2,2'-Bis(2-chlorophenyl)-4,4',5,5'-tetraphenyl-1,2'-biimidazole NEW
| Price | Get Latest Price | |
| Package | 1kg | 25kg |
| Min. Order: | 1kg |
| Supply Ability: | 30MT/Month |
| Update Time: | 2024-05-27 |
Product Details
| Product Name: 2,2'-Bis(2-chlorophenyl)-4,4',5,5'-tetraphenyl-1,2'-biimidazole | CAS No.: 7189-82-4 |
| EC-No.: 230-555-6 | Min. Order: 1kg |
| Purity: 99% | Supply Ability: 30MT/Month |
| Release date: 2024/05/27 |
7189-82-4 - Names and Identifiers
| Name | 2,2'-Bis(O-Chlorophenyl)-4,4',5,5'-Tetraphenyl-1,2'-Bi (III-Imidazole) |
| Synonyms | KSBC INBC BCIM Photopolymerizationinitiator 2,2'-di-(o-nitrophenoxy)-biphenyl 2,2-Bis(2-chlorophenyl)-4,4,5,5-tetraphenyl-1,2-biimidazole 2,2'-Bis(2-chlorophenyl)-4,4',5,5'-tetraphenyl-1,2'-biimidazo 2,2'-Bis(2-chlorophenyl)-4,4'5,5'-tetraphenyl-1,2'-biimidazole 2,2'-Bis(o-chlorophenyl)-4,4',5,5'-tetraphenyl-1,2'-biimidazole 2,2'-Bis(2-chlorophenyl)-4,4',5,5'-tetraphenyl-1,2'-biimidazole 2,2'-Bis(2-chlorophenyl)-4,5,4',5'-tetraphenyl-1,2'-biimidazole 2,2'-bis(2-chlorophenyl)-4,4',5,5'-tetraphenyl-2'H-1,2'-biimidazole 2,2'-bis(o-chlorophenyl)-4,4',5,5'-tetraphenyl-1,2'-bi(iii-imidazole) 2,2'-Bis(2-chlorophenyl)-4,4',5,5'-tetraphenyl-1,2'-biimidazole (BCIM) 2,2'-Bis(O-Chlorophenyl)-4,4',5,5'-Tetraphenyl-1,2'-Bi (III-Imidazole) 2-(2-CHLOROPHENYL)-1-[2-(2-CHLOROPHENYL)-4,5-DIPHENYL-IMIDAZOL-2-YL]-4,5-DIPHENYL-IMIDAZOLE |
| CAS | 7189-82-4 |
| EINECS | 230-555-6 |
| InChI | InChI=1/C42H28Cl2N4/c43-35-27-15-13-25-33(35)41-45-39(31-21-9-3-10-22-31)40(32-23-11-4-12-24-32)48(41)42(34-26-14-16-28-36(34)44)46-37(29-17-5-1-6-18-29)38(47-42)30-19-7-2-8-20-30/h1-28H |
7189-82-4 - Physico-chemical Properties
| Molecular Formula | C42H28Cl2N4 |
| Molar Mass | 659.6 |
| Density | 1.24±0.1 g/cm3(Predicted) |
| Melting Point | 194°C |
| Boling Point | 810.3±75.0 °C(Predicted) |
| Flash Point | 443.9°C |
| Vapor Presure | 0-0Pa at 20-25℃ |
| Appearance | Solid:crystalline |
| Color | Light yellow to Yellow to Green |
| pKa | 3.37±0.10(Predicted) |
| Storage Condition | Room Temprature |
| Refractive Index | 1.675 |
| MDL | MFCD00060081 |
7189-82-4 - Risk and Safety
| HS Code | 29339900 |
7189-82-4 - Reference Information
| LogP | 7.6 at 35℃ and pH9 |
| EPA chemical substance information | information provided by: ofmpeb.epa.gov (external link) |
| Application | hexaaryl biimidazoles are a class of organic compounds (abbreviated as ABI), typically hexaphenyl biimidazoles. 2,2 '-bis (2-chlorophenyl)-4,4'5,5'-tetraphenyl-1, 2 '-bis-imidazole is The photoinitiator O-chlorohexaaryl bis-imidazole (BCIM), the existing synthesis method is to use sodium hypochlorite as the oxidation condensation agent for the synthesis of BCIM, which brings more alkaline "wastewater" with low yield and high cost. |
| preparation | A preparation method of diimidazole photoinitiator, the specific steps are as follows:(1) add 30% ml of water or the previous batch of reaction mother liquor and 50g of 1 ml liquid alkali into a 100 ml glass reaction flask, stir and mix well;(2) add g of BCIM-monomer wet material, stir for 15 minutes, then add 300g of dichloromethane and 6g of dodecyldimethyl benzyl ammonium chloride;(3) Keep the temperature at 20-35 ° C., slowly drop 50g of 30% hydrogen peroxide for 4-6 hours, add it and stir for 60 minutes;(4) sample for liquid chromatography analysis; If the weight percentage of unreacted BCIM-monomer wet material is more than 0.5%, add 30% hydrogen peroxide, the weight is 2 times the weight of the unreacted BCIM-monomer wet material analyzed by liquid chromatography;(5) stirring for 1 hour, repeating the 4th step, until the unreacted BCIM-monomer wet material content is less than 0.5% by weight; (6) the reaction solution is poured into a 1000ml separatory funnel, and allowed to stand for 15 minutes to clarify, and then the aqueous layer is separated;(7) 200ml of water is added to the dichloromethane layer, and after stirring for 5 minutes, (8) separate the washed water layer, add deionized water, stir for 30 minutes, and then stand for 1 hour;(9) Pour the organic layer into a 500ml distillation flask, dichloromethane can be recovered by heating under normal pressure, and the dichloromethane recovered by distillation can be used for the next batch of reaction;(10) add 200ml isopropanol, continue distillation, and stop distillation when the reaction solution becomes turbid;(11) under stirring, add cold water, cool to room temperature, and filter; (12) the filter cake was slightly washed twice with fresh isopropanol;(13) dried in a drying cabinet to give 93-95g of yellow BCIM crystals in 93%-95% yield. |
Company Profile Introduction
Shijiazhuang Jianxin Biotechnology Co., Ltd., located in Xingtang Economic Development Zone, Shijiazhuang City, Hebei Province, is a comprehensive enterprise engaged in the procurement, research and development, production, sales, and import and export trade of functional electrolyte additives, pesticide intermediates, pharmaceutical intermediates, fluorine-containing chemicals, liquid crystal materials, OLED materials, and special functional monomers. It ranks among the top in the domestic and international market share in related fields.
The company has a 400㎡ R&D center, a first-class professional technical team, and is equipped with synthesis equipment and advanced analytical testing instruments that meet different reaction conditions. Through continuous development of more advanced new material processes, the company has production capabilities ranging from gram level to kilogram level laboratories, Chinese style workshops, and ton level production bases, which can achieve industrialization of products with different reaction needs.
Shijiazhuang Jianxin Biotechnology Co., Ltd. has a sound quality inspection institution and quality assurance system. The company always regards quality as life, service as leadership, and reputation as its purpose. We sell our products to China, Europe, the United States, Japan, South Korea and other places at reasonable prices, covering the global electrolyte additive industry, pharmaceutical, pesticide and other industries.
In the future, Jianxin Biotechnology will further strengthen the efficiency of new product research and industrialization, enhance the company's core competitiveness, and strive to build the company into a world advanced chemical material manufacturer.
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