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ChemicalBook >> CAS DataBase List >> Chromyl chloride

Chromyl chloride

Chromyl chloride price.
  • $56 - $1170.67
  • Product name: Chromyl chloride
  • CAS: 14977-61-8
  • MF: Cl2CrO2
  • MW: 154.9
  • EINECS:239-056-8
  • MDL Number:MFCD00010951
  • Synonyms:dichlorodioxo-chromiu ;Dichlorodioxochromium;Dioxodichlorochromium;dioxodichlorochromium[qr] ;Oxychlorure chromique;oxychlorurechromique ;oxychlorurechromique(french)[qr] ;Chromylchlorideredliq
7 prices
Selected condition：
Brand
  • Alfa Aesar
  • American Custom Chemicals Corporation
  • Sigma-Aldrich
  • Strem Chemicals
  • TRC
Package
  • 2.5g
  • 5g
  • 10g
  • 25g
  • 50g
  • ManufacturerAlfa Aesar
  • Product number040517
  • Product descriptionChromyl chloride, 99.99% (metals basis)
  • Packaging10g
  • Price$103.65
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product number040517
  • Product descriptionChromyl chloride, 99.99% (metals basis)
  • Packaging50g
  • Price$464.65
  • Updated2024-03-01
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0002747
  • Product descriptionCHROMYL CHLORIDE 95.00%
  • Packaging10G
  • Price$1170.67
  • Updated2021-12-16
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  • ManufacturerSigma-Aldrich
  • Product number200042
  • Product descriptionChromyl chloride ≥99.99% trace metals basis
  • Packaging10g
  • Price$101
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number93-2409
  • Product descriptionChromyl chloride, 99.5%
  • Packaging5g
  • Price$56
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number93-2409
  • Product descriptionChromyl chloride, 99.5%
  • Packaging25g
  • Price$223
  • Updated2024-03-01
  • Buy
  • ManufacturerTRC
  • Product numberC433140
  • Product descriptionChromyl chloride
  • Packaging2.5g
  • Price$85
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Alfa Aesar 040517 Chromyl chloride, 99.99% (metals basis) 10g $103.65 2024-03-01 Buy
Alfa Aesar 040517 Chromyl chloride, 99.99% (metals basis) 50g $464.65 2024-03-01 Buy
American Custom Chemicals Corporation ING0002747 CHROMYL CHLORIDE 95.00% 10G $1170.67 2021-12-16 Buy
Sigma-Aldrich 200042 Chromyl chloride ≥99.99% trace metals basis 10g $101 2024-03-01 Buy
Strem Chemicals 93-2409 Chromyl chloride, 99.5% 5g $56 2024-03-01 Buy
Strem Chemicals 93-2409 Chromyl chloride, 99.5% 25g $223 2024-03-01 Buy
TRC C433140 Chromyl chloride 2.5g $85 2021-12-16 Buy

Properties

Melting point :-96.5 °C (lit.)
Boiling point :117 °C (lit.)
Density :1.911 g/mL at 25 °C (lit.)
Flash point :117°C
solubility :reacts with H2O; soluble in ctc, chloroform,benzene
form :liquid
Specific Gravity :1.911
color :red
Water Solubility :Soluble in carbon tetrachloride, carbon disulfide, benzene, nitrobenzene, chloroform, and POCL3. Insoluble in water(Reacts).
Sensitive :Moisture Sensitive
Merck :14,2248
Exposure limits :ACGIH: TWA 0.0001 ppm; STEL 0.00025 ppm (Skin)
NIOSH: TWA 0.0002 mg/m3 Dielectric constant :2.6（20℃）
CAS DataBase Reference :14977-61-8(CAS DataBase Reference)
EPA Substance Registry System :Chromium(VI) dioxychloride (14977-61-8)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H271 May cause fire or explosion; strong oxidiser Oxidising liquids;Oxidising solids Category 1 Danger GHS hazard pictograms P210, P220, P221, P280, P283,P306+P360, P371+P380+P375,P370+P378, P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H317 May cause an allergic skin reaction Sensitisation, Skin Category 1 Warning GHS hazard pictograms P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H340 May cause genetic defects Germ cell mutagenicity Category 1A, 1B Danger GHS hazard pictograms
H350 May cause cancer Carcinogenicity Category 1A, 1B Danger GHS hazard pictograms
H410 Very toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 1 Warning GHS hazard pictograms P273, P391, P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Highly spin-polarized chromium dioxide (CrO2) thin films were deposited on 100 TiO2 substrates by chemical vapor deposition using chromyl chloride as a precursor. Chromyl chloride (Cr02C12) reacts with cyclohexane solvent at 75 OC to give a dark precipitate along with chlorocyclohexane and a small amount of cyclohexene (in 10.0 and ca. 0.3% yields based on chromium). Chromyl chloride, CrO2C12, oxidizes cyclooctane, isobutane, and toluene under mild conditions (25-60" C). The reactions give chlorinated products (chlorocyclooctane, tert- butyl chloride, and benzyl chloride) and a dark chromium-containing precipitate. Used for Organic oxidations and chlorination, chromium coordination complexes, catalyst for polymerization of olefins. Chromyl chloride in carbon tetrachloride solution reacts in the cold with cyclohexene, cyclopentene, and 1-hexene to give the various isomeric chlorohydrins as the major products.

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