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ChemicalBook--->CAS DataBase List--->74289-57-9

74289-57-9

74289-57-9 Structure

74289-57-9 Structure
IdentificationBack Directory
[Name]

BIS(3,5-DIMETHYLPHENYL)CHLOROPHOSPHINE
[CAS]

74289-57-9
[Synonyms]

BIS(3,5-DIMETHYLPHENYL)CHLOROPHOSPHINE
Chlorobis(3,5-dimethylphenyl)phosphine
chloro-bis(3,5-dimethylphenyl)phosphane
Bis(3,5-dimethylphenyl)phosphine chloride
Bis(3,5-dimethylphenyl)chlorophosphine,98%
Bis(3,5-dimethylphenyl)phosphinous chloride
Bis(3,5-dimethylphenyl)chlorophosphine, tech.
Chlorobis(3,5-dimethylphenyl)phosphine, tech. 90%
Phosphinous chloride, P,P-bis(3,5-dimethylphenyl)-
[EINECS(EC#)]

636-136-8
[Molecular Formula]

C16H18ClP
[MDL Number]

MFCD01630841
[MOL File]

74289-57-9.mol
[Molecular Weight]

276.74
Chemical PropertiesBack Directory
[Boiling point ]

115-135 °C(Press: 0.015 Torr)
[density ]

1.102 g/mL at 25 °C
[refractive index ]

n20/D 1.606
[Fp ]

110 °C
[form ]

liquid
[Water Solubility ]

Reacts with water.
[Sensitive ]

Moisture Sensitive
Safety DataBack Directory
[Hazard Codes ]

C
[Risk Statements ]

34
[Safety Statements ]

26-36/37/39-43-45
[RIDADR ]

UN3261
[WGK Germany ]

3
[HazardClass ]

8
[PackingGroup ]

II
Hazard InformationBack Directory
[Uses]

Chlorobis(3,5-dimethylphenyl)phosphine is used in the synthesis of (S)- and (R)-2,2?-Bis[bis(3,5-dimethylphenyl)phosphinoyl]-5,5?,6,6?,7,7?,8,8?-octahydro-1,1?-binaphthyl (Xyl-H 8 -BINAPO).
[reaction suitability]

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
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