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Postion:Product Catalog >Organic Chemistry>Hydrocarbons and derivatives>Hydrocarbon sulfonate>Benzenesulfonyl chloride
Benzenesulfonyl chloride
  • Benzenesulfonyl chloride

Benzenesulfonyl chloride

Price
Package
Min. Order: 1KG
Supply Ability: 10 MT/ Month
Update Time: 2024-10-22

Product Details

Product Name: Benzenesulfonyl chloride CAS No.: 99-09-9
Min. Order: 1KG Purity: 95%~99.99%
Supply Ability: 10 MT/ Month Release date: 2024/10/22
Heidi 494
Benzenesulfonyl chloride Basic information
Product Name: Benzenesulfonyl chloride
Synonyms: Benzenesulphochloride;BENZENESULFONYL CHLORIDE FOR SYNTHESIS;Benzenesulfonyl chloride for HPLC derivatization;Benzenesulfonyl Chloride , 99.0%(GC&T;Benzene Sulfonyl chloride & derivatives;4-Benzenesulfonic acid chloride;Phenylchloro sulfone;Benzenesulfonyl chloride,96%
CAS: 98-09-9
MF: C6H5ClO2S
MW: 176.62
EINECS: 202-636-6
Product Categories: Building Blocks;Chemical Synthesis;Organic Building Blocks;Sulfonyl Halides;Sulfur Compounds;Sulfonyl Halides;Sulfonyl HalidesDerivatization Reagents;Derivatization Reagents HPLC;Organic Building Blocks;Sulfur Compounds;UV-VIS;A-B, Puriss p.a.;Analytical Reagents for General Use;Puriss p.a.;Pharmaceutical Intermediates;Organics
Mol File: 98-09-9.mol
Article illustration
 
Benzenesulfonyl chloride Chemical Properties
Melting point  14.5 °C
Boiling point  251-252 °C(lit.)
density  1.384 g/mL at 25 °C(lit.)
vapor pressure  0.04 mm Hg ( 20 °C)
refractive index  n20/D 1.551(lit.)
Fp  >230 °F
storage temp.  2-8°C
solubility  alcohol: soluble
form  Liquid
color  Clear
Water Solubility  may decompose
Sensitive  Moisture Sensitive
Merck  14,1072
BRN  606926
Stability: Stable. Incompatible with water, strong oxidizing agents, strong bases, methyl formamide, dimethyl sulfoxide.
CAS DataBase Reference 98-09-9(CAS DataBase Reference)
NIST Chemistry Reference Benzenesulfonyl chloride(98-09-9)
EPA Substance Registry System Benzenesulfonyl chloride (98-09-9)
 
Safety Information
Hazard Codes  C
Risk Statements  20/22-34-42/43-29-22
Safety Statements  23-26-36/37/39-45
RIDADR  UN 2225 8/PG 3
WGK Germany  1
RTECS  DB8750000
21
TSCA  Yes
HazardClass  8
PackingGroup  III
HS Code  29049090
Hazardous Substances Data 98-09-9(Hazardous Substances Data)
Toxicity LD50 orl-rat: 1960 mg/kg MEPAAX 20,513,69
MSDS Information
Provider Language
SigmaAldrich English
ACROS English
ALFA English
 
Benzenesulfonyl chloride Usage And Synthesis
Chemical Properties colourless oily liquid
Chemical Properties Benzenesulfonyl chloride is a colorless oily liquid with a pungent odor.
Uses Intermediates of Liquid Crystals
General Description A colorless to slightly yellow solid that melts at approximately 40°F. Very irritating to skin, eyes and mucous membranes. May emit toxic fumes when heated to high temperatures. Used to make dyes and other chemicals.
Air & Water Reactions Insoluble and stable in cold water [Merck]. Decomposes in hot water to produce corrosive and toxic hydrochloric acid and benzenesulfonic acid. Rate of reaction decreases as temperature decreases.
Reactivity Profile Benzenesulfonyl chloride is incompatible with strong oxidizing agents and bases, including amines. Corrodes metals in the presence of water due to slow formation of hydrochloric acid and benzenesulfonic acid [USCG, 1999]. May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291].
Health Hazard May be fatal if inhaled, swallowed or absorbed through skin. Contact may cause skin and eye burns. Irritating to eyes, skin and mucous membranes. INGESTION: May cause abdominal spasm and vomiting.
Safety Profile Poison by intraperitoneal route. Adangerous storage hazard. It may explode in a sealedbottle. Explosive reaction with dimethyl sulfoxide. Reactsvigorously with methyl formamide. When heated todecomposition it emits toxic fumes of Cl- and SO
Potential Exposure It is used as a chemical intermediate for benzenesulfonamides, thiophenol, glybuzole (hypoglycemic agent), N-2-chloroehtylamides, benzonitrile; for its esters-useful as insecticides, and miticides.
Shipping UN2225 Benzene sulfonyl chloride, Hazard class: 8; Labels: 8—Corrosive material.
Purification Methods Distil the sulfonyl chloride, then treat it with 3mole % each of toluene and AlCl3, and allow it to stand overnight. The sulfonyl chloride is distilled off at 1mm pressure and then carefully fractionally distilled at 10mm in an all-glass column. [Adams & Marvel Org Synth Coll Vol I 84 1941, Jensen & Brown J Am Chem Soc 80 4042 1958, Beilstein 11 IV 49.] It is TOXIC.
Incompatibilities Violent reaction with strong oxidizers, dimethyl sulfoxide, and methyl formamide. It is very reactive with bases and many organic compounds. Incompatible with ammonia, aliphatic amines. Water contact forms hydrochloric and chlorosulfonic acids. Aqueous solutions of this chemical are strong acids that react violently with bases. Attacks metals in presence of moisture.
 

Company Profile Introduction

Technology research and transfer of pilot screening, pilot scale-up and mass production solutions , for pharmaceutical intermediates, biologicals and fine chemicals (Not including inflammable , explosive , hazardous goods ) ; Market : Nano material , metal catalyst , raw material of cosmetics , pharmaceutical intermediates , chemicals , photoelectric material , import and export of technology and goods (For projects subject to approval according to law, business activities can be carried out only after approval by relevant departments ).

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  • Since: 2020-12-17
  • Address: Room 702, Floor 7, Building 10, National University Science Park, High-Tech Zone, Zhengzhou City, He
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