[ CAS No. 119-80-2 ] {[proInfo.proName]}

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2D 3D

Structure of 119-80-2 * Storage: {[proInfo.prStorage]}

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Quality Control of [ 119-80-2 ]

COA NMR CNMR HPLC LC-MS

Related Doc. of [ 119-80-2 ]

SDS Specification

Alternatived Products of [ 119-80-2 ]

Product Details of [ 119-80-2 ]

CAS No. :	119-80-2	MDL No. :	MFCD00002465
Formula :	C₁₄H₁₀O₄S₂	Boiling Point :	No data available
Linear Structure Formula :	-	InChI Key :	LBEMXJWGHIEXRA-UHFFFAOYSA-N
M.W :	306.36	Pubchem ID :	8409
Synonyms :

Safety of [ 119-80-2 ]

Signal Word:	Warning	Class:
Precautionary Statements:	P261-P305+P351+P338	UN#:
Hazard Statements:	H315-H319-H335	Packing Group:
GHS Pictogram:

Application In Synthesis of [ 119-80-2 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Upstream synthesis route of [ 119-80-2 ]
Downstream synthetic route of [ 119-80-2 ]

[ 119-80-2 ] Synthesis Path-Upstream 1~1

1
[ 119-80-2 ]
[ 4299-07-4 ]

Reference： [1] Molecules, 2010, vol. 15, # 11, p. 8214 - 8228

[ 119-80-2 ] Synthesis Path-Downstream 1~1

1
[ 119-80-2 ]
[ 17672-21-8 ]
dimethyl 2,2’-((2,2’-disulfanediylbis(benzoyl))bis(azanediyl))bis(3-hydroxybenzoate) [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
33%		2,2?-Dithiodibenzoic acid (0.100g,0.326 mmol) and 1-1?-carbonyldiimidazole (0.127g, 0.782 mmol) weredissolved in THF (3mL) and stirred for 30 minutes under inert atmosphere.Methyl 3-hydroxyanthranilate (0.109g, 0.652 mmol) was added and the reactionmixture was refluxed for 21 hours. The reaction mixture was cooled to roomtemperature and transferred to a separatory funnel along with 30mL H2Oand extracted with EtOAc (3x30mL). Combined organic phases were washed with H2O(2x50mL) and brine (1x50mL), dried with MgSO4, and concentrated underreduced pressure to give a light brown solid. Crude product was purified viaflash chromatography (5% EtOAc in CH2Cl2) to give 0.0640gdesired compound as a yellow-orange solid (33% yield). 1H NMR(400MHz, CDCl3) d11.92 (1H, s), d 9.51(1H, s), d 7.90 (2H, d, J= 11.0Hz), d 7.68(1H, d, J= 7.4Hz), d7.46 (1H, t, J= 7.8Hz), d 7.35(2H, m), d 7.21 (1H, m), d 3.94 (3H, s).

Reference： [1]Bioorganic and Medicinal Chemistry Letters,2016,vol. 26,p. 1196 - 1199

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Isomers

Technical Information

? Arndt-Eistert Homologation ? Benzylic Oxidation ? Birch Reduction ? Blanc Chloromethylation ? Friedel-Crafts Reaction ? Hunsdiecker-Borodin Reaction ? Hydride Reductions ? Hydrogenolysis of Benzyl Ether ? Nucleophilicity of Sulfur Compounds ? Oxidation States of Sulfur Compounds ? Passerini Reaction ? Preparation of Alkylbenzene ? Preparation of Amines ? Preparation of Carboxylic Acids ? Reactions of Amines ? Reactions of Benzene and Substituted Benzenes ? Reactions of Carboxylic Acids ? Schmidt Reaction ? Specialized Acylation Reagents-Ketenes ? Ugi Reaction ? Vilsmeier-Haack Reaction

Historical Records

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[ 119-80-2 ]

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Ghs Precautionary Statements

Precautionary Statements-General
Code	Phrase
P101	If medical advice is needed,have product container or label at hand.
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Prevention
Code	Phrase
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Code	Phrase
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P302 + P352	IF ON SKIN: wash with plenty of soap and water.
P321
P322
P330	Rinse mouth.
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P301 + P312	IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P301 + P330 + P331	IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302 + P334	IF ON SKIN: Immerse in cool water/wrap in wet bandages.
P302 + P350	IF ON SKIN: Gently wash with plenty of soap and water.
P303 + P361 + P353	IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P304 + P312	IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell.
P304 + P340	IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P304 + P341	IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338	IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P306 + P360	IF ON CLOTHING: Rinse Immediately contaminated CLOTHING and SKIN with plenty of water before removing clothes.
P307 + P311	IF exposed: call a POISON CENTER or doctor/physician.
P308 + P313	IF exposed or concerned: Get medical advice/attention.
P309 + P311	IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician.
P332 + P313	IF SKIN irritation occurs: Get medical advice/attention.
P333 + P313	IF SKIN irritation or rash occurs: Get medical advice/attention.
P335 + P334	Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.
P337 + P313	IF eye irritation persists: Get medical advice/attention.
P342 + P311	IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician.
P370 + P376	In case of fire: Stop leak if safe to Do so.
P370 + P378	In case of fire:
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P370 + P380 + P375	In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion.
P371 + P380 + P375	In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion.
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P401
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P411 + P235	Keep cool.
Disposal
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Physical hazards
Code	Phrase
H200	Unstable explosive
H201	Explosive; mass explosion hazard
H202	Explosive; severe projection hazard
H203	Explosive; fire, blast or projection hazard
H204	Fire or projection hazard
H205	May mass explode in fire
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H221	Flammable gas
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H240	Heating may cause an explosion
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H250	Catches fire spontaneously if exposed to air
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H261	In contact with water releases flammable gas
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H373	May cause damage to organs through prolonged or repeated exposure
Environmental hazards
Code	Phrase
H400	Very toxic to aquatic life
H401	Toxic to aquatic life
H402	Harmful to aquatic life
H410	Very toxic to aquatic life with long-lasting effects
H411	Toxic to aquatic life with long-lasting effects
H412	Harmful to aquatic life with long-lasting effects
H413	May cause long-lasting harmful effects to aquatic life
H420	Harms public health and the environment by destroying ozone in the upper atmosphere

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[ CAS No. 119-80-2 ] {[proInfo.proName]}

Quality Control of [ 119-80-2 ]

Related Doc. of [ 119-80-2 ]

Product Details of [ 119-80-2 ]

Safety of [ 119-80-2 ]

Application In Synthesis of [ 119-80-2 ]

[ 119-80-2 ] Synthesis Path-Upstream 1~1

[ 119-80-2 ] Synthesis Path-Downstream 1~1

Technical Information

Related Functional Groups of [ 119-80-2 ]

Aryls

Carboxylic Acids

Sulfides

Precautionary Statements-General

Prevention

Response

Storage

Disposal

Physical hazards

Health hazards

Environmental hazards

Inquiry

Related Functional Groups of
[ 119-80-2 ]