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| | 2,2-Bis[4-(4-aminophenoxy)phenyl]propane Basic information |
| Product Name: | 2,2-Bis[4-(4-aminophenoxy)phenyl]propane | | Synonyms: | 4,4'-((Propane-2,2-diylbis(4,1-phenylene))bis(oxy))dianiline;2,2'-Di-[4-(4-aminophenyloxy)phenyl]-propane;4,4'-(4,4'-Isopropyl;2,2-Bis[4-(4-aminophenoxy)phenyl]propan;2,2-Bis[p-(4-aMinophenoxy)phenyl]propane;4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldioxy)dianiline 98%;4,4'-(4,4'-isopropylidenediphenyl-1,1'-diyldioxy),BAPP;4,4’-((1-methylethylidene)bis(4,1-phenyleneoxy)bis-benzenamin | | CAS: | 13080-86-9 | | MF: | C27H26N2O2 | | MW: | 410.51 | | EINECS: | 235-985-8 | | Product Categories: | fine chemicals, specialty chemicals, intermediates, electronic chemical, organic synthesis, functional materials;API;fine chemicals, specialty chemicals, intermediates, electronic chemical, organic synthesis;Organics;Miscellaneous;Bisphenol A type Compounds (for High-Performance Polymer Research);Functional Materials;Reagent for High-Performance Polymer Research;13080-86-9 | | Mol File: | 13080-86-9.mol | ![2,2-Bis[4-(4-aminophenoxy)phenyl]propane Structure](CAS/GIF/13080-86-9.gif) |
| | 2,2-Bis[4-(4-aminophenoxy)phenyl]propane Chemical Properties |
| Melting point | 127-130 °C(lit.) | | Boiling point | 587.1±50.0 °C(Predicted) | | density | 1.178±0.06 g/cm3(Predicted) | | vapor pressure | 0-0Pa at 20-25℃ | | storage temp. | Keep in dark place,Inert atmosphere,Room temperature | | form | Solid:particulate/powder | | pka | 5.16±0.10(Predicted) | | Water Solubility | Very slightly soluble in water. Soluble in acetone, Dimethyl sulfoxide(DMSO). | | InChI | InChI=1S/C27H26N2O2/c1-27(2,19-3-11-23(12-4-19)30-25-15-7-21(28)8-16-25)20-5-13-24(14-6-20)31-26-17-9-22(29)10-18-26/h3-18H,28-29H2,1-2H3 | | InChIKey | KMKWGXGSGPYISJ-UHFFFAOYSA-N | | SMILES | C(C1=CC=C(OC2=CC=C(N)C=C2)C=C1)(C1=CC=C(OC2=CC=C(N)C=C2)C=C1)(C)C | | LogP | 4.3-4.9 at 35℃ and pH7 | | CAS DataBase Reference | 13080-86-9(CAS DataBase Reference) | | EPA Substance Registry System | Benzenamine, 4,4'-[(1-methylethylidene)bis(4,1-phenyleneoxy)]bis- (13080-86-9) |
| Hazard Codes | Xn,Xi | | Risk Statements | 22-36/37/38 | | Safety Statements | 26-36 | | WGK Germany | 3 | | RTECS | CY1062500 | | TSCA | Yes | | HS Code | 29222990 |
| | 2,2-Bis[4-(4-aminophenoxy)phenyl]propane Usage And Synthesis |
| Description | 2,2-Bis[4-(4-aminophenoxy)phenyl]propane (BAPP), also known as 4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldioxy)dianiline, is a diamino monomer with a diphenoxy-phenyl core. Since the molecule has two amine groups at both ends, it can be cross-linked with carboxylic acids or carboxylic dianhydrides to synthesize polyimides. It is commonly as a monomer for the preparation of polyimides in application of batteries, fuel cells, low dielectric materials and OLEDs. | | Chemical Properties | 4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldioxy)dianiline (2,2-Bis[4-(4-aminophenoxy)phenyl]propane) is white solid | | Uses | 4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldioxy)dianiline is used for preparation polyimide and epoxy resin material. | | Uses | It is applied in pharmaceutical industry. | | Application | 2,2-Bis[4-(4-aminophenoxy)phenyl] propane (BAPP) can be used for:
(1) Preparation of polyimides. The glass transition temperature of this new polyimide is about 225-230°C. It has the typical yield of thermoplastic polymers. It has a typical thermoplastic polymer yield behaviour, which is very different from other polyimides. The elongation at break was 6% and 29% for polyamide and polyimide, respectively.
(2) Curing epoxy resin (ER) and poly(?-caprolactone) (PCL) for the preparation of crystalline thermoset blends.
(3) Constructing dental resin composites. | | Synthesis | 2,2‐Bis[4‐(4‐aminophenoxy)phenyl] propane (BAPP), as a monomer to prepare polyimide, was synthesized from Bisphenol A and p‐chloronitrobenzene via the nucleophilic substitution reaction[1]. | | References | [1] CUILI KONG. Synthesis, Structures and Properties of Polyimide Based on 2,2′‐Bis(4‐aminophenoxy phenyl) Propane[J]. Journal of Macromolecular Science, Part A, 2006. DOI:10.1080/10601320600941086. |
| | 2,2-Bis[4-(4-aminophenoxy)phenyl]propane Preparation Products And Raw materials |
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