| Identification | Back Directory | [Name]
Chemical Name：Chloro[1,3-bis(mesityl)imidazole-2-ylidene]gold(I) | [CAS]
852445-81-9 | [Synonyms]
IMesAuCl
Chloro[1,3-bis(mesityl)imidazole-2-ylidene]gold(I)
Chloro(1,3-dimesityl-1H-imidazol-2(3H)-ylidene)aurate(I)
Chemical Name：Chloro[1,3-bis(mesityl)imidazole-2-ylidene]gold(I)
Chloro[1,3-bis(2,4,6-trimethylphenyl)2H-imidazol-2-ylidene]gold(I), 98% | [Molecular Formula]
C21H24AuClN2 | [MDL Number]
MFCD11656059 | [MOL File]
852445-81-9.mol | [Molecular Weight]
536.848 |
| Hazard Information | Back Directory | [Description]
Chloro[1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene]gold(I), also known as [(IMes)AuCl], is an useful organometallic catalyst. Organometallics are useful reagents, catalysts, and precursor materials with applications in thin film deposition, industrial chemistry, pharmaceuticals, LED manufacturing, and others.
| [Chemical Properties]
White powder | [Uses]
| [Preparation]
Ag2O (0.5 mmol) was added to the CH2Cl2 solution of 1,3-bis(mesityl)imidazolium chloride (1mmol). After stirring at room temperature for 3 hours, the suspension becomes clear. Then drop 1mmol of Me2SAuCl solution into CH2Cl2 and stir for 4 hours. After the mixture is filtered through Celite, the solvent is evaporated. Hexane is added to the remaining mixture and filtered to obtain Chloro[1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene]gold(I).![Chemical Name：Chloro[1,3-bis(mesityl)imidazole-2-ylidene]gold(I)](/NewsImg/2023-10-09/6383245566383785326572571.jpg "Chemical Name：Chloro[1,3-bis(mesityl)imidazole-2-ylidene]gold(I)") | [reaction suitability]
core: gold
reagent type: catalyst |
| Questions And Answer | Back Directory | [Reaction]
- Catalyst for the rearrangement of alkynyl sulfoxides to benzothiepinones
- Catalyst for the rearrangement of homopropargylic ethers to α,β-unsaturated carbonyl compounds
- Catalyst for oxidative cyclopropanation of N-Allylynamides to 3-aza-bicyclo[3.1.0]-hexan-2-one derivatives
- Catalyst for oxidative rearrangement of homopropargylic ethers to cyclobutanones
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