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ChemicalBook >> CAS DataBase List >>Irganox 3052

Irganox 3052

CAS No.
61167-58-6
Chemical Name:
Irganox 3052
Synonyms
AN GM;At 3052;HS 3052;AO-3052;JADEADD GM;JADEWIN GM;Sumilizer GM;IRGANOX 3052;antioxygenGM;PowerNox 3052
CBNumber:
CB6254573
Molecular Formula:
C26H34O3
Molecular Weight:
394.55
MDL Number:
MFCD28047606
MOL File:
61167-58-6.mol
Last updated:2024-09-25 08:53:54

Irganox 3052 Properties

Melting point 128-133°C
Boiling point 491℃
Density 1.03
Flash point 185℃
storage temp. -20°C Freezer, Under inert atmosphere
solubility Chloroform (Slightly), Ethyl Acetate (Slightly)
pka 11.66±0.48(Predicted)
form Solid
color White to Off-White
Water Solubility 123ng/L at 20℃
Indirect Additives used in Food Contact Substances 2,2'-METHYLENEBIS(4-METHYL-6-TERT-BUTYLPHENOL) MONOACRYLATE
FDA UNII 5FAC6GZ50W
EPA Substance Registry System 2-tert-Butyl-6-(3-tert-butyl-2-hydroxy-5-methylbenzyl)-4-methylphenyl acrylate (61167-58-6)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H317
Precautionary statements  P261-P272-P280-P302+P352-P333+P313-P321-P363-P501

Irganox 3052 price

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TRC I764150 Irganox3052 61167-58-6 500mg $285 2021-12-16 Buy
TRC I764150 Irganox3052 61167-58-6 1g $550 2021-12-16 Buy
American Custom Chemicals Corporation CHM1031222 IRGANOX 3052 95.00% 61167-58-6 5MG $503.64 2021-12-16 Buy
Product number Packaging Price Buy
I764150 500mg $285 Buy
I764150 1g $550 Buy
CHM1031222 5MG $503.64 Buy

Irganox 3052 Chemical Properties,Uses,Production

Performance

2,2′-methylenebis(6-tert-butyl-4-methylphenol) monoacrylate, (also known under the trade names Sumilizer GM, BNX 3052, and Irganox 3052), is a heat and light stabilizer and an antioxidant used in a wide range of adhesive, plastic, and elastomer materials. Unlike traditional phenolic stabilizers/antioxidants, this substance is an effective alkyl radical scavenger. This property is especially useful in processes at high temperatures and in low oxygen environments, such as during the initial mixing of adhesives.
The stabilizing mechanism involves trapping of polymer alkyl radicals at the double bond of the acrylate group, and subsequent hydrogen transfer from the intramolecular hydrogen-bonded phenolic hydroxyl group, which results in a stable phenoxyl radical. 2,2′-methylenebis(6-tert-butyl-4-methylphenol) monoacrylate may also be grafted using the acrylate moeity.

Description

Irganox 3052 is an antioxidant. It contains 2-(1,1-dimethylethyl)-6-[[3-(1,1-dimethylethyl)-2-hydroxy-5-methylphenylymethyl-4-methylphenyl acrylate. It is non-staining, non-discoloring, has a low volatility and is resistant to extraction. It protects organic substrates against both, thermo-oxidative and purely thermal degradation. It is particularly active under high processing temperature and anaerobic polymerization and processing conditions. It is compatible with HIPS, ABS, BR, IIR, SBR, SBS, SEBS, EPDM, EPM, MBS, MABS, SMA, modified acrylate, hydrocarbon resins, terpene, terpene phenolic resins, rosin, polycarbonates, polyester-carbonates, polymethacrylates, polyolefins, polyamides or polyphenyleneoxides. Irganox 3052 is suitable for food contact applications. It is listed in AICS, EINECS, PICCS, DSL, MITI, TSCA, CHINA and ECL.

Uses

Irganox 3052 has been used in to study the mechanical properties and performance of stretch films of plasticized PVC and non-PVC alternatives used for retail fresh meat packaging; heat stabilizers for butadiene-styrene copolymers;

Flammability and Explosibility

Not classified

Synthesis

To a 2-liter four-necked flask equipped with a thermometer, stirring apparatus, condenser and dropping funnel were added 340.51 g (1.0 mol) of 2,2'-methylenebis(6-tert-butyl-4-methylphenol), 72.06 g (1.0 mol) of acrylic acid, 500 g of toluene and 209.47 g (2.07 mol) of triethylamine. After replacing the air in the container with nitrogen, 105.8 g (0.69 mol) of phosphorus oxychloride was added dropwise with stirring. After completion of the dropwise addition, the reaction solution was kept at 80 ℃. for 1 hour. After that, the organic layer was washed with water until it became neutral, and toluene was removed under reduced pressure. The residue was then recrystallized from n-hexane to obtain 374.8 g of a white crystalline 2,2'-methylenebis(6-tert-butyl-4-methylphenol) monoacrylate (Irganox 3052) having a melting point of 132 to 134 ℃. Yield, 95%.

119-47-1
814-68-6
61167-58-6
Synthesis of Irganox 3052 from 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) and Acryloyl chloride

Irganox 3052 Preparation Products And Raw materials

Global( 103)Suppliers
Supplier Tel Email Country ProdList Advantage
Jiangxi Lotchem Co.,Ltd.
+8615270827708 lancetu@jxlotchem.com CHINA 338 58
Qingdao Truelight functional Material Technology Co., Ltd.
+86-13573844393 songjames@truelightchem.com China 221 58
Hebei Mojin Biotechnology Co., Ltd 		+86 13288715578 +8613288715578 sales@hbmojin.com China 12825 58
Dalian Richfortune Chemicals Co., Ltd 		0411-84820922 8613904096939 sales@richfortunechem.com China 304 57
Henan Tianfu Chemical Co.,Ltd. 		+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21639 55
Hangzhou FandaChem Co.,Ltd. 		008657128800458; +8615858145714 fandachem@gmail.com China 9218 55
Tianjin Zhongxin Chemtech Co., Ltd. 		+86-022-66880623 +8618622897568 sales@tjzxchem.com China 563 58
career henan chemical co 		+86-0371-86658258 +8613203830695 sales@coreychem.com China 29886 58
Hebei Weibang Biotechnology Co., Ltd 		+8615531157085 abby@weibangbio.com China 8816 58
Hubei xin bonus chemical co. LTD 		86-13657291602 linda@hubeijusheng.com CHINA 22963 58

View Lastest Price from Irganox 3052 manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Antioxidant 3052 pictures 2024-10-31 Antioxidant 3052
61167-58-6
 US $0.00 / Kg/Drum 1KG 98%min 1000kg WUHAN FORTUNA CHEMICAL CO., LTD
ANTIOXIDANT TRUELICHT GM pictures 2024-10-21 ANTIOXIDANT TRUELICHT GM
61167-58-6
 US $0.00 / KG 1drums 98.0% 20 tons Qingdao Truelight functional Material Technology Co., Ltd.
antioxidant GM pictures 2024-09-20 antioxidant GM
61167-58-6
 US $0.00 / KG 25KG 98% 20 tons QINGDAO JADE NEW MATERIAL TECNOLOGY CO.,LTD
  • Antioxidant 3052 pictures
  • Antioxidant 3052
    61167-58-6
  • US $0.00 / Kg/Drum
  • 98%min
  • WUHAN FORTUNA CHEMICAL CO., LTD
  • antioxidant GM pictures
  • antioxidant GM
    61167-58-6
  • US $0.00 / KG
  • 98%
  • QINGDAO JADE NEW MATERIAL TECNOLOGY CO.,LTD
2,2’-methylenebis(4-methyl-6-tert-butylphenol)monoacrylate 2-Propenoicacid,2-(1,1-dimethylethyl)-6-[[3-(1,1-dimethylethyl)-2-hydroxy-5-methylphenyl]methyl]-4-methylphenylester 2-tert-Butyl-6-(3-tert-butyl-2-hydroxy-5-methylbenzyl)-4-methylphenylacrylate 2-(1,1-dimethylethyl)-6-[[3-(1,1-dimethylethyl)-2-hydroxy-5-methylphenyl]methyl]-4-methylphenyl acrylate 2-Propenoic acid, 2-(1,1-dimethylethyl)-6-[[3-(1,1-dimethylethyl)-2-hydroxy-5-methylphenyl]methyl]-4-methylphenyl ester 2,2''-Methylenebis-(6-tert-butyl-p-cresol) monoacrylate Acrylic acid 2-(2-hydroxy-3-tert-butyl-5-methylbenzyl)-4-methyl-6-tert-butylphenyl ester Acrylic acid 2-tert-butyl-4-methyl-6-(2-hydroxy-3-tert-butyl-5-methylbenzyl)phenyl ester Acrylic acid 2-tert-butyl-6-(3-tert-butyl-2-hydroxy-5-methylbenzyl)-4-methylphenyl ester Acrylic acid 2-tert-butyl-6-[(3-tert-butyl-2-hydroxy-5-methylphenyl)methyl]-4-methylphenyl ester Sumilizer GM At 3052 2-(1,1-Dimethylethyl)-6-((3-(1,1-dimethylethyl)-2-hydroxy-5-methylphenyl)methyl)-4-methylphenyl acrylate Einecs 262-634-6 2-(2-Hydroxy-3-tert-butyl-5-methylbenzyl)-4-methyl-6-tert-butylphenyl acrylate IRGANOX 3052 Antioxidant 3052 2-Tert-butyl-6-(3-tert-butyl-2-hydroxy-5-methylphenyl)methyl-4-methylp-henyl acrylate Antioxidatant 3052 PowerNox 3052 HS 3052 AN GM antioxidant GM antioxygenGM 2,2'-Methylenebis(6-tert-butyl-4-methylphenol) Monoacrylate IRGANOX 3052 ISO 9001：2015 REACH ANTIOXIDANT TRUELICHT GM JADEADD GM JADEWIN GM 2-(1,1-dimethylethyl)-6-[[3-(1,1-dimethylethyl)-2-hydroxy-5-... AO-3052 Antioxidant AO-3052 Sinanox? 3052 / IRGANOX 3052 / 4-methylphenyl Acrylate / Antioxidant 3052 2-(1,1-Dimethylethyl)-6-[[3-(1,1-dimethylethyl)-2-hydroxy-5-methylphenyl]methyl]-4-methylphenylacrylat 61167-58-6