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Postion:Product Catalog >Inorganic chemistry>Inorganic salts>Metal Sulphides and sulphates>Aluminum sulfide
Aluminum sulfide
  • Aluminum sulfide
  • Aluminum sulfide

Aluminum sulfide

Price Get Latest Price
Package 5g 100g
Min. Order: 5g
Supply Ability: 10kg
Update Time: 2019-11-18

Product Details

Product Name: Aluminum sulfide CAS No.: 1302-81-4
Min. Order: 5g Purity: 99.9%
Supply Ability: 10kg Release date: 2019/11/18

Aluminum sulfide or aluminium sulphide is a chemical compound with the formula Al2S3. This colorless species has an interesting structural chemistry, existing in several forms. The material is sensitive to moisture, hydrolyzing to hydrated aluminium oxides/hydroxides.[1] This can begin when the sulfide is exposed to the atmosphere. The hydrolysis reaction generates gaseous hydrogen sulfide (H2S).

Crystal structure

More than six crystalline forms of aluminium sulfide are known and only some are listed below. Most of them have rather similar, wurtzite-like structures, and differ by the arrangement of lattice vacancies, which form ordered or disordered sublattices.

Form
Symmetry
Space
group
a (A)
c (A)
ρ (g/cm3)
α
Hexagonal
 
6.423
17.83
2.32
β
Hexagonal
P63mc
3.579
5.829
2.495
γ
Trigonal
 
6.47
17.26
2.36
δ
Tetragonal
I41/amd
7.026
29.819
2.71

The β and γ phases are obtained by annealing the most stable α-Al2S3 phase at several hundred degrees Celsius.[4] Compressing aluminium sulfide to 2–65 kbar results in the δ phase where vacancies are arranged in a superlattice of tetragonal symmetry.

Unlike Al2O3, in which the Al(III) centers occupy octahedral holes, the more expanded framework of Al2S3 stabilizes the Al(III) centers into one third of the tetrahedral holes of a hexagonally close-packed arrangement of the sulfide anions. At higher temperature, the Al(III) centers become randomized to give a "defect wurtzite" structure. And at still higher temperatures stabilize the γ-Al2S3 forms, with a structure akin to γ-Al2O3.

Molecular derivatives of Al2S3 are not known. Mixed Al-S-Cl compounds are however known. Al2Se3 and Al2Te3 are also known.

Company Profile Introduction

TOP SCIENCE BIOCHEMICAL is a leading worldwide manufacturer of specialty organic chemicals . TSBIO provides organic laboratory chemicals as well as pharmaceutical, cosmetic and functional materials.TSBIO established overseas facilities in North America, Europe, China and India to serve customers worldwide. TSBIO provides a wide range of services to support the pharmaceutical industry through all stages of drug discovery including Custom Synthesis of those chemicals that are not in stock, Isotope Labeling Service, Chiral Synthesis and Resolution, Bioconjugation, PEGylation services, analytical services. Our capacity to provide pharmaceutical discovery services across the entire spectrum of the drug discovery process has assisted many of our esteemed clients in reaching their R&D goals.

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