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Chemical Structure| 140-22-7 Chemical Structure| 140-22-7
Chemical Structure| 140-22-7

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CAS No.: 140-22-7

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Sulowska, Agnieszka ; Borzyszkowska, Agnieszka Fiszka ; Pisarek, Marcin ; Trzciński, Konrad ; Zielińska-Jurek, Anna ;

Abstract: In this paper, a new series of Fe2TiO5 - polypyrrole (FTO-xP) were prepared by the facile polymerisation method using sulphuric acid and hydrogen peroxide as oxidising agents. The synthesised compounds were characterised by diffuse reflectance spectroscopy (DR/UV-vis), Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), microscopic analysis (SEM) and specific surface area analysis (BET) to evaluate their optical and surface properties, morphology, phase composition and crystallinity. The new composites were used for photocatalytic removal of micropollutants: highly toxic Cr(VI) and (IBU). The effect of polypyrrole content in the composite on the efficiency of selected micropollutants degradation was investigated. The results showed that FTO-xP composites had better adsorption capacity and photocatalytic activity than single components. Hybrid FTO-xP composites could efficiently remove inorganic/organic micropollutants in the aqueous phase.

Keywords: Polypyrrole ; Fe2TiO5 ; Ibuprofen ; Cr(VI) ; Photocatalysis ; Pseudobrookite ; Micropollutants

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Sulowska, Agnieszka ; Fiszka Borzyszkowska, Agnieszka ; Cysewska, Karolina ; Siwinska-Ciesielczyk, Katarzyna ; Nikiforow, Konstantin ; Trykowski, Grzegorz , et al.

Abstract: The present study represents an approach to apply organic-inorganic hybrid materials for photocatalytic removal of heavy metals from the aqueous environment. The photocatalytic activity of the semiconductor modified with the conjugated polymer may depends on the conjugated polymer type, its amount and morphol. Therefore, in the present study the effect of poly(3,4-ethylenedioxythiophene) (PEDOT) morphol. on adsorption and photoreduction of Cr(VI) to Cr(III) under simulated solar light (UV-vis) and vis light (λ > 400 nm) was investigated. The composite of titanium (IV) oxide and PEDOT of different morphol. was obtained using the water-in-oil microemulsion method. The obtained hybrid photocatalysts were characterized by diffuse reflectance spectroscopy (DR/UV-vis), Fourier transform IR spectroscopy (FTIR), X-ray diffraction (XRD), scanning and transmission electron microscopy (SEM, TEM), sp. surface area (BET) and XPS analyzes. PEDOT and its composites with TiO2 nanosheets of anatase were used for the degradation of highly toxic Cr(VI) under the simulated solar light. The 2D TiO2/PEDOT composite with PEDOT microvesicular morphol. reveals the highest efficiency of Cr(VI) photoreduction to Cr(III). The synergistic effect of 2D TiO2 and PEDOT for Cr(VI) removal is observed in UV-vis light, resulting from the increased separation of photogenerated electrons and holes involved in redox reactions. Furthermore, the 2D TiO2/PEDOT composite with PEDOT microvesicular morphol. reveals improved photocatalytic activity under visible light irradiation (λ > 400 nm).

Keywords: 2DTiO2 ; PEDOT ; Cr(VI) reduction ; Photocatalysis

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Alternative Products

Product Details of 1,5-Diphenylcarbazide

CAS No. :140-22-7
Formula : C13H14N4O
M.W : 242.28
SMILES Code : O=C(NNC1=CC=CC=C1)NNC2=CC=CC=C2
MDL No. :MFCD00003013
InChI Key :KSPIHGBHKVISFI-UHFFFAOYSA-N
Pubchem ID :8789

Safety of 1,5-Diphenylcarbazide

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H315-H319-H335
Precautionary Statements:P261-P305+P351+P338
 

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