Cupric acetate monohydrate NEW
Price | Get Latest Price |
Package | 25KG |
Min. Order: | 1KG |
Supply Ability: | 50000KG/month |
Update Time: | 2023-10-26 |
Product Details
Product Name: Cupric acetate monohydrate | CAS No.: 6046-93-1 |
EC-No.: 611-978-9 | Min. Order: 1KG |
Purity: 99% | Supply Ability: 50000KG/month |
Release date: 2023/10/26 |
CAS: | 6046-93-1 |
MF: | C4H8CuO5 |
MW: | 199.65 |
EINECS: | 611-978-9 |
Product Categories: | metal acetate salt |
Mol File: | 6046-93-1.mol |
Cupric acetate monohydrate Chemical Properties |
Melting point | 115 °C |
Boiling point | 240 °C |
density | 1.88 |
vapor density | 6.9 (vs air) |
storage temp. | Store at +5°C to +30°C. |
solubility | 72g/l |
form | Solid |
Specific Gravity | 1.882 |
color | Dark Green |
Odor | Slight acetic acid odor |
PH | 5.2-5.5 (20g/l, H2O, 20℃) |
PH Range | 5.2 - 5.5 |
Water Solubility | 72 g/L (20 oC) |
Hydrolytic Sensitivity | 0: forms stable aqueous solutions |
Merck | 14,2624 |
BRN | 3730548 |
Exposure limits | ACGIH: TWA 1 mg/m3 NIOSH: IDLH 100 mg/m3; TWA 1 mg/m3 |
Stability: | Stable. Incompatible with oxidizing agents. |
InChIKey | NWFNSTOSIVLCJA-UHFFFAOYSA-L |
LogP | -0.285 (est) |
CAS DataBase Reference | 6046-93-1(CAS DataBase Reference) |
Cupric acetate monohydrate Usage And Synthesis |
Physical Properties | Bluish-green fine powder; hygroscopic. The monohydrate is dimeric; density 1.88 g/cm3; melts at 115°C; decomposes at 240°C; soluble in water and ethanol; and slightly soluble in ether. |
Uses | Copper(II) acetate is used as a pigment for ceramics; in the manufacture of Paris green; in textile dyeing; as a fungicide; and as a catalyst. Copper(II) acetate monohydrate is used in DNA extraction in biochemical applications. It is also used as a catalyst or oxidizing agent in organic syntheses. Catalyst for activation of alcohols as greener alkylating reagents. Copper-Catalyzed Aerobic Oxidation of Amines to Imines under Neat Conditions with Low Catalyst Loading. |
Preparation | Copper(II) acetate is prepared by treatment of copper(II) oxide, CuO, or copper(II) carbonate, CuCO3, with acetic acid, followed by crystallization: CuO + 2CH3COOH → (CH3COO)2Cu + H2O |
Toxicity | Copper(II) acetate is moderately toxic by ingestion and possibly other routes of administration. LD50 oral (rat): c. 600 mg/kg |
Chemical Properties | Dark green small crystal with odour of acetic acid |
Chemical Properties | Cupric acetate is a greenish Blue powder or small crystals. |
Uses | Cupric acetate monohydrate can be used in preparation of Fehling's reagent for sugars |
Uses | Copper(II) acetate monohydrate is used in formation of Cu chelates of ?-dicarbonyl compounds as a means of purification and in the eglinton (modified glaser) coupling of terminal alkynes. It is also used as a catalyst for the michael reaction giving increased yields and absence of side-reactions. It Promotes ullmann-type C-O and C-N coupling reactions of arylboronic acids with phenols, amines and various other nitrogen derivatives. It is also used in biochemical applications such as DNA extraction. |
Uses | Catalyst for activation of alcohols as greener alkylating reagents Copper-Catalyzed Aerobic Oxidation of Amines to Imines under Neat Conditions with Low Catalyst Loading |
Preparation | Copper(II) acetate monohydrate can easily be produced by the reaction of acetic acid solutions with copper(II) carbonate or copper(II) hydroxide or by the reaction of copper(II) oxide with hot acetic acid. Large-scale commercial production uses copper metal in the presence of air and refluxing acetic acid. Copper(II) acetate monohydrate is used as a catalyst in the polymerization of organic materials and as a mordant in the dying of textiles. It is also used as a ceramic pigment and as a fungicide. |
General Description | Copper (II) acetate monohydrate is soluble in water and slightly soluble in methanol, diethylether and acetone. It can be synthesized by reacting acetic acid with copper (II) carbonate or copper(II) hydroxide or copper (II) oxide. Large scale commercial production is undertaken by placing copper metal in the presence of air and refluxing acetic acid. As a transition metal acetate, it can be used to form oxide nanoparticles by sonochemical methods. |
Potential Exposure | Cupric acetate is used as a fungicide, as a catalyst for organic reactions; in textile dyeing and as a pigment for ceramics. |
Shipping | UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required. |
Purification Methods | Recystallise it twice from warm dilute acetic acid solutions (5mL/g) by cooling. [Beilstein 2 IV 111.] |
Incompatibilities | Forms explosive materials with acetylene gas, ammonia, caustic solutions; sodium hypobromite; notromethane. Keep away from chemically active metals; strong acids; nitrates. Decomposes above 240C forming acetic acid fumes |
Waste Disposal | Copper-containing soluble wastes can be concentrated through the use of ion exchange, reverse osmosis, or evaporators to the point where copper can be electrolytically removed and sent to a reclaiming firm. If recovery is not feasible, the copper can be precipitated through the use of caustics and the sludge deposited in a chemical waste landfill. |
Packing &shipping&Payment
Shipping:by sea or by air
Payment:T/T,western union,moneygram
Packaging Details drum
Port:Tianjin
Lead Time :
Quantity(Kilograms) | 1 - 10000 | >10000 |
Est. Time(days) | 5 | To be negotiated |
Company information
Hebei Mojin Biotechnology Co., Ltd, Our company is a professional in 4'-Methylacetophenone,Levamisole hydrochloride ,N-Methylformamide and other chemical reagents research and development production enterprises. Our business covers more than 30 countries, most of the big customers come from Europe, America and other countries in the world, we can guarantee the quality and price. In recent decades, with the efforts of all employees, we have established many cooperative companies in shandong, henan, guangdong and other places. Our corporate purpose is based on the market, enhance the strength, take the road of scientific and environmental sustainable development, relying on the country. Technology r & d center, increase the investment in r & d, based on the domestic market, expand the international market, manufacturing quality products, sincere service to the society, into a modern, ecological, scientific and technological enterprise world.
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