| Identification | Back Directory | [Name]
5-(11bS)-Dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-yl-5H-dibenz[b,f]azepine | [CAS]
942939-38-0 | [Synonyms]
(S)-(+)-N-(3,5-Dioxa-4-phosphacyclohepta[2,1-a
3,4-a']dinaphthalen-4-yl)-5H-dibenz[b,f]azepine
3,4-a']dinaphthalen-4-yl)-5H-dibenz[b,f]azepine,min.97%
3,4-a']dinaphthalen-4-yl)-5H-dibenz[b,f]azepine, min. 97%
3,4-a']dinaphthalen-4-yl)-dibenzo[b,f]azepine >=95% (elemental analysis)
5-(11bS)-Dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-yl-5H-dibenz[b,f]azepine
(S)-(+)-N-(3,5-Dioxa-4-phosphacyclohepta[2,1-a,3,4-a′]dinaphthalen-4-yl)-dibenzo[b,f]azepine
(S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)-5H-dibenz[b,f]azepine, min. 97% | [Molecular Formula]
C34H22NO2P | [MDL Number]
MFCD22666424 | [MOL File]
942939-38-0.mol | [Molecular Weight]
507.53 |
| Chemical Properties | Back Directory | [Melting point ]
246 °C | [Boiling point ]
711.5±63.0 °C(Predicted) | [storage temp. ]
Inert atmosphere,2-8°C | [form ]
solid | [pka]
-2.70±0.20(Predicted) | [color ]
yellow | [Sensitive ]
air sensitive, moisture sensitive |
| Questions And Answer | Back Directory | [Reaction]
- The ligand is used in the stereodivergent α-allylation of linear aldehydes with dual iridium and amine catalysis.
- The ligand used in the direct, enantioselective iridium-catalyzed amination and (thio-) etherification of racemic allylic alcohols.
- The ligand used in an asymmetric, rhodium-catalyzed, intramolecular hydroacylation reaction.
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