五硫化リン 化學(xué)特性,用途語,生産方法
特徴
P4S10分子
説明
Phosphorus pentasulfide, is a nonmetallic inorganic compound . It is a yellow to greenish-yellow crystalline mass with an odor similar to hydrogen sulfide. It is a dangerous fire risk and ignites by friction or in contact with water. Boiling point is 995°F (535°C) and ignition temperature is 287°F (141°C). It decomposes upon contact with water or moist air, liberating toxic and flammable hydrogen-sulfide gas. Specific gravity is 2.09, so it is heavier than water. It is toxic by inhalation, with a TLV of 1 mg/m3 of air. The four-digit UN identification number is 1340. The NFPA 704 designation is health 2, flammability 1, and reactivity 2. Primary uses are in insecticides, safety matches, ignition compounds, and sulfonation.
化學(xué)的特性
Phosphorus pentasulfide is a greenish-gray to yellow, crystalline solid with an odor of rotten eggs. The Odor Threshold is 0.005 ppm.
使用
Phosphorus pentasulfide is used in the manufacture of lubricant additives, pesticides, safety matches, and flotation agents.
一般的な説明
A greenish yellow solid with an odor of rotten eggs that may paralyze the sense of smell at hazardous concentrations in air. Density 2.04 g / cm3. Phosphorus pentasulfide is used for making lube oil additives, insecticides, flotation agents, safety matches, blown asphalt, and other products and chemicals.
空気と水の反応
Highly flammable. May heat and spontaneously ignite in presence of moisture [Haz. Chem. Data. 1969]. Reaction with water forms toxic hydrogen sulfide gas and phosphoric acid. Dangerous when wet.
反応プロフィール
PHOSPHORUS PENTASULFIDE reacts vigorously with strong oxidants. Exothermically violent decomposition reaction with water, steam or acids to produce irritating fumes of phosphorus pentaoxide and highly toxic hydrogen sulfide gas. May ignite in contact with limited amounts of water [Haz. Chem. Data, 1975, p. 239]. Can be ignited by sparks or friction and its dust presents an explosion hazard in air at sufficient concentrations. Hydrogen sulfide gas evolved from reactions with water may also form explosive mixtures with air.
健康ハザード
Phosphorus pentasulfide is an irritant to the skin and eyes. Inhalation of its vapors can cause irritation of the respiratory passage. Oral toxicity of this compound in rats was found to be moderate.
LD50 value, oral (rats): 389 mg/kg (NIOSH 1986)
Phosphorus pentasulfide can readily produce highly toxic hydrogen sulfide in the presence of moisture. Other toxic products from its combustion are sulfur dioxide and phosphorus pentoxide (corrosive)..
火災(zāi)危険
Special Hazards of Combustion Products: Products of combustion include sulfur dioxide and phosphorus pentoxide, which are irritating, toxic and corrosive.
安全性プロファイル
A poison by ingestion.
A severe eye and skin irritant. Readily
liberates toxic hydrogen sulfide and
phosphorus pentoxide and evolves heat on
contact with moisture. Dangerous fire
hazard in the form of dust when exposed to
heat or flame. Spontaneous heating in the
presence of moisture. Moderate explosion
hazard in solid form by spontaneous
chemical reaction. Reacts with water, steam,
or acids to produce toxic and flammable
vapors; can react vigorously with oxidizing
materials. Incompatible with air, alcohols,
water. To fight fire, use CO2snow, dry
chemical, or sand. Used as an intermedate
in manufacturing lubricant addltives,
insecticides, and fertilizer agents. When
heated to decomposition it emits highly
toxic fumes of SO, and PO,. See also
HYDROGEN SULFIDE.
職業(yè)ばく露
Phosphorus pentasulfide is used as an intermediate in the manufacture of lubricant additives; insecticides, flotation agents; lubricating oil; ignition compounds; and matches. It is also used to introduce sulfur into rubber, and organic chemicals, such as pharmaceuticals.
輸送方法
UN1340 Phosphorus pentasulfate, free from yellow or white phosphorus, Hazard Class: 4.3; Labels: 4.3-Dangerous when wet material, 4.1-flammable solid.
純化方法
Purify P2S5 by extraction and crystallisation with CS2, using a Soxhlet extractor, and is heated in a CO2 atmosphere at 150o to remove solvent. It liberates H2S in moist air. HARMFUL VAPOURS. [Klements in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol I p 568 1963.]
不和合性
Flammable solid; dust may form explosive mixture with air. Contact with water forms phosphorus pentoxide and an explosive mixture of hydrogen sulfide with air. Phosphorus pentasulfide is incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, ammonia, strong acids, strong bases, alcohols. Reaction with water or moisture in the air releases heat, hydrogen sulfide (H2S), sulfur dioxide, and phosphoric acid. Pyrophoric hazard, may self-ignite in moist air.
廃棄物の処理
Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal. Decompose with water, forming phosphoric acid, sulfuric acid and hydrogen sulfide. Provisions must be made for scrubbing hydrogen sulfide emissions. The acids may then be neutralized and diluted slowly to solution of soda ash and slaked lime with stirring, then flush to sewer with large volumes of water.
參考文獻(xiàn)
A. Vos, et al., Acta Crystallogr., 19, 864 (1965), DOI: 10.1107/S0365110X65004516.
五硫化リン 上流と下流の製品情報
原材料
準(zhǔn)備製品
クロロチオりん酸ジメチル
1,3-ジヒドロ-7-クロロ-5-フェニル-2H-1,4-ベンゾジアゼピン-2-チオン
4-SULFANYLNICOTINIC ACID
チオりん酸O,O-ジメチルO-(2-クロロ-4-ニトロフェニル)
Dimethylphenyl dithiophosphate,sodium salt
6-メルカプトプリン
(2-(トリフルオロメチル)チアゾール-5-イル)メタノール
トルレスタット
ジチオりん酸O,O-ジエチルS-[(4-クロロフェニルチオ)メチル]
2,4-ジメチルチアゾール
ジチオりん酸O,O-ジエチルS-(6-クロロ-2-オキソベンゾオキサゾール-3(2H)-イル)メチル
α,β-ジチオ二りん酸Oα,Oα,Oβ,Oβ-テトラエチル
チオりん酸ジエチル4-ニトロフェニル
5,6-ジアミノピリミジン-4(1H)-チオン
3-メチル-2-ベンゾチアゾリノンヒドラゾン塩酸塩一水和物
チオ酢酸
ホスホロジチオ酸O-エチルO-[4-(メチルチオ)フェニル]S-プロピル
6-(METHYLTHIO)PYRIMIDINE-4,5-DIAMINE
ヘプタメチレンイミン
2,5-ジメチルチオフェン
クアゼパム
ホスメット
4-ヒドロキシベンゾニトリル
2-メチルチアゾリン
O，O-dialkyl thiophosphoryl chloride
6-メルカプトプリン 水和物
チオりん酸O,O-ジメチルO-[p-シアノフェニル]
チオアセトアミド
Malathion emulsifiable concentrate
ローソン試薬
ジチオりん酸 O,O-ジエチル
チオりん酸O,O-ジメチルO-(3,5,6-トリクロロ-2-ピリジニル)
6-メトキシ-2-メチルベンゾチアゾール
5-フルオロ-2-メチルベンゾチアゾール
Antioxidant and antiseptic agent T202
ジチオりん酸水素O,O-ジメチル
ジチオりん酸O-(2,4-ジクロロフェニル)O-エチルS-プロピル
フルフリルメルカプタン
ブロチゾラム
7-(トリフルオロメチル)-4-キノリンチオール