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CAS No. : | 1633-41-6 | MDL No. : | MFCD00971952 |
Formula : | C6H7N3O2 | Boiling Point : | - |
Linear Structure Formula : | - | InChI Key : | - |
M.W : | 153.14 | Pubchem ID : | - |
Synonyms : |
|
Signal Word: | Warning | Class: | N/A |
Precautionary Statements: | P261-P305+P351+P338 | UN#: | N/A |
Hazard Statements: | H302-H315-H319-H335 | Packing Group: | N/A |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
7.17 g (88%) | With methylamine; In ethanol; | EXAMPLE 1 endo-4-(1-Aza-bicyclo[2.2.1]hept-3-yloxy)-1-methyl-1H-imidazo[4,5-c]pyridine <strong>[31872-62-5]4-Methoxy-3-nitropyridine</strong> (8.17 g, 53.0 mmol) was transferred to a bomb in EtOH (5-10 mL). To this was added a solution of methylamine in EtOH (26.4 mL, 8.03M, 0.212 mol). The bomb was sealed and lowered into an oil bath at 120° C. The bath temperature fell to 90° C. and remained that way for 2 hours. The temperature was raised to 140° C. over 0.5 hour and held there 0.5 hour. The contents were transferred to a flask with EtOH (not very soluble) and the solvent was evaporated. Flash chromatography on silica gel with a gradient of CH2 Cl2 /CH3 OH gave 7.17 g (88percent) of 4-methylamino-3-nitropyridine as a yellow solid: nap 155°-158° C. |
7.17 g (88%) | With methylamine; In ethanol; | EXAMPLE 1 endo-4-(1-Aza-bicyclo[2.2.1]hept-3-yloxy)-1-methyl-1H-imidazol[4,5-c]pyridine <strong>[31872-62-5]4-Methoxy-3-nitropyridine</strong> (8.17 g, 53.0 mmol) was transferred to a bomb in EtOH (5-10 mL). To this was added a solution of methylamine in EtOH (26.4 mL, 8.03M, 0.212 mol). The bomb was sealed and lowered into an oil bath at 120° C. The bath temperature fell to 90° C. and remained that way for 2 hours. The temperature was raised to 140° C. over 0.5 hour and held there 0.5 hour. The contents were transferred to a flask with EtOH (not very soluble) and the solvent was evaporated. Flash chromatography on silica gel with a gradient of CH2 Cl2 /CH3 OH gave 7.17 g (88percent) of 4-methylamino-3-nitropyridine as a yellow solid: mp 155°-158° C. |
With methylamine; In ethanol; water; for 3h;Reflux; | Example 210 55.1 methyl-(3-nitropyridin-4-yl)-amine 2.36 g <strong>[31872-62-5]4-methoxy-3-nitro-pyridine</strong> and 2.33 ml methylamine (40percent in water) are refluxed in 25 ml of ethanol for 3 h. Then the reaction mixture is evaporated to dryness. 2.3 g product are obtained as a solid. |
With methylamine; In ethanol; water; | 30.1methyl-(3-nitropyridin-4-yl)-amine2.36 g <strong>[31872-62-5]4-methoxy-3-nitro-pyridine</strong> and 2.33 ml methylamine (40percent in water) are refluxed in 25 ml of ethanol for 3 h.Then the reaction mixture is evaporated to dryness.2.3 g product are obtained in the form of a solid. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
2.3 g | In ethanol; water; for 3h;Reflux; | 30.1 methyl-(3-nitropyridin-4-yl)-amine 2.36 g <strong>[31872-62-5]4-methoxy-3-nitro-pyridine</strong> and 2.33 ml methylamine (40percent in water) are refluxed in 25 ml of ethanol for 3 h. Then the reaction mixture is evaporated to dryness. 2.3 g product are obtained as a solid. |
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