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ChemicalBook--->CAS DataBase List--->944450-48-0

944450-48-0

944450-48-0 Structure

944450-48-0 Structure
IdentificationBack Directory
[Name]

Diacetato[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole] ruthenium(II) Ru(OAc)2[(R)-segphos]
[CAS]

944450-48-0
[Synonyms]

(R)-Ru(OAc)2(SEGPHOS)
Diacetato[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole] ruthenium(II) Ru(OAc)2[(R)-segphos] 
Diacetato[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Ru(OAc)2[(R)-segphos(R)]
[Molecular Formula]

C42H34O8P2Ru
[MDL Number]

MFCD09753024
Chemical PropertiesBack Directory
[Melting point ]

>100°C
[storage temp. ]

2-8°C
[form ]

Powder
[color ]

dark yellow
[Sensitive ]

air sensitive
Questions And AnswerBack Directory
[Reaction]

  1. Highly active highly enantioselective catalyst for hydrogenation of functionalized ketones. The acetate salts are frequently used for hydrogenation of allyl alcohols, unsaturated carboxylic acids and reductive amination.
  2. Asymmetric hydrogenation of substituted allyl alcohols.
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