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ChemicalBook--->CAS DataBase List--->944451-26-7

944451-26-7

944451-26-7 Structure

944451-26-7 Structure
IdentificationBack Directory
[Name]

Chloro[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl](p-cymene)ruthenium (II)chloride [RuCl(p-cymene)((R)-H8-binap)]Cl
[CAS]

944451-26-7
[Synonyms]

Chloro[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl](p-cymene)r
[(R)-(+)-2,2'-Bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl](p-cymene)ruthenium(II) dichloride
Chloro[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl](p-cymene)ruthenium (II)chloride [RuCl(p-cymene)((R)-H8-binap)]Cl
[Molecular Formula]

C54H54Cl2P2Ru
[MDL Number]

MFCD09753016
[MOL File]

944451-26-7.mol
[Molecular Weight]

936.93
Chemical PropertiesBack Directory
[Melting point ]

>100°C
[storage temp. ]

2-8°C
[form ]

Powder
[color ]

pale yellow
[Sensitive ]

air sensitive
Safety DataBack Directory
[WGK Germany ]

3
Questions And AnswerBack Directory
[Reaction]

  1. Biaryl bisphosphine ligand. The H8-BINAP ligand, as the ruthenium complex, catalyzes hydrogenation of unsaturated carboxylic acids to a higher ee than does BINAP.
  2. The ruthenium catalyzed hydrogenation of aryl propenoic acid to produce the drug Ibuprofen.
Reactions of 944451-26-7
Hazard InformationBack Directory
[Uses]

Takasago Ligands and Complexes for Asymmetric Reactions
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