[ CAS No. 108464-88-6 ] {[proInfo.proName]}

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Quality Control of [ 108464-88-6 ]

COA NMR CNMR HPLC LC-MS

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SDS Specification

Alternatived Products of [ 108464-88-6 ]

Product Citations

Preparation and properties of bisphenol A polyetherketoneketone based phthalonitrile resins

Loren C. Brown ; Tyler J. Richardson ; Clair F. Lusk , et al. J. Appl. Polym. Sci.,2024,141(11):e55080. DOI: 10.1002/app.55080

Abstract: A promising high temperature phthalonitrile (PN) resin composed of a polyetherketoneketone (PEKK) core bridged by two bisphenol A linkers and end capped with PN groups is presented. This PEKK-PN resin was characterized via differential scanning calorimetry, thermogravimetric analysis, proton nuclear magnetic resonance spectroscopy, scanning electron microscopy, dynamic mechanical analysis, attenuated total reflection Fourier transform infrared, and rheometry. The PEKK-PN resin was evaluated with two different compositions containing 1) 70:30 PEKK-PN to bisphenol A PN (n?=?0) and 2) pure PEKK-PN. The 70:30 PEKK-PN resin was mixed with bis[4-(3-aminophenoxy)phenyl]sulfone and exhibited a melt viscosity of 271?cP, much lower than the 657?cP viscosity of the pure PEKK-PN mixture. Void-free PEKK-PN polymers were easily prepared by degassing and curing up to 380°C, resulting in fully crosslinked networks exhibiting thermal stability above 500°C and a 75% char yield. Additionally, the cured PEKK-PN polymer samples displayed good mechanical integrity retaining 50% stiffness at 300°C. This combination of properties suggests these new PEKK-PN resins are excellent materials for high temperature thermosets in composite applications.

Keywords: bisphenol A ; phthalonitrile ; resin ; thermoset

Purchased from AmBeed: 31643-49-9 ; 108464-88-6

Product Details of [ 108464-88-6 ]

CAS No. :	108464-88-6	MDL No. :	MFCD00239360
Formula :	C₂₀H₁₂F₂O₂	Boiling Point :	-
Linear Structure Formula :	-	InChI Key :	PISLKPDKKIDMQT-UHFFFAOYSA-N
M.W :	322.30	Pubchem ID :	688263
Synonyms :

Safety of [ 108464-88-6 ]

Signal Word:	Warning	Class:
Precautionary Statements:	P233-P260-P261-P264-P271-P280-P302+P352-P304-P304+P340-P305+P351+P338-P312-P321-P332+P313-P337+P313-P340-P362-P403-P403+P233-P405-P501	UN#:
Hazard Statements:	H315-H319-H335	Packing Group:
GHS Pictogram:

Application In Synthesis of [ 108464-88-6 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Downstream synthetic route of [ 108464-88-6 ]

[ 108464-88-6 ] Synthesis Path-Downstream 1~4

1
[ 92-88-6 ]
[ 135-53-5 ]
[ 108464-88-6 ]
Polymer; Monomer(s): 1,3-bis(4-fluorobenzoyl)benzene, 5 mmol; sodium 6,7-dihydroxy-2-naphthalenesulfonate, 4.5 mmol; 4,4\-biphenol, 0.5 mmol [ No CAS ]

Reference： [1]Macromolecules,2004,vol. 37,p. 6748 - 6754

2
[ 92-88-6 ]
[ 135-53-5 ]
[ 108464-88-6 ]
Polymer; Monomer(s): 1,3-bis(4-fluorobenzoyl)benzene, 5 mmol; sodium 6,7-dihydroxy-2-naphthalenesulfonate, 4 mmol; 4,4\-biphenol, 1 mmol [ No CAS ]

Reference： [1]Macromolecules,2004,vol. 37,p. 6748 - 6754

3
[ 92-88-6 ]
[ 135-53-5 ]
[ 108464-88-6 ]
Polymer; Monomer(s): 1,3-bis(4-fluorobenzoyl)benzene, 5 mmol; sodium 6,7-dihydroxy-2-naphthalenesulfonate, 3.5 mmol; 4,4\-biphenol, 1.5 mmol [ No CAS ]

Reference： [1]Macromolecules,2004,vol. 37,p. 6748 - 6754

4
[ 92-88-6 ]
[ 135-53-5 ]
[ 108464-88-6 ]
Polymer; Monomer(s): 1,3-bis(4-fluorobenzoyl)benzene, 5 mmol; sodium 6,7-dihydroxy-2-naphthalenesulfonate, 3 mmol; 4,4\-biphenol, 2 mmol [ No CAS ]

Reference： [1]Macromolecules,2004,vol. 37,p. 6748 - 6754

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Technical Information

? Alkyl Halide Occurrence ? Baeyer-Villiger Oxidation ? Barbier Coupling Reaction ? Baylis-Hillman Reaction ? Benzylic Oxidation ? Birch Reduction ? Blanc Chloromethylation ? Bucherer-Bergs Reaction ? Clemmensen Reduction ? Corey-Bakshi-Shibata (CBS) Reduction ? Corey-Chaykovsky Reaction ? Fischer Indole Synthesis ? Friedel-Crafts Reaction ? Grignard Reaction ? Henry Nitroaldol Reaction ? Horner-Wadsworth-Emmons Reaction ? Hydride Reductions ? Hydrogenolysis of Benzyl Ether ? Lawesson's Reagent ? Leuckart-Wallach Reaction ? McMurry Coupling ? Meerwein-Ponndorf-Verley Reduction ? Passerini Reaction ? Paternò-Büchi Reaction ? Petasis Reaction ? Peterson Olefination ? Pictet-Spengler Tetrahydroisoquinoline Synthesis ? Preparation of Aldehydes and Ketones ? Preparation of Alkylbenzene ? Preparation of Amines ? Prins Reaction ? Reactions of Aldehydes and Ketones ? Reactions of Amines ? Reactions of Benzene and Substituted Benzenes ? Reformatsky Reaction ? Robinson Annulation ? Schlosser Modification of the Wittig Reaction ? Schmidt Reaction ? Specialized Acylation Reagents-Ketenes ? Stobbe Condensation ? Tebbe Olefination ? Ugi Reaction ? Vilsmeier-Haack Reaction ? Wittig Reaction ? Wolff-Kishner Reduction

Historical Records

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[ 108464-88-6 ]

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P302 + P334	IF ON SKIN: Immerse in cool water/wrap in wet bandages.
P302 + P350	IF ON SKIN: Gently wash with plenty of soap and water.
P303 + P361 + P353	IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
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P304 + P340	IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
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P305 + P351 + P338	IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
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P335 + P334	Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.
P337 + P313	IF eye irritation persists: Get medical advice/attention.
P342 + P311	IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician.
P370 + P376	In case of fire: Stop leak if safe to Do so.
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H200	Unstable explosive
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H242	Heating may cause a fire
H250	Catches fire spontaneously if exposed to air
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H401	Toxic to aquatic life
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[ CAS No. 108464-88-6 ] {[proInfo.proName]}

Quality Control of [ 108464-88-6 ]

Related Doc. of [ 108464-88-6 ]

Product Citations

Product Details of [ 108464-88-6 ]

Safety of [ 108464-88-6 ]

Application In Synthesis of [ 108464-88-6 ]

[ 108464-88-6 ] Synthesis Path-Downstream 1~4

Technical Information

Related Functional Groups of [ 108464-88-6 ]

Fluorinated Building Blocks

Aryls

Ketones

Precautionary Statements-General

Prevention

Response

Storage

Disposal

Physical hazards

Health hazards

Environmental hazards

Inquiry

Related Functional Groups of
[ 108464-88-6 ]