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[ CAS No. 114798-26-4 ] {[proInfo.proName]}

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Chemical Structure| 114798-26-4
Chemical Structure| 114798-26-4
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Wang, Zaoming ; Pacheco-Fernández, Idaira ; Carpenter, James E , et al. DOI:

Abstract: The wide presence of pharmaceuticals and personal care products (PPCPs) in water is a major pollution concern even at the part per billion level, which urges their detection and removal. Current research emphasizes the use of microporous materials as adsorbents for pollutant removal but demonstrates the performance at a higher concentration than realistic environmental water due to the absence of efficient detection methods that can be coupled with the removal process. Here we report a pore-networked membrane (PNM) that can simultaneously remove and detect targeted trace-level PPCPs. These PNMs are designed by interconnecting adsorbents within polymer matrices, forming continuous, tunable porous networks that are accessible for PPCPs, thereby offering high selectivity and adsorption capacity. Evaluations across water samples containing 13 pollutants demonstrate the capability of PNMs to selectively adsorb PPCPs for removal and subsequently release them into analysis solution for detection, positioning their promising use in real water treatment workflow.

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Wang, Zaoming ; Pacheco-Fernandez, Idaira ; Carpenter, James E. , et al. DOI:

Abstract: The wide presence of pharmaceuticals and personal care products (PPCPs) in water is a major concern regarding current emerging pollution and urges their selective monitoring to establish water quality management. Microporous materials have been developed to extract organic contaminants and further embedded as fillers into polymeric composites like matrix-mixed membranes (MMMs) for practical use. Considering the relatively large mol. size of PPCPs and their slow diffusion in the membrane, the MMM configuration is, however, inadequate for liquid-phase separations Here we report pore-networked membranes (PNMs) based on the concept of interconnecting the microporous fillers within the polymer matrix to form a continuous porous phase. Linked metal-organic polyhedra (MOP) network is designed for the continuous porous phase with tunable micro/mesopores, which are accessible for big PPCP mols. to facilitate their diffusion and adsorption. By contrast to MMMs, PNMs show enhanced stability, capacity and extraction selectivity towards specific pharmaceutical drugs amongst 13 PPCPs in environmental water matrixes at trace-level concentrations

Keywords: Porous materials ; Membranes ; Water contaminants ; Metal-organic polyhedra

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Product Details of [ 114798-26-4 ]

CAS No. :114798-26-4 MDL No. :MFCD00865831
Formula : C22H23ClN6O Boiling Point : -
Linear Structure Formula :- InChI Key :PSIFNNKUMBGKDQ-UHFFFAOYSA-N
M.W : 422.91 Pubchem ID :3961
Synonyms :
DuP-753
Chemical Name :(1-((2'-(1H-Tetrazol-5-yl)-[1,1'-biphenyl]-4-yl)methyl)-2-butyl-4-chloro-1H-imidazol-5-yl)methanol

Safety of [ 114798-26-4 ]

Signal Word:Danger Class:4.1
Precautionary Statements:P210-P501-P261-P272-P202-P201-P280-P302+P352-P308+P313-P362+P364-P333+P313-P405 UN#:1325
Hazard Statements:H317-H361-H228 Packing Group:Ⅲ
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[ 114798-26-4 ]

Chemical Structure| 124750-99-8

A561984[ 124750-99-8 ]

(1-((2'-(2H-Tetrazol-5-yl)-[1,1'-biphenyl]-4-yl)methyl)-2-butyl-4-chloro-1H-imidazol-5-yl)methanol, potassium salt

Reason: Free-salt

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