Exceptional ligands for Pd-catalyzed amination and amidation of aryl sulfonates.

 Ligand used for the Pd-catalyzed Suzuki-Miyaura coupling reaction and carbonyl enolate coupling.

 Ligand used for the chemoselective amination of aryl chlorides.

 Ligand used for the Pd-catalyzed borylation of aryl chlorides, for the formation of trifluoroborates.

 Ligand used for the Pd-catalyzed amination of vinyl halides and triflates.

 Ligand used for the Pd-catalyzed three-component synthesis of indoles.

 Ligand used for the Pt-catalyzed regioselective hydrosilylation of functionalized terminal arylalkynes.

 Ligand used for the Pd-catalyzed synthesis of carbazoles.

 Ligand used for the Pd-catalyzed Suzuki-Miyaura coupling of aryl chloride and NHC-boranes.

 Ligand used for the direct arylation of picoline N-oxide.

 Ligand used for the Negishi coupling of 2-heterocyclic organozinc reagents.

 Catalyst for a phosphine-catalyzed Heine reaction.

 Ligand used for the palladium-catalyzed oxidative coupling of indoles and heteroarenes.

 Ligand used for the silver-catalyzed hydrogenation of aldehydes.

 Ligand used for the palladium-catalyzed cyanation of heterycyclic halides.