(1R,2S)-2-(3,4-difluorophenyl)cyclopropanamine hydrochloride

1156491-10-9

CAS番號.: 1156491-10-9

化學名:

別名:

英語名:: (1R,2S)-2-(3,4-difluorophenyl)cyclopropanamine hydrochloride

英語別名:: (1S,2R)-2-(3,4-difluorophenyl)cyclopropanaMine;(1R,2S)-rel-2-(3,4-Difluorophenyl)cyclopropanamine hydrochloride;(1R,2S)-2-(3,4-difluorophenyl)cyclopropanaMine Hydrochloride(1:1);(1R trans)-2-(3,4-difluorophenyl)cyclopropane aMine hydrochloride;Ticagrelor USP RC A;Ticagrelor side chain 2 hydrochloride;2-(3,4-Difluoro-phenyl)-cyclopropylamine;(1R,2S)-rel-2-(3,4- Difluorophenyl)cyclo;(1R,2S)-rel-2-(3,4-Difluorophenyl)cyclopropanami;(1R,2S)-2-(3,4-Difluorophenyl)cyclopropanamine HCl

CBNumber:: CB22498775

化學式:: C9H10ClF2N

分子量:: 205.63

MOL File:: 1156491-10-9.mol

物理性質(zhì)

安全性情報

価格5

用途語

生産企業(yè) 265

(1R,2S)-2-(3,4-difluorophenyl)cyclopropanamine hydrochloride 物理性質(zhì)

融點 :: >172°C (dec.)

貯蔵溫度 :: Inert atmosphere,Store in freezer, under -20°C

溶解性:: DMSO（微量）、メタノール（微量）

外見 :: 個體

色:: 白い

InChI:: InChI=1/C9H9F2N.ClH/c10-7-2-1-5(3-8(7)11)6-4-9(6)12;/h1-3,6,9H,4,12H2;1H/t6-,9+;/s3

InChIKey:: IMYLOCHFFLYHPS-RHUSADAZNA-N

SMILES:: N[C@@H]1C[C@H]1C1C=CC(F)=C(F)C=1.Cl |&1:1,3,r|

安全性情報

リスクと安全性に関する聲明
危険有害性情報のコード(GHS)

絵表示（GHS）

注意喚起語

警告

危険有害性情報

コード	危険有害性情報	危険有害性クラス	區(qū)分	注意喚起語	P コード
H302	飲み込むと有害	急性毒性、経口	4	警告	P264, P270, P301+P312, P330, P501
H315	皮膚刺激	皮膚腐食性/刺激性	2	警告	P264, P280, P302+P352, P321,P332+P313, P362
H319	強い眼刺激	眼に対する重篤な損傷性/眼刺激性	2A	警告	P264, P280, P305+P351+P338,P337+P313P
H335	呼吸器への刺激のおそれ	特定標的臓器毒性、単回暴露；気道刺激性	3	警告

注意書き

P261	粉じん/煙/ガス/ミスト/蒸気/スプレーの吸入を避けること。
P305+P351+P338	眼に入った場合：水で數(shù)分間注意深く洗うこと。次にコンタクトレンズを著用していて容易に外せる場合は外すこと。その後も洗浄を続けること。

(1R,2S)-2-(3,4-difluorophenyl)cyclopropanamine hydrochloride 価格もっと(5)

メーカー	製品番號	製品説明	CAS番號	包裝	価格	更新時間	購入
富士フイルム和光純薬株式會社(wako)	W01COBQH-7456	(1R,2S)-Rel-2-(3,4-difluorophenyl)cyclopropanamine hydrochloride	1156491-10-9	25g	￥44000	2024-03-01	購入
富士フイルム和光純薬株式會社(wako)	W01COBQH-7456	(1R,2S)-Rel-2-(3,4-difluorophenyl)cyclopropanamine hydrochloride	1156491-10-9	100mg	￥104400	2018-12-26	購入
富士フイルム和光純薬株式會社(wako)	W01COBQH-7456	(1R,2S)-Rel-2-(3,4-difluorophenyl)cyclopropanamine hydrochloride	1156491-10-9	250mg	￥147600	2018-12-26	購入
富士フイルム和光純薬株式會社(wako)	W01COBQH-7456	(1R,2S)-Rel-2-(3,4-difluorophenyl)cyclopropanamine hydrochloride	1156491-10-9	1g	￥10000	2024-03-01	購入
富士フイルム和光純薬株式會社(wako)	W01COBQH-7456	(1R,2S)-Rel-2-(3,4-difluorophenyl)cyclopropanamine hydrochloride	1156491-10-9	5g	￥19500	2024-03-01	購入

(1R,2S)-2-(3,4-difluorophenyl)cyclopropanamine hydrochloride 化學特性,用途語,生産方法

合成

1,2-Difluorobenzene is reacted with 3-chloropropionyl chloride to produce 3-chloro-1-(3',4'-difluorophenyl)-propan-1-one, which is by addition of N,N-dimethylformamide, phloroglucinol and sodium iodide in the next step converted to 1-(3',4'-difluorophenyl)-3-nitro-propan-1-one. The keto group of the latter intermediate is in the subsequent step stereochemically reduced to hydroxyl group by the use of chiral oxazaborolidine together with borane dimethyl sulfide or borane-N,N-diethyl aniline complex in the presence of tetrahydrofurane. The obtained (1R)-1-(3',4'-difluorophenyl)-3-nitro-propan-1-ol is then added to a mixture of triphenylphosphine and diethylazodicarboxylate in benzene to yield (1S,2R)-2-(3',4'-difluorophenyl)-1-nitrocyclopropane, which is in the last step converted to 2-(3,4-difluorophenyl)cyclopropane amine by reduction of the nitro group by catalytic hydrogenation with palladium catalyst and zink dust.

(1R,2S)-2-(3,4-difluorophenyl)cyclopropanamine hydrochloride 上流と下流の製品情報

原材料

準備製品

(1R,2S)-2-(3,4-difluorophenyl)cyclopropanamine hydrochloride 生産企業(yè)

Global( 265)Suppliers

名前	電話番號	電子メール	國籍	製品カタログ	優(yōu)位度
Shanghai Safer Pharmaceutical Technology Co., Ltd.	021-31761238	sales@saferph.com	CHINA	897	58
Shanghai Jinli Pharmaceutical Co.,Ltd	+86-21-57256005 +86-15921811235	chang@shjlchem.com	China	20	58
Hebei Yanxi Chemical Co., Ltd.	+8617531153977	allison@yan-xi.com	China	5855	58
Henan Fengda Chemical Co., Ltd	+86-371-86557731 +86-13613820652	info@fdachem.com	China	20262	58
hebei hongtan Biotechnology Co., Ltd	+86-86-1913198-3935 +8617331935328	sales03@chemcn.cn	China	970	58
HEBEI BRANT PHARMACEUTICAL CO.,LTD	+86-311-84455288 +86-18832137600	rice@brantpharm.com	China	17	58
Shanghai Daken Advanced Materials Co.,Ltd	+86-371-66670886	info@dakenam.com	China	18949	58
Nanjing Gold Pharmaceutical Technology Co. Ltd.	025-84209270 15906146951		CHINA	115	55
Beijing Cooperate Pharmaceutical Co.,Ltd	010-60279497	sales01@cooperate-pharm.com	CHINA	1803	55
Hi-Tech Chemistry Corp	0519-86626038	yuhh@hitechem.com	CHINA	810	58

1156491-10-9()キーワード:

カナグリフロジン 4-[(4-メチル-1-ピペラジニル)メチル]安息香酸二塩酸塩 1-[2-アミノ-1-(4-メトキシフェニル)エチル]シクロヘキサノール塩酸塩チカグレロル (2R,3R,4S,5R)-2,3,4,5-テトラヒドロキシヘキサン二酸2-(((3AR,4S,6R,6AS)-6-アミノ-2,2-ジメチルテトラヒドロ-3AH-シクロペンタ[D]-[1,3]ジオキソール-4-イル)オキシ)エタノール 5-アミノ-4,6-ジクロロ-2-(プロピルチオ)ピリミジン 4,6-ジクロロ-5-ニトロ-2-(プロピルチオ)ピリミジン (3AR,4S,6R,6AS)-6-アミノ-2,2-ジメチルテトラヒドロ-3AH-シクロペンタ[D][1,3]ジオキソール-4-オール (2R)-ヒドロキシ(フェニル)エタン酸(1R,2S)-2-(3,4-ジフルオロフェニル)シクロプロパンアミン 2-[[(3AR,4S,6R,6AS)-6-アミノテトラヒドロ-2,2-ジメチル-4H-シクロペンタ-1,3-ジオキソール-4-イル]オキシ]エタノール (1R,2S)-2-(3,4-ジフルオロフェニル)シクロプロパンアミン塩酸塩 (1R,2S)-2-(3,4-ジフルオロフェニル)シクロプロパンアミン (2R,3R)-2,3-ジヒドロキシこはく酸(1R,2S)-2-(3,4-ジフルオロフェニル)シクロプロパンアミン

1156491-10-9
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(1R,2S)-rel-2-(3,4-Difluorophenyl)cyclopropanamine HCl
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