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    ChemicalBook >> CAS DataBase List >> BrettPhos Pd G3

    BrettPhos Pd G3

    BrettPhos Pd G3 price.
    • $13 - $1945
    • Product name: BrettPhos Pd G3
    • CAS: 1470372-59-8
    • MF: C48H66NO5PPdS
    • MW: 906.51
    • EINECS:
    • MDL Number:MFCD22572666
    • Synonyms:Methanesulfonato2-Dicyclohexylphosphino-3,6-dimethoxy-2'-4' -6'-tri-i-propyl-1,1'-bipheny)(2'-amino-1,1'-biphenyl-2-yl)palladium(II);BrettPhos Pd G3 95%;[2'-(Amino)[1,1'-biphenyl]-2-yl][dicyclohexyl[3,6-dimethoxy-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine](methanesulfonato)palladium;Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladiu;[2'-(Amino-κN)[1,1'-biphenyl]-2-yl-κC][dicyclohexyl[3,6-dimethoxy-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine-κP](methanesulfonato-κO)palladium;Methanesulfonato(2-dicyclohexylphosphino-3,6-diMethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II), Min. 98% [BrettPhos Palladacycle];Methanesulfonato(2-dicyclohexylphosphino-3,6-diMethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II), Min. 98%;BrettPhos Pd G3
    34 prices
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    Brand
    • AK Scientific
    • Alfa Aesar
    • Ambeed
    • Apolloscientific
    • Arctom
    • Chemenu
    • Crysdot
    • Sigma-Aldrich
    • Strem Chemicals
    Package
    • 100mg
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    • 500mg
    • 1g
    • 2g
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    • 25g
    • ManufacturerAK Scientific
    • Product number0516AQ
    • Product descriptionBrettPhos Pd G3
    • Packaging250mg
    • Price$139
    • Updated2021-12-16
    • Buy
    • ManufacturerAlfa Aesar
    • Product number047250
    • Product descriptionBrettPhos Palladacycle 3rd Generation, 98%
    • Packaging5g
    • Price$1470.65
    • Updated2024-03-01
    • Buy
    • ManufacturerAlfa Aesar
    • Product number047250
    • Product descriptionBrettPhos Palladacycle 3rd Generation, 98%
    • Packaging1g
    • Price$460
    • Updated2024-03-01
    • Buy
    • ManufacturerAlfa Aesar
    • Product number047250
    • Product descriptionBrettPhos Palladacycle 3rd Generation, 98%
    • Packaging250mg
    • Price$122
    • Updated2024-03-01
    • Buy
    • ManufacturerAmbeed
    • Product numberA1194516
    • Product description[(2-Di-cyclohexylphosphino-3,6-dimethoxy-2′,4′,6′-triisopropyl-1,1′-biphenyl)-2-(2′-amino-1,1′-biphenyl)]palladium(II)methanesulfonate 98+%
    • Packaging100mg
    • Price$13
    • Updated2021-12-16
    • Buy
    • ManufacturerAmbeed
    • Product numberA1194516
    • Product description[(2-Di-cyclohexylphosphino-3,6-dimethoxy-2′,4′,6′-triisopropyl-1,1′-biphenyl)-2-(2′-amino-1,1′-biphenyl)]palladium(II)methanesulfonate 98+%
    • Packaging250mg
    • Price$23
    • Updated2021-12-16
    • Buy
    • ManufacturerAmbeed
    • Product numberA1194516
    • Product description[(2-Di-cyclohexylphosphino-3,6-dimethoxy-2′,4′,6′-triisopropyl-1,1′-biphenyl)-2-(2′-amino-1,1′-biphenyl)]palladium(II)methanesulfonate 98+%
    • Packaging1g
    • Price$75
    • Updated2021-12-16
    • Buy
    • ManufacturerAmbeed
    • Product numberA1194516
    • Product description[(2-Di-cyclohexylphosphino-3,6-dimethoxy-2′,4′,6′-triisopropyl-1,1′-biphenyl)-2-(2′-amino-1,1′-biphenyl)]palladium(II)methanesulfonate 98+%
    • Packaging5g
    • Price$330
    • Updated2021-12-16
    • Buy
    • ManufacturerAmbeed
    • Product numberA1194516
    • Product description[(2-Di-cyclohexylphosphino-3,6-dimethoxy-2′,4′,6′-triisopropyl-1,1′-biphenyl)-2-(2′-amino-1,1′-biphenyl)]palladium(II)methanesulfonate 98+%
    • Packaging10g
    • Price$592
    • Updated2021-12-16
    • Buy
    • ManufacturerAmbeed
    • Product numberA1194516
    • Product description[(2-Di-cyclohexylphosphino-3,6-dimethoxy-2′,4′,6′-triisopropyl-1,1′-biphenyl)-2-(2′-amino-1,1′-biphenyl)]palladium(II)methanesulfonate 98+%
    • Packaging25g
    • Price$1306
    • Updated2021-12-16
    • Buy
    • ManufacturerApolloscientific
    • Product numberOR939181
    • Product descriptionBrettPhos Pd G3 98%
    • Packaging250mg
    • Price$61
    • Updated2021-12-16
    • Buy
    • ManufacturerApolloscientific
    • Product numberOR939181
    • Product descriptionBrettPhos Pd G3 98%
    • Packaging1g
    • Price$196
    • Updated2021-12-16
    • Buy
    • ManufacturerApolloscientific
    • Product numberOR939181
    • Product descriptionBrettPhos Pd G3 98%
    • Packaging5g
    • Price$538
    • Updated2021-12-16
    • Buy
    • ManufacturerArctom
    • Product numberSY073041
    • Product descriptionMethanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2’,4’,6’-tri-i-propyl-1,1’-biphenyl)(2’-amino-1,1’-biphenyl-2-yl)palladium(II) ≥98%
    • Packaging250mg
    • Price$55
    • Updated2021-12-16
    • Buy
    • ManufacturerArctom
    • Product numberSY073041
    • Product descriptionMethanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2’,4’,6’-tri-i-propyl-1,1’-biphenyl)(2’-amino-1,1’-biphenyl-2-yl)palladium(II) ≥98%
    • Packaging1g
    • Price$135
    • Updated2021-12-16
    • Buy
    • ManufacturerArctom
    • Product numberSY073041
    • Product descriptionMethanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2’,4’,6’-tri-i-propyl-1,1’-biphenyl)(2’-amino-1,1’-biphenyl-2-yl)palladium(II) ≥98%
    • Packaging5g
    • Price$480
    • Updated2021-12-16
    • Buy
    Manufacturer Product number Product description Packaging Price Updated Buy
    AK Scientific 0516AQ BrettPhos Pd G3 250mg $139 2021-12-16 Buy
    Alfa Aesar 047250 BrettPhos Palladacycle 3rd Generation, 98% 5g $1470.65 2024-03-01 Buy
    Alfa Aesar 047250 BrettPhos Palladacycle 3rd Generation, 98% 1g $460 2024-03-01 Buy
    Alfa Aesar 047250 BrettPhos Palladacycle 3rd Generation, 98% 250mg $122 2024-03-01 Buy
    Ambeed A1194516 [(2-Di-cyclohexylphosphino-3,6-dimethoxy-2′,4′,6′-triisopropyl-1,1′-biphenyl)-2-(2′-amino-1,1′-biphenyl)]palladium(II)methanesulfonate 98+% 100mg $13 2021-12-16 Buy
    Ambeed A1194516 [(2-Di-cyclohexylphosphino-3,6-dimethoxy-2′,4′,6′-triisopropyl-1,1′-biphenyl)-2-(2′-amino-1,1′-biphenyl)]palladium(II)methanesulfonate 98+% 250mg $23 2021-12-16 Buy
    Ambeed A1194516 [(2-Di-cyclohexylphosphino-3,6-dimethoxy-2′,4′,6′-triisopropyl-1,1′-biphenyl)-2-(2′-amino-1,1′-biphenyl)]palladium(II)methanesulfonate 98+% 1g $75 2021-12-16 Buy
    Ambeed A1194516 [(2-Di-cyclohexylphosphino-3,6-dimethoxy-2′,4′,6′-triisopropyl-1,1′-biphenyl)-2-(2′-amino-1,1′-biphenyl)]palladium(II)methanesulfonate 98+% 5g $330 2021-12-16 Buy
    Ambeed A1194516 [(2-Di-cyclohexylphosphino-3,6-dimethoxy-2′,4′,6′-triisopropyl-1,1′-biphenyl)-2-(2′-amino-1,1′-biphenyl)]palladium(II)methanesulfonate 98+% 10g $592 2021-12-16 Buy
    Ambeed A1194516 [(2-Di-cyclohexylphosphino-3,6-dimethoxy-2′,4′,6′-triisopropyl-1,1′-biphenyl)-2-(2′-amino-1,1′-biphenyl)]palladium(II)methanesulfonate 98+% 25g $1306 2021-12-16 Buy
    Apolloscientific OR939181 BrettPhos Pd G3 98% 250mg $61 2021-12-16 Buy
    Apolloscientific OR939181 BrettPhos Pd G3 98% 1g $196 2021-12-16 Buy
    Apolloscientific OR939181 BrettPhos Pd G3 98% 5g $538 2021-12-16 Buy
    Arctom SY073041 Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2’,4’,6’-tri-i-propyl-1,1’-biphenyl)(2’-amino-1,1’-biphenyl-2-yl)palladium(II) ≥98% 250mg $55 2021-12-16 Buy
    Arctom SY073041 Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2’,4’,6’-tri-i-propyl-1,1’-biphenyl)(2’-amino-1,1’-biphenyl-2-yl)palladium(II) ≥98% 1g $135 2021-12-16 Buy
    Arctom SY073041 Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2’,4’,6’-tri-i-propyl-1,1’-biphenyl)(2’-amino-1,1’-biphenyl-2-yl)palladium(II) ≥98% 5g $480 2021-12-16 Buy

    Properties

    Melting point :150-193°C (decomposition)
    storage temp. :under inert gas (nitrogen or Argon) at 2–8 °C
    form :Powder
    color :yellow to beige
    InChIKey :ASZHREKEHVNFFW-UHFFFAOYSA-N
    SMILES :P(C1CCCCC1)(C1CCCCC1)(C1C(=CC=C(OC)C=1C1C(=CC(C(C)C)=CC=1C(C)C)C(C)C)OC)[Pd+2]1(NC2=CC=CC=C2C2=CC=CC=[C-]12)[O-]S(=O)(=O)C

    Safety Information

    Symbol(GHS): GHS hazard pictograms
    Signal word: Warning
    Hazard statements:
    Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
    H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
    H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
    H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
    Precautionary statements:
    P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
    P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
    P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
    P405 Store locked up.

    Description

    BrettPhos Pd G3 may be used for the C-N coupling reaction between monosubstituted ureas and 1,2 dihaloaromatic system to form benzimidazolones.
    It may be used in the synthesis of following compounds:
    • [Pd(cinnamyl)(BrettPhos)]OTf by reacting with [(cinnamyl)PdCl]2 and AgOTf.
    • [Pd(crotyl)(BrettPhos)]OTf by reacting with [(crotyl)PdCl]2 and AgOTf.
    • [Pd(allyl)(BrettPhos)]OTf by reacting with [(allyl)PdCl]2 and AgOTf.
    • Pd(allyl)(BrettPhos)Cl by reacting with [(allyl)PdCl]2.

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