[ CAS No. 1774-35-2 ] {[proInfo.proName]}

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2D 3D

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Quality Control of [ 1774-35-2 ]

COA NMR CNMR HPLC LC-MS

Related Doc. of [ 1774-35-2 ]

SDS Specification

Alternatived Products of [ 1774-35-2 ]

Product Details of [ 1774-35-2 ]

CAS No. :	1774-35-2	MDL No. :	MFCD00008546
Formula :	C₁₄H₁₄OS	Boiling Point :	-
Linear Structure Formula :	-	InChI Key :	MJWNJEJCQHNDNM-UHFFFAOYSA-N
M.W :	230.33	Pubchem ID :	15680
Synonyms :

Safety of [ 1774-35-2 ]

Signal Word:	Warning	Class:	N/A
Precautionary Statements:	P261-P305+P351+P338	UN#:	N/A
Hazard Statements:	H302-H315-H319-H335	Packing Group:	N/A
GHS Pictogram:

Application In Synthesis of [ 1774-35-2 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Downstream synthetic route of [ 1774-35-2 ]

[ 1774-35-2 ] Synthesis Path-Downstream 1~6

1
[ 1774-35-2 ]
[ 599-66-6 ]

Reference： [1]Russian Journal of Organic Chemistry,1995,vol. 31,p. 1520 - 1525
Zhurnal Organicheskoi Khimii,1995,vol. 31,p. 1692 - 1697
[2]Journal of Organic Chemistry,1983,vol. 48,p. 3585 - 3587
[3]Journal of Organic Chemistry,2007,vol. 72,p. 5847 - 5850
[4]Canadian Journal of Chemistry,1984,vol. 62,p. 1164 - 1168
[5]Journal of the American Chemical Society,1946,vol. 68,p. 973,974, 976, 2671
Journal of the American Chemical Society,1947,vol. 69,p. 644,2310
[6]Magnetic Resonance in Chemistry,1989,vol. 27,p. 360 - 367
[7]Journal of the Chemical Society. Chemical communications,1982,p. 1352 - 1353
[8]Journal of the American Chemical Society,1981,vol. 103,p. 3832 - 3837
[9]Canadian Journal of Chemistry,1987,vol. 65,p. 2421 - 2424
[10]Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical,1981,vol. 20,p. 505 - 506
[11]Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical,1986,vol. 25,p. 678 - 680
[12]Journal of the Indian Chemical Society,1992,vol. 69,p. 819 - 821
[13]Journal of Organic Chemistry,1993,vol. 58,p. 5055 - 5059
[14]Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical,1989,vol. 28,p. 250 - 252
[15]Tetrahedron,2001,vol. 57,p. 1369 - 1374
[16]Journal of Chemical Research, Miniprint,2000,p. 1118 - 1133
[17]Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical,2005,vol. 44,p. 71 - 75
[18]Journal of the Indian Chemical Society,2007,vol. 84,p. 679 - 682

2
[ 620-94-0 ]
[ 599-66-6 ]
[ 1774-35-2 ]

Reference： [1]Bulletin of the Chemical Society of Japan,1999,vol. 72,p. 2351 - 2356
[2]Bulletin of the Chemical Society of Japan,1999,vol. 72,p. 2351 - 2356
[3]Journal of Organic Chemistry,2000,vol. 65,p. 8391 - 8394
[4]Synthetic Communications,1986,vol. 16,p. 1206 - 1216

3
[ 1774-35-2 ]
[ 620-94-0 ]
[ 599-66-6 ]

Yield	Reaction Conditions	Operation in experiment
83%; 12%	With [ReOCl3(PPh3)2]; In chloroform; for 17h;Reflux;	General procedure: To a solution of ReOCl3(PPh3)2 (10.0 mol %) in CHCl3 (3 mL) was added the sulfoxide (1.0 mmol). The reaction mixture was heated at reflux temperature under air atmosphere (the reaction times are indicated in the Table 1, Table 2 and Table 3) and the progress of the reaction was monitored by TLC or 1H NMR. Upon completion, the reaction mixture was evaporated and purified by silica gel column chromatography with n-hexane to afford sulfides and sulfones, which are all known compounds.

Reference： [1]Tetrahedron,2012,vol. 68,p. 8194 - 8197
[2]Tetrahedron Letters,1987,vol. 28,p. 6201 - 6204
[3]Green Chemistry,2013,vol. 15,p. 999 - 1005

4
[ 455-16-3 ]
[ 108-88-3 ]
[ 599-66-6 ]
[ 1774-35-2 ]

Reference： [1]Journal of Organic Chemistry,1991,vol. 56,p. 1867 - 1874

5
[ 1774-35-2 ]
KMnO₄ [ No CAS ]
[ 599-66-6 ]

Reference： [1]Chemische Berichte,1890,vol. 23,p. 1845

6
[ 108-88-3 ]
[ 599-66-6 ]
[ 10381-68-7 ]
[ 1774-35-2 ]

Yield	Reaction Conditions	Operation in experiment
16%Chromat.; 26%Chromat.; 50%Chromat.	With aluminum (III) chloride; thionyl chloride; at 25℃;	General procedure: The reactions were conducted in the fume hood at 25 Cand 70 C, respectively, with the molar ratio of PhX:SOCl2:AlCl3 being 2:1:1 and usage of SOCl2 approximately 10 mmol. For eachreaction, granular AlCl3 was added piecewise to the PhX-SOCl2 mixture (X=CH3 or Cl) in a large test tube (~ 80 mL) as follows: First, one piece of AlCl3 was added and gas (HCl) bubbles started to form immediately. The piece of AlCl3 was crushed using a stirring rod. When most of the piece of AlCl3 had dissolved and bubbling occurredvery slowly, another piece of AlCl3 was added. All the AlCl3 granules were eventually added into the PhX-SOCl2 mixture piece-by-piece. The solution was initially light green and it turned dark green as the reaction went to completion, indicated by ceasing of bubbling after all the AlCl3 had been added. Then iced water (40 mL) was poured into thereaction mixture and the green colour disappeared. This was followed by addition of diethyl ether (20 mL). All the contents were transferredinto a separating funnel and shaken well to assure the organic productbeing fully extracted into the ether phase. The ether and water phaseswere separated. The water phase was extracted by diethyl ether (20 mL) again. Then all the ether solutions were combined and dried by anhydrous sodium sulfate. The dried ether solution was filtered off and left in the fume hood. Eventually, all the diethyl ether solvent evaporated, giving the final reaction product. The product was thencharacterised by GC-MS, and the results are shown in Table 1.

Reference： [1]Journal of Chemical Research,2013,vol. 37,p. 736 - 744

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Technical Information

? Benzylic Oxidation ? Birch Reduction ? Blanc Chloromethylation ? Friedel-Crafts Reaction ? Hydrogenolysis of Benzyl Ether ? Nucleophilicity of Sulfur Compounds ? Oxidation States of Sulfur Compounds ? Preparation of Alkylbenzene ? Preparation of Phosphorus and Sulfur Ylides ? Reactions of Benzene and Substituted Benzenes ? Vilsmeier-Haack Reaction

Historical Records

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[ 1774-35-2 ]

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P304 + P340	IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
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P305 + P351 + P338	IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P306 + P360	IF ON CLOTHING: Rinse Immediately contaminated CLOTHING and SKIN with plenty of water before removing clothes.
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[ CAS No. 1774-35-2 ] {[proInfo.proName]}

Quality Control of [ 1774-35-2 ]

Related Doc. of [ 1774-35-2 ]

Product Details of [ 1774-35-2 ]

Safety of [ 1774-35-2 ]

Application In Synthesis of [ 1774-35-2 ]

[ 1774-35-2 ] Synthesis Path-Downstream 1~6

Technical Information

Related Functional Groups of [ 1774-35-2 ]

Aryls

Sulfoxides

Precautionary Statements-General

Prevention

Response

Storage

Disposal

Physical hazards

Health hazards

Environmental hazards

Inquiry

Related Functional Groups of
[ 1774-35-2 ]