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CAS No. : | 1271-51-8 | MDL No. : | MFCD00001434 |
Formula : | C12H12Fe | Boiling Point : | - |
Linear Structure Formula : | (C5H5)Fe(C5H4C2H3) | InChI Key : | - |
M.W : | 212.07 | Pubchem ID : | - |
Synonyms : |
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Signal Word: | Danger | Class: | 4.1 |
Precautionary Statements: | P210 | UN#: | 1325 |
Hazard Statements: | H228 | Packing Group: | Ⅱ |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With tributyl-amine;tri-tert-butyl phosphine; palladium diacetate; In 1,4-dioxane; for 96h;Inert atmosphere; Reflux; | About 424 mg (about 2 mmol) of vinylferrocene, about 312 mg (about 0.5 mmol) of <strong>[4181-20-8]tris(4-iodophenyl)amine</strong> and about 7 mg (about 6 mol percent) of palladium acetate were placed in a flask. After a reflux condenser was connected to the flask, about 3 ml of 1,4-dioxene as a solvent, about 480 mul (about 2 mmol) of tri-n-butylamine as a base and about 11 mul (about 9 mol percent) of tri-t-butylphosphine were injected into the flask using a syringe under a nitrogen atmosphere. The solution was degassed with nitrogen gas, and refluxed in an oil bath. The reaction was allowed to proceed for about 4 days. The reaction solution was diluted with about 10 ml of methylene chloride and neutralized with a saturated aqueous solution of ammonium chloride. The neutralized solution was transferred to a separatory funnel, followed by phase separation. The obtained organic layer was dried over anhydrous magnesium sulfate and passed through a glass filter to obtain a transparent polymer solution. The polymer solution was evaporated under reduced pressure to remove the solvents. The residue was purified by column chromatography using toluene/hexane (1/2), yielding the metallocenyl dendrimer (about 301 mg) of Formula 2 as an orange solid. The 1H-NMR spectrum of the metallocenyl dendrimer is shown in FIG. 3. |