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ChemicalBook--->CAS DataBase List--->92361-49-4

92361-49-4

92361-49-4 Structure

92361-49-4 Structure
IdentificationBack Directory
[Name]

PENTAMETHYLCYCLOPENTADIENYLBIS(TRIPHENY&
[CAS]

92361-49-4
[Synonyms]

Cp*RuCl(PPh3)2
phosphine)ruthenium(II) chL
Chloro(pentamethylcyclopentadienyl)
PENTAMETHYLCYCLOPENTADIENYLBIS(TRIPHENY&
Chloro(η5-pentamethylcyclopentadiene)[bis(triphenylphosphine)]ruthenium
Pentamethylcyclopentadienylbis(triphenylphosphine)ruthenium(II) chlorid
Chloro(pentaMethylcyclopentadienyl)bis(triphenylphosphine)rutheniuM(II),99%
Chloro(pentamethylcyclopentadienyl)bis(triphenylphosphine)ruthenium(II),98%
chlororuthenium(1+),1,2,3,4,5-pentamethylcyclopenta-1,3-diene,triphenylphosphane
Ruthenium,chloro[(1,2,3,4,5-h)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]bis(triphenylphosphine)-
[Molecular Formula]

C46H47ClP2Ru
[MDL Number]

MFCD09038426
[MOL File]

92361-49-4.mol
[Molecular Weight]

798.35
Chemical PropertiesBack Directory
[Melting point ]

128 °C (D)
[storage temp. ]

2-8°C
[solubility ]

Soluble in dichloromethane, chloroform, toluene, tetrahydrofuran.
[form ]

Powder
[color ]

orange
[Sensitive ]

Air Sensitive
[Stability:]

store cold
Safety DataBack Directory
[WGK Germany ]

3
Hazard InformationBack Directory
[Uses]

Catalyst employed in the cycloaddtion of azides with acetylenes giving exclusively the 1,5-disubstitutedtriazoles in contrast to the 1,4-regiochemistry commonly observed with copper catalysis. Ruthenium catalysis also enables the use of internal acetylenes in these "click cycloaddtions".
[reaction suitability]

core: ruthenium
reagent type: catalyst
reaction type: click chemistry
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