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Postion:Product Catalog >Inorganic chemistry>Inorganic salts>Carbides and carbonates>Cupric carbonate basic
Cupric carbonate basic
  • Cupric carbonate basic
  • Cupric carbonate basic
  • Cupric carbonate basic
  • Cupric carbonate basic
  • Cupric carbonate basic

Cupric carbonate basic NEW

Price Get Latest Price
Package 25KG
Min. Order: 1KG
Supply Ability: 50000KG/month
Update Time: 2023-09-21

Product Details

Product Name: Cupric carbonate basic CAS No.: 12069-69-1
EC-No.: 235-113-6 Min. Order: 1KG
Purity: 99% Supply Ability: 50000KG/month
Release date: 2023/09/21

CAS:12069-69-1
MF:CO3.Cu.CuH2O2
MW:221.11
EINECS:235-113-6
Product Categories:Inorganics;metal carbonate
Mol File:12069-69-1.mol
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Cupric carbonate basic Chemical Properties
Melting point 200 °C
density 4
storage temp. Sealed in dry,Room Temperature
solubility Aqueous Acid (Slightly)
form Solid
color green
Specific Gravity4.
Water Solubility Insoluble
Merck 14,2631
Solubility Product Constant (Ksp)pKsp: 9.86
Exposure limitsACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 1 mg/m3
CAS DataBase Reference12069-69-1(CAS DataBase Reference)
EPA Substance Registry SystemCopper carbonate, basic (12069-69-1)
UsesIt can be applied to the fields of pyrotechnics, pesticides, pigments, feed, fungicides, preservatives and other industries for the manufacturing of copper compounds.
It can be applied to analysis reagents and pesticides
It can be applied to organic catalysts, pyrotechnics and pigments. In the field of agriculture, it can be used for the prevention of plants smut, as the poisoning antidote for insecticides and phosphorus poison antidote as well as the germicide of the seeds; being mixed with asphalt can prevent animal husbandry and wild rat from eating seedlings; it can be applied to feed as the copper additive. In the crude oil storage, it can be used as alkali agent and the raw material for the production of copper compounds. It can also be used for electroplating, corrosion and analysis reagents.
It can be applied to paint color, pyrotechnics, pesticides, seed treatment germicide and for preparation of other copper salts. It can also be used as solid fluorescent powder activator.
Production methodCopper sulfate method; formulate the baking soda into solution of relative density of 1.05, first add to the reactor, at 50 ° C, under stirring, add refined copper sulfate solution and control the reaction temperature of 70~80 ° C. The reaction takes the change of the precipitate color to peacock green as the turning point with the pH being maintained at 8. After the stopping of the reaction, after standing and sedimentation, use 70~80 ℃ water or no ion-water to wash to until the lotion has no SO42-anymore, followed by centrifugal separation, drying to obtain the finished product of cupric carbonate base. The reaction is:
2CuSO4 + 4NaHCO3 → CuCO3 ? Cu (OH) 2 + 2Na2SO4 + 3CO2 ↑ + H2O
Copper nitrate: after the electrolytic copper is reacted with concentrated nitric acid to produce copper nitrate, and then have reaction with the mixture solution of sodium carbonate and sodium bicarbonate to generate cupric carbonate basic. The precipitate is subjecting to washing, separation and dehydration, drying to yield the final products. The reaction processes are:
Cu + 4HNO3 → Cu (NO3) 2 + 2NO2 ↑ + 2H2O
2Cu (NO3) 2 + 2Na2CO3 + H2O → CuCO3 ? Cu (OH) 2 + 4NaNO3 + CO2 ↑
2Cu (NO3) 2 + 4NaHCO3 → CuCO3 ? Cu (OH) 2 + 4NaNO3 + 3CO2 ↑ + H2O
CategoryPesticides
Toxic gradingpoisoning
Acute ToxicityOral-Rat LD50: 1350 mg/kg
Flammability and hazardous propertiesit is non-combustible with combustion yielding toxic copper-containing fumes;
Storage and transport characteristicsTreasury at low temperature, ventilation, dry
Fire extinguishing agentwater, carbon dioxide, dry powder, and sand
Professional StandardTWA 1 mg/m3; STEL 3 mg/m3
Chemical PropertiesCopper carbonate (basic), dark green monoclinic crystals, insoluble in cold H20, decomposes in H20, soluble in potassium cyanide. Malachite, copper ore, is of this composition. Refmed compound is used as a pigment.
Chemical PropertiesCopper Carbonate (Basic), CuCO3·Cu(OH)2, darkgreen monoclinic crystals, insoluble in cold H2O decomposes in hot H2O, soluble in potassium cyanide. Malachite, a copper ore, is of this composition. Refined compound is used as a pigment.
Physical propertiesNatural malachite is a dark green crystalline solid; monoclinic crystals; density 4.0 g/cm3; refractive index 1.655; decomposes at 200°C; insoluble in cold water and alcohols; decomposes in hot water; soluble in acids, ammonium hydroxide and potassium cyanide solutions. Natural azurite is blue monoclinic crystal; density 3.88 g/cm3shiz; refractive index 1.730; decomposes at 220°C; insoluble in cold water; decomposes in hot water; soluble in ammonium hydroxide and hot sodium bicarbonate solutions.
UsesCopper(II) carbonate dihydroxide is used as pigments and in treatment for copper deficiency in ruminants. It is also used in pyrotechnics, in sweetening of petrol sour crude stock and animal and poultry feeds. It finds application in some types of make-up such as lipstick. In analytical chemistry, it is used as a reagent for analysis.
UsesUsed to kill algae and as a pigment
UsesAs seed treatment fungicide; in pyrotechnics; as paint and varnish pigment; in animal and poultry feeds; in sweetening of petrol sour crude stock; in manufacture of other Cu salts.
PreparationBasic carbonate is obtained from its naturally occurring minerals. It also may be prepared by mixing a solution of copper sulfate with sodium carbonate. The precipitate is then filtered and dried.
General DescriptionCopper(II) carbonate basic is naturally found in azurite and malachite. On heating, it undergoes decomposition to form copper(II) oxide, carbon dioxide and water. Due to its high initial discharge capacity, copper(II) carbonate (basic) is being considered as a promising candidate as anode materials for lithium-ion batteries.
HazardToxic by ingestion.

Packing &shipping&Payment

Packing:25kg/drum
Shipping:by sea or by air
Payment:T/T,western union,moneygram
Packaging Details drum
Port:Tianjin
Lead Time :
Quantity(Kilograms)1 - 10000>10000
Est. Time(days)5To be negotiated

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Article illustrationCompany information
Hebei Mojin Biotechnology Co., Ltd, Our company is a professional in 4'-Methylacetophenone,Levamisole hydrochloride ,N-Methylformamide and other chemical reagents research and development production enterprises. Our business covers more than 30 countries, most of the big customers come from Europe, America and other countries in the world, we can guarantee the quality and price. In recent decades, with the efforts of all employees, we have established many cooperative companies in shandong, henan, guangdong and other places. Our corporate purpose is based on the market, enhance the strength, take the road of scientific and environmental sustainable development, relying on the country. Technology r & d center, increase the investment in r & d, based on the domestic market, expand the international market, manufacturing quality products, sincere service to the society, into a modern, ecological, scientific and technological enterprise world.

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