| Identification | Back Directory | [Name]
CIS-1,4-HEXADIENE | [CAS]
7318-67-4 | [Synonyms]
Nsc157585
(z)-4-hexadiene
CIS-1,4-HEXADIENE
(z)-1,4-hexadiene
1,4-cis-hexadiene
1,4-hexadiene-cis
1,cis-4-hexadiene
4-Hexadiene,(Z)-1
hexa-1,4cis-diene
(Z)-hexa-1,4-diene
(4Z)-1,4-Hexadiene
1,4-Hexadiene, (Z)-
1,4-Hexadiene, (4Z)-
(Z)-CH2=CHCH2CH=CHCH3
cis-1,4-Hexadiene >=99.0%
CIS-1,4-HEXADIENE ISO 9001：2015 REACH | [EINECS(EC#)]
230-783-6 | [Molecular Formula]
C6H10 | [MDL Number]
MFCD00066517 | [MOL File]
7318-67-4.mol | [Molecular Weight]
82.14 |
| Chemical Properties | Back Directory | [Melting point ]
-94.9°C (estimate) | [Boiling point ]
65-66 °C (lit.) | [density ]
0.707 g/mL at 20 °C (lit.) | [refractive index ]
n20/D 1.415 | [Fp ]
-46 °C | [BRN ]
1839519 | [LogP]
2.910 (est) |
| Hazard Information | Back Directory | [General Description]
cis-1,4-Hexadiene can be synthesized from the cobalt-catalyzed reaction between butadiene and ethylene. The reaction of this hydrocarbon with Fe(CO)5 affords the trans-1,3-hexadiene-iron tricarbonyl complex (I), plus a small amount of the trans,trans-2,4-hexadiene complex(II). Mechanism of the conversion of cis-1,4-hexadiene to trans-2-methyl-1,3-pentadiene, via rearrangement in the presence of a nickel catalyst has been investigated. |
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