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ChemicalBook--->CAS DataBase List--->751-97-3

751-97-3

751-97-3 Structure

751-97-3 Structure
IdentificationBack Directory
[Name]

ROLITETRACYCLINE
[CAS]

751-97-3
[Synonyms]

prm-tc
reverin
sq15,659
bristacin
syntetrex
syntetrin
Syntodecin
Tetraverin
Velacycline
velacicline
superciclin
synotodecin
transcycline
Rolitetracyclin
ROLITETRACYCLINE
HMEYVGGHISAPJR-IAHYZSEUSA-N
Pyrolidinomethyltetracycline
pirrolidinometil-tetraciclina
pyrrolidinomethyl-tetracyclin
pyrrolidino-methyl-tetracycline
n-(pyrrolidinomethyl)tetracycline
Rolitetracycline (Technical Grade)
n-(1-pyrrolidinylmethyl)-tetracycline
N-(pyrrolidin-1-ylmethyl)tetracycline
Rolitetracycline (base and/or unspecified derivatives)
12,12a-pentahydroxy-6-methyl-1,11-dioxo-n-(1-pyrrolidinylmethyl)-1
Abricycline, PyrrolidinylMethyltetracycline, SQ 15659, Transcycline, Velacycline
2-Naphthacenecarboxamide, 4-(dimethylamino)-1,4,4a,5,5a,6,11,12a-octahydro-3,6,10,12,12a-pentahydroxy-6-methyl-1,11-dioxo-N-(1-pyrrolidinylmethyl)-, (4S,4aS,5aS,6S,12aS)-
[EINECS(EC#)]

212-031-9
[Molecular Formula]

C27H33N3O8
[MDL Number]

MFCD00864995
[MOL File]

751-97-3.mol
[Molecular Weight]

527.57
Chemical PropertiesBack Directory
[Melting point ]

163.5°C
[Boiling point ]

608.16°C (rough estimate)
[density ]

1.2902 (rough estimate)
[refractive index ]

1.7120 (estimate)
[storage temp. ]

-20°C Freezer, Under inert atmosphere
[solubility ]

DMSO (Slightly), Methanol (Very Slightly)
[form ]

Solid
[pka]

pKa 7.4 (Uncertain)
[color ]

Very Dark Red to Very Dark Brown
[Water Solubility ]

>20g/L(21 ºC)
Safety DataBack Directory
[Hazard Codes ]

Xn
[Risk Statements ]

22-36/37/38
[Safety Statements ]

26-36
[WGK Germany ]

1
[RTECS ]

QI9150000
Hazard InformationBack Directory
[Uses]

neuromuscular blocker
[Uses]

Rolitetracycline is a tetracycline antibiotic that may be given intravenously or intramuscularly in serious bacterial infections when oral administration is not practicable.
[Uses]

Rolitetracycline, launched in the late 1950s, was the first of the semi-synthetic tetracyclines. Rolitetracycline is formed by a Mannich condensation of formaldehyde and pyrrolidine with tetracycline. Rolitetracycline is a pro-drug of tetracycline, in which the pyrrolidine moiety improves bioavailability compared with tetracycline. Rolitetracycline has broad spectrum Gram positive activity in vivo, but pH instability limits use to parenteral administration. The intrinsic in vitro activity and SARs for this region of the tetracycline molecule have not been extensively investigated.
[Definition]

ChEBI: A derivative of tetracycline in which the amide function is substituted with a pyrrolidinomethyl group.
[Brand name]

Syntetrin (Bristol-Myers Squibb).
[General Description]

Rolitetracycline, N-(pyrrolidinomethyl)tetracycline(Syntetrin), was introduced for use by intramuscular or intravenousinjection. This derivative is made by condensingtetracycline with pyrrolidine and formaldehyde in the presenceof tert-butyl alcohol. It is very soluble in water (1 g dissolvesin about 1 mL) and provides a means of injecting theantibiotic in a small volume of solution. It has been recommendedfor cases when the oral dosage forms are not suitable,but it is no longer widely used.
[Pharmaceutical Applications]

2-N-pyrrolidinomethyl-tetracycline. A semisynthetic derivative of tetracycline supplied as the nitrate sesquihydrate for parenteral use.
It is not absorbed from the gastrointestinal tract. It is highly soluble and therefore can be administered parenterally. Peak plasma concentrations of 4–6 mg/L occur at 0.5–1 h after 350 mg intravenously. The plasma elimination half-life is 5–8 h. About 50% of the dose is excreted in the urine, producing high concentrations.
Intravenous administration is occasionally accompanied by abnormal taste, shivering and rigors, hot flushes, facial reddening, dizziness and, rarely, circulatory collapse. Symptoms of myasthenia gravis have occasionally been exacerbated.
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