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ChemicalBook >> CAS DataBase List >>[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)

CAS No.
72287-26-4
Chemical Name:
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
Synonyms
PDCL2(DPPF);(dppf)2PdCl2;dichloropalladiuM;1,1-BIS(DIPHENYLPHOSPHINO)FERROCENEDICHLOROPALLADIUM(II);Palladium(II) chloride-1,1’-bis(diphenylphosphino)ferrocene,complex with CH2Cl2;oropaL;[1,1′(DPPF)PdCl2;JACS-72287-26-4;CHEMWISH IC30255
CBNumber:
CB3276259
Molecular Formula:
C34H28Cl2FeP2Pd
Molecular Weight:
731.7
MDL Number:
MFCD00015757
MOL File:
72287-26-4.mol
Last updated:2025-02-07 17:39:05

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Properties

Melting point 275-280 °C(lit.)
storage temp. Keep in dark place,Inert atmosphere,Room temperature
solubility Soluble in dichloromethane.
form powder
color red to very dark red
Stability Hygroscopic
InChI InChI=1S/2C17H11P.2ClH.Fe.Pd/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;;;;/h2*1-6,9-12,18H;2*1H;;/q;;;;+2;/p-2
InChIKey LMSWLYFMTLONFK-UHFFFAOYSA-L
SMILES [Cl-][Pd+2]1(P(C2C=CC=CC=2)(C2C=CC=CC=2)[C-]23C4=C5C6=C2[Fe+2]27893456C3C2=C7[C-]8(C9=3)P1(C1C=CC=CC=1)C1C=CC=CC=1)[Cl-]
UNSPSC Code 12352103
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P280a-P304+P340-P305+P351+P338-P405-P501a
Hazard Codes  Xn,Xi
Risk Statements  20/21/22-36/37/38-40
Safety Statements  23-24/25-26-36/37
WGK Germany  3
TSCA  No
HazardClass  IRRITANT
HS Code  28439000

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) price More Price(37)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 697230 [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) 72287-26-4 1g $74.3 2024-03-01 Buy
Sigma-Aldrich 697230 [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) 72287-26-4 5g $227 2024-03-01 Buy
Alfa Aesar 046503 Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II), Pd 13.5-15.5% 72287-26-4 1g $72.5 2023-06-20 Buy
Sigma-Aldrich 697230 [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) 72287-26-4 250g $9580 2024-03-01 Buy
TRC B430465 [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) 72287-26-4 1g $100 2021-12-16 Buy
Product number Packaging Price Buy
697230 1g $74.3 Buy
697230 5g $227 Buy
046503 1g $72.5 Buy
697230 250g $9580 Buy
B430465 1g $100 Buy

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Chemical Properties,Uses,Production

Uses

[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II), is a palladium catalyst used in chemical synthesis of various compounds. Is used in preparation of Nucleosides as Ectonucleotidase inhibitors.

Chemical Properties

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) is Red solid

Uses

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) is used as a catalyst for Suzuki and Stile couplings.

Uses

suzuki reaction

Uses

Catalyst for C-C and C-N coupling reaction.

Application

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) may be used as an effective palladium catalyst in the following reactions:
Cross-coupling of sec-alkyl and n-alkyl Grignard reagents with high yield and selectivity.
Suzuki coupling of aryl boronic esters with [11C]methyl iodide to form functionalized [11C]toluene derivatives.
Kumada cross-coupling of 1,3,5-tribromobenzene with Grignard reagents to form star-shaped oligothiophenes.

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

Mechanism of action

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) (pd(dppf)cl2) catalysis has gained widespread use in industrial and academic synthetic chemistry laboratories as a powerful methodology for the formation of C-C and C-Heteroatom bonds.
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) uses
R = usually sp2 hybridised carbon
X = usually I, Br, Cl or OTf
The nature of R' and M are dependant upon
the specic coupling being performed

12150-46-8
90243-59-7
72287-26-4
Synthesis of [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) from 1,1'-Bis(diphenylphosphino)ferrocene and Palladium, bis(acetonitrile)dichloro-, (SP-4-2)-
Global( 511)Suppliers
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Wuhan Huahan Dingcheng New Material Technology Co., Ltd
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INNOBIO PHARM CO.,LTD
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View Lastest Price from [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) pictures 2025-02-27 [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
72287-26-4
 US $100.00 / kg 1kg 99% 50000KG/month Hebei Mujin Biotechnology Co.,Ltd
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) pictures 2025-02-20 [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
72287-26-4
 US $30.00-9.00 / kg 1kg 0.99 15 tons Hebei Yanxi Chemical Co., Ltd.
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) pictures 2025-02-19 [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
72287-26-4
 US $10.00 / KG 100KG 99% 100 mt Hebei Weibang Biotechnology Co., Ltd
1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENEDICHLOROPALLADIUM(II) 1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE PALLADIUM DICHLORIDE 1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENEPALLADIUM(II) DICHLORIDE Dichloro(1,1'-bis(diphenylphosphino)ferrocene)palladium (II) dichloromethane add 1,1'-Bis(diphenylphosphino)ferroceneüpalladium(II) chloride, 1:1 complex with dichloromethane [bis(diphenylphosphino)ferrocene]PdCl2/ dichloromethane 1,1'-Bis(diphenylphosphino)ferrocene palladium dichloride ,99% [1,1'-Bis(diphenylphosphino)ferrocene]dichloropall 1,1'-Bis(diphenylphosphino)ferrocene-palladium dichloride,98% 1,1'-Bis(diphenylphosphino)ferrocene palladium(II)dichloride [Pd(dppf)Cl2] Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II) 1'-Bis(diphenylphosphino)ferrocene-palladiuM(II) dichloride 1,1'-Bis(diphenylphosphino)ferrocene palladium dichloride ,99.9% [1,1′-Bis(diphenylph [1,1'-Bis(Diphenylphosphino)Ferrocene]Dichloropalladium dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(ii) dichloromethane complex (1:1) -Bis(diphenylphosphino)ferrocene]dichloropalladium(II) 1,1-BIS(DIPHENYLPHOSPHINO)FERROCENEDICHLOROPALLADIUM(II): 99.9% (II)dichloromethane adduct 1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) complex with dichloromethane Palladium, 1,1-bis(diphenylphosphino-.kappa.P)ferrocenedichloro-, (SP-4-2)- [1,1'-bis(diphenylphosphino)ferrocene]dichloropalladium(ii) dichloromethane complex (1:1) [1,1'-bis(diphenylphosphino)ferrocene]palladium(ii) dichloride dichloromethane complex (1:1) (1,1'-Bis(diphenylphosphimoferrocene)dichloropalladium (II)-CH2CL2 [1,1-BIS(DIPHENYLPHOSPHINO)FERROCENE]DICHLOROPALLADI [1,1''-Bis-(diphenylphosphino)-ferrocene]-palladous dichloride [1,1''-Bis(diphenyphosphino)ferrocene]dichloropalladium(II) [1,1’-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) PdCl2(dppf) 1,1''-BIS(DIPHENYLPHOSPHINO)FERROCENE]DICHLOROPALLADIUM() COMPLEX WITH DICHLOROMETHANE (1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE)-P ALLADIUM(II) CHLORIDE CH2CL2 COMPL DICHLORO-((BIS-DIPHENYLPHOSPHINO)FERROCENYL)-PALLADIUM(II) 1,1'-Bis(diphenylphosphino)ferrocenepalladiuM( II) dichloride Pd DICHLORO-((BIS-DIPHENYLPHOSPHINO)FERROCENYL)-PALLADIUM(II) DICHLOROMETHANE ADDUCT [1,1'-Bis(diphenylphosphino)ferrocen]dichloropalladiuM(II), coMplex with dichloroMethane -Bis(diphenylphosphino)ferrocene-palladiuM(II)dichloride dichloroMethane coMplex 1,1'-Bis(diphenylphosphiNA)ferrocene palladiuM(II)dichloride Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladiuM(II), (DPPF)PdCl2 [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(Ⅱ) [1,1'-Bis(diphenylphosphino)ferrocene]Pd(II)Cl2 CHEMWISH IC30255 JACS-72287-26-4 1,1'-Bis(diphenylphosphino)ferrocene palladiuM(II)dichlorid (Diphenylphosphino)Ferrocene PalladiuM Dichlorid 1,1'-BIS(DIPHENYLPHOSPHINO) 1,1'-BIS(DIPHENYLPHOSP [1,1&prime 1'1-Bis(diphenylphosphino)fewocene palladium(Ⅱ)chloride [1,1’-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) (Pd(dppf)Cl2) [1,1'-Bis(diphenyL oropaL phosphino)ferrocene]dichL 1,1 '- bis (diphenylphosphino) ferrocene palladium dichloride (II) 1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)，Pd 14.5% Diphenylphosphinoferrocene dichloropalladium 1’1-Bis(diphenylphosphino)fewocene Palladium(Ⅱ)chloride [1,1 '- bis (diphenylphosphonyl) ferrocene] palladium dichloride [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Basic information 1,1'-Bis(diphenylphosphino)ferrocene - dichloropalladium (1:1)