Identification | Back Directory | [Name]
(+)-1,2-BIS((2S,5S)-2,5-DIPHENYLPHOSPHOLANO)ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE | [CAS]
849950-53-4 | [Synonyms]
(S,S)-Ph-BPE-Rh (+)-1,2-BIS((2S,5S)-2,5-DIPHENYLPHOSPHOLANO)ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE | [Molecular Formula]
C42H48BF4P2Rh | [MDL Number]
MFCD07369038 | [MOL File]
849950-53-4.mol | [Molecular Weight]
804.49 |
Questions And Answer | Back Directory | [Reaction]
- Phenyl-BPE exhibits enhanced activity and selectivity over existing members of the BPE ligand family in rhodium catalysed asymmetric hydrogenation.
- This ligand is highly efficient for the hydrogenation of N-acyl aryl-enamides.
- Molar substrate/catalyst ratios of up to 100,000/1 are achieved with excellent reactivity and enantioselectivity using commercial grade substrates and solvents.
- Ligand in the rhodium-catalyzed asymmetric hydroformylation of olefins.
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