastereomeric nature, there is only a single report employing this material as an ionic liquid constituent. Through quaternization and anion exchange, a total of 24 new room temperature ionic liquids were prepared containing bromide (Br-), bis(trifluoromethanesulfonyl)imide (Tf2N-), hexafluorophosphate (PF-6), and tetrafluoroborate (BF-4) anions. In addition to the usual anal. methods, the compounds phys. properties such as d., solubility, viscosity, and surface tension were probed to ascertain their suitability for aerospace applications. Differential scanning calorimetry (DSC) and thermogravimetric anal. (TGA) were employed to study the thermal behavior of the materials focusing on phase transitions and degradation behavior. Remarkably, all ionic liquids prepared in this study are liquids at room temperature with relatively low viscosities and are soluble in many common organic solvents. Structure-property relationships were assessed, particularly focusing on the effect that the chain length appendage and/or anion type has on a given phys. property. An updated synthetic procedure and characterization of the tri(2-ethylhexyl)phosphine starting material are provided. A new synthesis procedure for the starting material silver(I) tetrafluoroborate is also reported.

Keywords: Room temperature ionic liquid ; Phosphonium cation ; DSC ; TGA ; Diastereomer mixture ; Branched alkane

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Product Details of [ 18908-66-2 ]

CAS No. :18908-66-2 MDL No. :MFCD00000220
Formula : C8H17Br Boiling Point : -
Linear Structure Formula :CH3(CH2)4CH(CH2CH3)Br InChI Key :NZWIYPLSXWYKLH-UHFFFAOYSA-N
M.W : 193.12 Pubchem ID :86804
Synonyms :

Safety of [ 18908-66-2 ]

Signal Word:Warning Class:
Precautionary Statements:P501-P210-P264-P280-P302+P352-P370+P378-P337+P313-P305+P351+P338-P362+P364-P332+P313-P403+P235 UN#:
Hazard Statements:H315-H319-H227 Packing Group:
GHS Pictogram:

Application In Synthesis of [ 18908-66-2 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 18908-66-2 ]

[ 18908-66-2 ] Synthesis Path-Downstream   1~4

  • 1
  • [ 18908-66-2 ]
  • [ 2785-78-6 ]
  • [ 1333889-82-9 ]
  • 2
  • [ 18908-66-2 ]
  • [ 1000623-95-9 ]
  • 3
  • 3,6-dithiophen-2-yl-2,5-dihydropyrrolo[3,4-c]pyrrole-1,4-dione [ No CAS ]
  • [ 18908-66-2 ]
  • [ 1000623-95-9 ]
  • 4
  • [ 18908-66-2 ]
  • [ 56309-94-5 ]
  • C22H40O3 [ No CAS ]
YieldReaction ConditionsOperation in experiment
20% Slowly added magnesium (shaving) (3.67g) andTHF (50 ml) was put into a solution of 1-bromo-2-hexene (29.1 g) in THF (50 ml) into the reactor and stirred at 30 ° C for 1 hour.A solution of the compound (T-83) (30.0 g) in THF (100 ml) was slowly added dropwise thereto, and the mixture was stirred at room temperature for 6 hours.The reaction mixture was poured into water and the aqueous layer was extracted with ethyl acetate. ToThe organic layer formed while washing with water was dried over anhydrous magnesium sulfate. The solution was concentrated under reduced pressure and chromatographed on silica gelThe residue was purified by a method (volume ratio, toluene: ethyl acetate = 4: 1) to obtain Compound (T-84) (8.88 g; 20percent).
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