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CAS No. : | 123-01-3 | MDL No. : | MFCD00008974 |
Formula : | C18H30 | Boiling Point : | - |
Linear Structure Formula : | H(CH2)12C6H5 | InChI Key : | KWKXNDCHNDYVRT-UHFFFAOYSA-N |
M.W : | 246.43 | Pubchem ID : | 31237 |
Synonyms : |
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Chemical Name : | Dodecylbenzene |
Signal Word: | Warning | Class: | N/A |
Precautionary Statements: | P261-P301+P312-P302+P352-P304+P340-P305+P351+P338 | UN#: | N/A |
Hazard Statements: | H302-H315-H319-H335 | Packing Group: | N/A |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
38.5% | Synthesis of 3,6-Diphenyl-9-tosyl-9H-carbazole 3-Bromo-9-tosyl-9H-carbazole (4.20 g, 13.2 mmol), <strong>[56525-79-2]3,6-diphenyl-9H-carbazole</strong> (4.87 g, 12.5 mmol) and copper(I) oxide (4.54 g, 31.8 mmol) were added to dodecylbenzene (12.3 mL), and the mixture was heated to 220°C under a nitrogen gas environment for 20 hours. After completing the reaction, copper (I) oxide was removed by filtration, and then the filtrate was purified by silica gel column chromatography (developing solvent: hexane/dichloromethane = 50/50) (yield amount: 3.24 g (5.07 mmol), yield: 38.5percent). 1H-NMR (500 MHz, CDCl3) : delta (ppm) 8.58 (d, J = 8.5 Hz, 1H), 8.43 (d, J = 1.5 Hz, 2H), 8.41 (d, J = 8.5 Hz, 1H), 8.14 (d, J = 2.0 Hz, 1H), 7.92 (d, J = 7.5 Hz, 1H), 7.84 (d, J = 8.5 Hz, 2H), 7.75-7.72 (m, 6H), 7.68 (dd, J = 1.5 Hz, J=2.0Hz, 2H), 7.59-7.56 (m, 1H), 7.52-7.45 (m, 5H), 7.42-7.39 (m, 1H), 7.37-7.35 (m, 2H), 2.34 (s, 3H) |