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Postion:Product Catalog >Chemical Reagents>Organic reagents>Oxime>Salicylaldoxime
Salicylaldoxime
  • Salicylaldoxime
  • Salicylaldoxime
  • Salicylaldoxime
  • Salicylaldoxime
  • Salicylaldoxime

Salicylaldoxime NEW

Price Get Latest Price
Package 25KG
Min. Order: 1KG
Supply Ability: 50000KG/month
Update Time: 2023-09-05

Product Details

Product Name: Salicylaldoxime CAS No.: 94-67-7
EC-No.: 202-353-8 Min. Order: 1KG
Purity: 99% Supply Ability: 50000KG/month
Release date: 2023/09/05

CAS:94-67-7
MF:C7H7NO2
MW:137.14
EINECS:202-353-8
Product Categories:Aromatic Hydrazides, Hydrazines, Hydrazones and Oximes
Mol File:94-67-7.mol
Article illustration

Salicylaldoxime Chemical Properties
Melting point 57-59 °C 59-61 °C (lit.)
Boiling point 251.96°C (rough estimate)
density 1.2528 (rough estimate)
refractive index 1.5030 (estimate)
storage temp. Sealed in dry,Room Temperature
solubility sparingly soluble in water, soluble in ethanol, diethyl ether, acetone, benzene.
pkapK1:1.37(+1);pK2:9.18;pK3:12.11 (25°C)
form Powder
color Bordeaux to purple-red
OdorOdorless
Water Solubility Slightly soluble in water
Merck 14,8327
BRN 1859881
InChIKeyORIHZIZPTZTNCU-VMPITWQZSA-N
CAS DataBase Reference94-67-7(CAS DataBase Reference)
NIST Chemistry ReferenceBenzaldehyde, 2-hydroxy-, oxime(94-67-7)
EPA Substance Registry SystemBenzaldehyde, 2-hydroxy-, oxime (94-67-7)
Salicylaldoxime Usage And Synthesis
Uses

Salicylaldoxime is an organic compound described by the formula C6H4CH=NOH-2-OH and it is the oxime of salicylaldehyde. This crystalline, colorless solid is a chelator and sometimes used in the analysis of samples containing transition metal ions, with which it often forms brightly colored coordination complexes.

Elements Extraction

Salicylaldoxime is recognized as a selective precipitant for copper, although it forms water-insoluble chelates with a number of elements. Ingvar Dahl invested the extraction of divalent magnesium, manganese, cobalt, nickel, copper, zinc, cadmium, mercury, and lead with solutions of salicylaldoxime in benzene and the effect of the reagent concentration and particularly the pH of the aqueous phase on the extractability was also studied. The solubility of salicylaldoxime in organic solvents has been utilized in the solvent extraction of carious elements.

Chemical Propertiesoff-white to light beige crystalline powder
UsesAs a reagent for copper and nickel.
UsesSalicylaldoxime reacts with several metal ions to give intensively coloured complexes which are insoluble in water. The structure of the copper(II), nickel(II) and palladium(II) complexes is shown in Fig. 14 (structure I), and that of the manganese(II), iron(II), cobalt(II) and zinc(II) complexes in Fig. 14 (structure II). The copper(Il) and palladium(II) salicylaldoxime complexes are of importance from an analytical point of view. The complexes precipitated from aqueous media are easily filterable and washable and are weighed after drying at 100°C. The precipitates are of stoichiometric composition.
The outstanding stabilities of the copper(II) and palladium(II) complexes make the reagent suitable for the selective determination of these metal ions. These two complexes form quantitatively at low pH values where the complexes of other metal ions do not exist.
Besides the gravimetric method, salicylaldoxime is also useful in the volumetric, amperometric and nephelometric determinations of copper and palladium.
Salicylaldoxime gives a black precipitate with VOs~ in media containing sulfuric acid; this is soluble in chloroform to give an orange solution. The reaction is specific for vanadium which can thus be detected by this method in the presence of almost all other metals.
In neutral medium salicylaldoxime reacts with iron(III) to give a red complex which is soluble in water. The reaction is utilized for the detection of micro amounts of iron.

Packing &shipping&Payment

Packing:25kg/drum
Shipping:by sea or by air
Payment:T/T,western union,moneygram
Packaging Details drum
Port:Tianjin
Lead Time :
Quantity(Kilograms)1 - 10000>10000
Est. Time(days)5To be negotiated

Article illustration

Article illustrationCompany information
Hebei Mojin Biotechnology Co., Ltd, Our company is a professional in 4'-Methylacetophenone,Levamisole hydrochloride ,N-Methylformamide and other chemical reagents research and development production enterprises. Our business covers more than 30 countries, most of the big customers come from Europe, America and other countries in the world, we can guarantee the quality and price. In recent decades, with the efforts of all employees, we have established many cooperative companies in shandong, henan, guangdong and other places. Our corporate purpose is based on the market, enhance the strength, take the road of scientific and environmental sustainable development, relying on the country. Technology r & d center, increase the investment in r & d, based on the domestic market, expand the international market, manufacturing quality products, sincere service to the society, into a modern, ecological, scientific and technological enterprise world.

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