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ChemicalBook--->CAS DataBase List--->76899-34-8

76899-34-8

76899-34-8 Structure

76899-34-8 Structure
IdentificationBack Directory
[Name]

2,2'-BIPYRIDINIUM CHLOROCHROMATE
[CAS]

76899-34-8
[Synonyms]

BPCC
2,2'-Bipyridium Chlorochromate
2,2'-BIPYRIDINIUM CHLOROCHROMATE
2,2'-Dipyridinium chlorochromate
2,2'-Bipyridinium chlorochromate,97%
2,2'-Bipyridinium chlorochromateBPCC
hydrogen chlorotrioxochromate(1-) , compound with 2,2'-bipyridine (1:1)
[EINECS(EC#)]

278-569-1
[Molecular Formula]

C10H9ClCrN2O3
[MDL Number]

MFCD00012806
[MOL File]

76899-34-8.mol
[Molecular Weight]

292.64
Chemical PropertiesBack Directory
[Appearance]

dark brown crystalline powder
[solubility ]

insol dichloromethane; sol acetone.
[color ]

yellow crystalline solid
Hazard InformationBack Directory
[Chemical Properties]

dark brown crystalline powder
[storage]

2,2′-Bipyridinium chlorochromate is an air-stable and nonhygroscopic solid; it can be stored for extended periods protected from light and over calcium chloride. Solvents must be anhydrous and free of reducing impurities. 2,2′-Bipyridinium chlorochromate is reputed to be a toxic agent. The reagent should be handled in a fume hood.
[Purification Methods]

Wash it with cold conc HCl, then H2O (sintered glass funnel) and dry it in a vacuum (CaCl2) to give a free-flowing yellow-brown powder. Store it in the dark. [Guziec & Luzzio Synthesis 691 1980, Chakraborty & Chandrasekaran Synth Commun 10 951 1980.] SUSPECTED CARCINOGEN.
Safety DataBack Directory
[Symbol(GHS) ]


GHS03,GHS08,GHS09,GHS06
[Signal word ]

Danger
[Hazard statements ]

H331-H272-H315-H350-H335-H311-H319-H301-H400
[Precautionary statements ]

P210-P220-P221P280-P370+P378-P501-P264-P280-P302+P352-P321-P332+P313-P362-P264-P280-P305+P351+P338-P337+P313P-P261-P271-P304+P340-P311-P321-P403+P233-P405-P501-P280-P302+P352-P312-P322-P361-P363-P405-P501-P273-P391-P501-P264-P270-P301+P310-P321-P330-P405-P501
[Hazard Codes ]

O,T,N
[Risk Statements ]

45-8-23/24/25-36/37/38-50/53
[Safety Statements ]

53-17-26-36/37/39-45-60-61
[RIDADR ]

UN 1479 5.1/PG 2
[WGK Germany ]

3
[HazardClass ]

5.1
[PackingGroup ]

III
[HS Code ]

29333999
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