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| | Monoperoxyphthalic acid magnesium salt hexahydrate Basic information |
| | Monoperoxyphthalic acid magnesium salt hexahydrate Chemical Properties |
| Melting point | 93 °C (dec.)(lit.) | | storage temp. | Sealed in dry,Room Temperature | | solubility | DMSO, Methanol | | form | Solid | | color | White to Off-White | | InChIKey | WWOYCMCZTZTIGU-UHFFFAOYSA-L | | CAS DataBase Reference | 84665-66-7(CAS DataBase Reference) |
| Hazard Codes | O,Xi | | Risk Statements | 8-36/37/38 | | Safety Statements | 26 | | WGK Germany | 3 | | HS Code | 29173990 |
| | Monoperoxyphthalic acid magnesium salt hexahydrate Usage And Synthesis |
| Chemical Properties | White Granules | | Uses | Reagent for:
- Trans-diaxial hydroxylation under bismuth(III) triflate catalyst
- Oxidation rections under mild conditions
- Epoxidation of unsaturated steroids
- Synthesis of ring-B oxygenated steroids as anticancer agents
| | Uses | Monoperoxyphthalic acid magnesium salt hexahydrate is used as disinfectant for hard surfaces (hospital, food industrial, institution). | | General Description | Magnesium monoperoxyphthalate hexahydrate is an organic peroxide used in many oxidation reactions. It exhibits non-deflagrating and non-shock-sensitive properties and also used as a surface disinfectant. | | Purification Methods | MMPP is a safer reagent than m-chloroperbenzoic acid for oxidation reactions because it is not as explosive and has advantages of solubility. It is soluble in H2O, low-molecular-weight alcohols, i-PrOH and DMF. The product of reaction, Mg phthalate, is soluble in H2O. It has been used in aqueous phase to oxidise compounds in e.g. CHCl3 and using a phase transfer catalyst, e.g. methyltrioctylammonium chloride [Brougham Synthesis 1015 1987]. The oxidising activity can be checked (as for perbenzoic acid in Silbert et al. Org Synth Coll Vol V 906 1973], and if found to be low it would be best to prepare afresh from phthalic anhydride (1mol), H2O2 (1mol) and MgO at 20-25o to give MMPP. [Hignett, European Pat Appl 27 693 1981, Chem Abstr 95 168810 1981, Beilstein 9 IV 3260.] |
| | Monoperoxyphthalic acid magnesium salt hexahydrate Preparation Products And Raw materials |
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