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CAS No. : | 158984-83-9 | MDL No. : | MFCD08275034 |
Formula : | C14H19NO3 | Boiling Point : | No data available |
Linear Structure Formula : | - | InChI Key : | IVHHZZKGSYGTKZ-UHFFFAOYSA-N |
M.W : | 249.31 | Pubchem ID : | 10060623 |
Synonyms : |
|
Signal Word: | Warning | Class: | |
Precautionary Statements: | P261-P305+P351+P338 | UN#: | |
Hazard Statements: | H302-H315-H319-H335 | Packing Group: | |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With di-isopropyl azodicarboxylate; triphenylphosphine; In tetrahydrofuran; at 0 - 20℃; | A solution of diisopropyl azodicarboxylate (0.503 mL, 2.59 mmol) in THF (11.800 mL) was added dropwise to a cooled (0 C) solution of tert-butyl 6-hydroxy-3,4- dihydroisoquinoline-2(lH)-carboxylate (586 mg, 2.351 mmol), triphenylphosphine (678 mg, 2.59 mmol) and (2-methyl-[l, -biphenyl]-3-yl)methanol (513 mg, 2.59 mmol) in dry THF (11.800 mL). The resulting yellow solution was allowed to slowly warm to room temperature and stirred overnight. Excess solvent was removed and the residue purified via chromatography with 0-35% ethyl acetate in hexane on a silica gel column. 1H NMR (400MHz, CHLOROFORM-d) delta 7.48-7.42 (m, 3H), 7.41-7.33 (m, 3H), 7.30-7.26 (m, 2H), 7.07 (d, J=8.3 Hz, IH), 6.90 (dd, J=8.3, 2.7 Hz, IH), 6.83 (d, J=2.4 Hz, IH), 5.09 (s, 2H), 4.55 (s, 2H), 3.66 (t, J=5.6 Hz, 2H), 2.85 (t, J=5.7 Hz, 2H), 2.69 (br. s., 2H), 2.27 (s, 3H), 1.52 (s, 9H). |
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