成人免费xx,国产又黄又湿又刺激不卡网站,成人性视频app菠萝网站,色天天天天

Home Cart 0 Sign in  

[ CAS No. 140472-69-1 ] {[proInfo.proName]}

,{[proInfo.pro_purity]}
Cat. No.: {[proInfo.prAm]}
HazMat Fee +

There will be a HazMat fee per item when shipping a dangerous goods. The HazMat fee will be charged to your UPS/DHL/FedEx collect account or added to the invoice unless the package is shipped via Ground service. Ship by air in Excepted Quantity (each bottle), which is up to 1g/1mL for class 6.1 packing group I or II, and up to 25g/25ml for all other HazMat items.

Type HazMat fee for 500 gram (Estimated)
Excepted Quantity USD 0.00
Limited Quantity USD 15-60
Inaccessible (Haz class 6.1), Domestic USD 80+
Inaccessible (Haz class 6.1), International USD 150+
Accessible (Haz class 3, 4, 5 or 8), Domestic USD 100+
Accessible (Haz class 3, 4, 5 or 8), International USD 200+
Chemical Structure| 140472-69-1
Chemical Structure| 140472-69-1
Structure of 140472-69-1 * Storage: {[proInfo.prStorage]}

Please Login or Create an Account to: See VIP prices and availability

Cart0 Add to My Favorites Add to My Favorites Bulk Inquiry Inquiry Add To Cart

Search after Editing

* Storage: {[proInfo.prStorage]}

* Shipping: {[proInfo.prShipping]}

Quality Control of [ 140472-69-1 ]

Related Doc. of [ 140472-69-1 ]

Alternatived Products of [ 140472-69-1 ]
Product Citations

Product Details of [ 140472-69-1 ]

CAS No. :140472-69-1 MDL No. :MFCD06797980
Formula : C7H5BrO3 Boiling Point : -
Linear Structure Formula :- InChI Key :WGIBEMRBLBGETQ-UHFFFAOYSA-N
M.W : 217.02 Pubchem ID :15735511
Synonyms :

Safety of [ 140472-69-1 ]

Signal Word:Danger Class:6.1
Precautionary Statements:P273-P301+P310-P305+P351+P338 UN#:2811
Hazard Statements:H301-H410 Packing Group:Ⅲ
GHS Pictogram:

Application In Synthesis of [ 140472-69-1 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 140472-69-1 ]

[ 140472-69-1 ] Synthesis Path-Downstream   1~2

  • 1
  • [ 42237-85-4 ]
  • [ 140472-69-1 ]
YieldReaction ConditionsOperation in experiment
66% With sulfuric acid; water; sodium nitrite; for 1.75h;Reflux; The title compound of Preparation 50 (5.80 g, 26.85 mmols), in 10% sulphuric acid (55 ml), was diazotised with sodium nitrite (1.85 g), and the solution boiled with dilute sulphuric acid (1:1) ( 30ml) for one hour and forty-five minutes. The solution was cooled at room temperature. The suspension was filtered and the solid give 3.83 g (66%) of the title compound. HPLC/MS (10 min) retention time 5.06 min LRMS: m/z 215 (M-1)
66% With sulfuric acid; water; sodium nitrite; In water; for 1.75h;Reflux; PREPARATION 22 3-Bromo-5-hydroxybenzoic acid The title compound of Preparation 21 (5.80 g, 26.85 mmols), in 10% sulphuric acid (55 mL), was diazotised with sodium nitrite (1.85 g), and the solution boiled with dilute sulphuric acid (1:1) (30 mL) for one hour and forty-five minutes. The solution was cooled at room temperature. The suspension was filtered and the solid give 3.83 g (66%) of the title compound. HPLC/MS (10 min) retention time 5.06 min LRMS: m/z 215 (M-1)
  • 2
  • [ 49851-36-7 ]
  • [ 140472-69-1 ]
  • methyl 2-(2-(3-bromo-5-hydroxybenzamido)phenyl)acetate [ No CAS ]
YieldReaction ConditionsOperation in experiment
TEA (2.248 mL, 16.13 mmol) was added to a mixture of 3-bromo-5-hydroxybenzoic acid (CAS 140472-69-1 ) (1000 mg, 4.61 mmol), <strong>[49851-36-7]methyl 2-(2-aminophenyl)acetate hydrochloride</strong> (CAS 49851-36-7) (978 mg, 4.61 mmol) and HATU (1927 mg, 5.07 mmol) in DMF (10 mL) at 23 C. The resulting mixture was stirred at rt overnight. To the mixture was added K2C03 (191 1 mg, 13.82 mmol) and the mixture was heated to 100 C for 2 hours. The reaction mixture was diluted with EtOAc and washed with water. The organic layer was concentrated and the residue was purified by flash column on silica gel (EtOAc-heptane 0-100%) to give the title compound. MS (ESI+) m/z 364.1 , 366.1 (M+1 ).
Recommend Products
Same Skeleton Products

Technical Information

? Acidity of Phenols ? Alkyl Halide Occurrence ? Appel Reaction ? Arndt-Eistert Homologation ? Benzylic Oxidation ? Birch Reduction ? Blanc Chloromethylation ? Buchwald-Hartwig C-N Bond and C-O Bond Formation Reactions ? Chan-Lam Coupling Reaction ? Chugaev Reaction ? Corey-Kim Oxidation ? Dess-Martin Oxidation ? Electrophilic Substitution of the Phenol Aromatic Ring ? Etherification Reaction of Phenolic Hydroxyl Group ? Friedel-Crafts Reaction ? General Reactivity ? Grignard Reaction ? Halogenation of Phenols ? Hiyama Cross-Coupling Reaction ? Hunsdiecker-Borodin Reaction ? Hydride Reductions ? Hydrogenolysis of Benzyl Ether ? Jones Oxidation ? Kinetics of Alkyl Halides ? Kumada Cross-Coupling Reaction ? Martin's Sulfurane Dehydrating Reagent ? Mitsunobu Reaction ? Moffatt Oxidation ? Oxidation of Alcohols by DMSO ? Oxidation of Phenols ? Passerini Reaction ? Pechmann Coumarin Synthesis ? Preparation of Alcohols ? Preparation of Aldehydes and Ketones ? Preparation of Alkylbenzene ? Preparation of Amines ? Preparation of Carboxylic Acids ? Reactions of Alcohols ? Reactions of Alkyl Halides with Reducing Metals ? Reactions of Amines ? Reactions of Benzene and Substituted Benzenes ? Reactions of Carboxylic Acids ? Reactions of Dihalides ? Reactions with Organometallic Reagents ? Reimer-Tiemann Reaction ? Ritter Reaction ? Schmidt Reaction ? Sharpless Olefin Synthesis ? Specialized Acylation Reagents-Ketenes ? Stille Coupling ? Substitution and Elimination Reactions of Alkyl Halides ? Suzuki Coupling ? Swern Oxidation ? Ugi Reaction ? Vilsmeier-Haack Reaction
Historical Records

Related Functional Groups of
[ 140472-69-1 ]

Aryls

Chemical Structure| 1261951-96-5

[ 1261951-96-5 ]

3'-Bromo-5'-hydroxy-[1,1'-biphenyl]-3,5-dicarboxylic acid

Similarity: 0.93

Chemical Structure| 1261951-62-5

[ 1261951-62-5 ]

3'-Bromo-5'-hydroxy-[1,1'-biphenyl]-3-carboxylic acid

Similarity: 0.93

Chemical Structure| 1261991-91-6

[ 1261991-91-6 ]

3-Bromo-5-(4-carboxyphenyl)phenol

Similarity: 0.93

Chemical Structure| 157893-14-6

[ 157893-14-6 ]

3-Bromo-5-methoxybenzoic acid

Similarity: 0.90

Chemical Structure| 61203-46-1

[ 61203-46-1 ]

3-Bromo-4,5-dihydroxybenzoic acid

Similarity: 0.90

Bromides

Chemical Structure| 1261951-96-5

[ 1261951-96-5 ]

3'-Bromo-5'-hydroxy-[1,1'-biphenyl]-3,5-dicarboxylic acid

Similarity: 0.93

Chemical Structure| 1261951-62-5

[ 1261951-62-5 ]

3'-Bromo-5'-hydroxy-[1,1'-biphenyl]-3-carboxylic acid

Similarity: 0.93

Chemical Structure| 1261991-91-6

[ 1261991-91-6 ]

3-Bromo-5-(4-carboxyphenyl)phenol

Similarity: 0.93

Chemical Structure| 157893-14-6

[ 157893-14-6 ]

3-Bromo-5-methoxybenzoic acid

Similarity: 0.90

Chemical Structure| 61203-46-1

[ 61203-46-1 ]

3-Bromo-4,5-dihydroxybenzoic acid

Similarity: 0.90

Carboxylic Acids

Chemical Structure| 1261951-96-5

[ 1261951-96-5 ]

3'-Bromo-5'-hydroxy-[1,1'-biphenyl]-3,5-dicarboxylic acid

Similarity: 0.93

Chemical Structure| 1261951-62-5

[ 1261951-62-5 ]

3'-Bromo-5'-hydroxy-[1,1'-biphenyl]-3-carboxylic acid

Similarity: 0.93

Chemical Structure| 1261991-91-6

[ 1261991-91-6 ]

3-Bromo-5-(4-carboxyphenyl)phenol

Similarity: 0.93

Chemical Structure| 157893-14-6

[ 157893-14-6 ]

3-Bromo-5-methoxybenzoic acid

Similarity: 0.90

Chemical Structure| 61203-46-1

[ 61203-46-1 ]

3-Bromo-4,5-dihydroxybenzoic acid

Similarity: 0.90

; ;