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CAS No. : | 1541-10-2 | MDL No. : | MFCD00218475 |
Formula : | C9H12S | Boiling Point : | - |
Linear Structure Formula : | - | InChI Key : | PKANQZUPJCMBAK-UHFFFAOYSA-N |
M.W : | 152.26 | Pubchem ID : | 284449 |
Synonyms : |
|
Signal Word: | Danger | Class: | 9 |
Precautionary Statements: | P261-P305+P351+P338-P342+P311-P273 | UN#: | 3334 |
Hazard Statements: | H319-H334-H410 | Packing Group: | Ⅲ |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
68.1% | With potassium fluoride; In acetonitrile; at 5 - 20℃; for 3h; | General procedure: In the synthesis of Example 1 (1) The compound (4-1), except that a beta-naphthol(compound (a-1)), a 2,4,6-trimethyl-thiophenol (Compound (a-2)) It is to obtain a compound (4-2) in the same manner (yield: 68.1percent). |
3.7 g | With potassium fluoride; In acetonitrile; at 20 - 25℃; for 2h; | Thetetrafluoro Phthalo nitrile (compound (5)) 3.0 g (15mmol), and the potassiumfluoride 15 g (1.2eq.) and acetonitrile 20ml were put in the reactor in whichthe entrance of 100ml placing the thermometer was 4 and it was stirred and itcooled to 5. Here, 2, 4, 6- trimethyl thiophenol (compound(a-11): purity 77percent) 3.0 g (1.0eq.) was unloaded. The temperature of the mixturewas increased to 20 and it reacted at 20 through25 after the load finish. Thereaction mixture was emitted to water after the completion of reaction and thesegregatedsolid was filtered and it took out. The obtained crude product was well wipedoff with the isopropanol and it dried and the compound (4-1) 3.7g which was thewhite solid was obtained (yield 74percent). |