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ChemicalBook--->CAS DataBase List--->72-55-9

72-55-9

72-55-9 Structure

72-55-9 Structure
IdentificationBack Directory
[Name]

4,4'-DDE
[CAS]

72-55-9
[Synonyms]

P,P'-DDE
4,4'-DDE
NSC 1153
4,4'-DDEe
DDE(p,p')
NCI-C00555
PARAPARADDE
4,4'-dde solution
p, p’-DDE Standard
p, p'-DDE solution
ddtdehydrochloride
DDT dehydrochloride
p,p'-DDE in Methanol
P,P'-DDE, 100MG, NEAT
2,4'-DDE, 100MG, NEAT
4,4'-DDE, 1000MG, NEAT
p,p'-DDE solution,10ppm
p,p'-DDE Solution, 100ppm
p,p'-DDE solution,1000ppm
p.p'-DDE 100mg [72-55-9]
DICHLORODIPHENYLDICHLOROETHENE
4,4'-DDE, 1X1ML, MEOH, 20UG/ML
4,4'-DDE, 1X10ML, ISO, 200UG/ML
4, 4′-DDE, 100 μg/μL in acetone
4,4' DDE, 1X1ML, MEOH, 5000UG/ML
Dichlorodiphenyldichloroethylene
DI(PARA-CHLOROPHENYL)DICHLOROETHENE
4,4'-DICHLORODIPHENYLDICHLOROETHYLENE
p,p’-dichlorodiphenyldichloroethylene
2,2-bis(p-Chlorophenyl)-1-chloroethene
BIS(4-CHLOROPHENYL)-1,1-DICHLOROETHENE
p,p'-(Dichlorodiphenyl)dichloroethylene
PARAPARADICHLORODIPHENYLDICHLOROETHYLENE
4,4'-DDE PESTANAL, 250 MG (2,2-BIS(4-CHL
2,2-bis(4-chlorophenyl)1,1-dichloroethene
2,2-Bis(4-chlorophenyl)-1,1-dichloroethene
1,1-Dichloro-2,2-bis(p-chlorophenyl)ethene
1,1-dichloro-2,2-bis(4-chlorophenyl)ethene
1,1-BIS(4-CHLOROPHENYL)-2,2-DICHLOROETHENE
1,1-DI(4-CHLOROPHENYL)-2,2-DICHLOROETHYLENE
1,1-dichloro-2,2-bis(4-chorophenyl)ethylene
1,1-Dichloro-2,2-di(p-chlorophenyl)ethylene
bis(chloro-4phenyl)-2,2dichloro-1,1ethylene
p,p'-(Dichlorodiphenyl)-2,2-dichloroethylene
2,2-BIS(4-CHLOROPHENYL)-1,1-DICHLOROETHYLENE
2,2-BIS(P-CHLOROPHENYL)-1,1-DICHLOROETHYLENE
1,1-dichloro-2,2-bis(p-chlorophenyl)-ethylen
1,1-Bis(p-chlorophenyl)-2,2-dichloroethylene
2,2-Dichloro-1,1-bis(4-chlorophenyl)ethylene
1,1’-(dichloroethylidene)bis(4-chlorobenzene)
1,1-DICHLORO-2,2-BIS(P-CHLOROPHENYL)-ETHYLENE
1,1’-dichloroethenylidene)bis(4-chlorobenzene)
1,1’-(dichloroethenylidene)bis(4-chloro-benzen
1,1-Dichloro-2,2-bis(4-chlorophenyl)ethene 99%
1,1’-(dichloroethenylidene)bis(4-chloro-Benzene
1,1’-(dichloroethenylidene)bis(4-chlorobenzene)
1,1'-(Dichloroethenylidene)bis(4-chlorobenzene)
1,1-dichloro-2,2-bis(para-chlorophenyl)ethylene
Ethylene, 1,1-dichloro-2,2-bis(p-chlorophenyl)-
p,p'-DDE [4,4'-Dichlorodiphenyldichloroethylene]
2,2-Bis(4-chlorophenyl)-1,1-dichloroethylene,99%
dde(1,1-dichloro-2,2-bis(p-chlorophenyl)ethylene)
Benzene, 1,1'-(dichloroethenylidene)bis*4-chloro-
Benzene, 1,1'-(dichloroethenylidene)bis[4-chloro-
1,1-Dichloro-2,2-bis(4-chlorophenyl)ethene p,p'-DDE
1,1-dichloro-2,2-bis(4-chlorophenyl)ethene solution
1,1-Dichloro-2,2-bis(4-chlorophenyl)ethene, 4,4μ-DDE
2,2-BIS-(4-CHLOROPHENYL)-1,1-DICHLOROETHYLENE (4,4'-DDE)
1-Chloro-4-[2,2-dichloro-1-(4-chlorophenyl)vinyl]benzene
1,1-Dichloro-2,2-bis(4-chlorophenyl)ethene solution, 4,4μ-DDE solution
[EINECS(EC#)]

200-784-6
[Molecular Formula]

C14H8Cl4
[MDL Number]

MFCD00000837
[MOL File]

72-55-9.mol
[Molecular Weight]

318.03
Chemical PropertiesBack Directory
[Appearance]

white crystalline powder
[Melting point ]

88-90 °C(lit.)
[Boiling point ]

403.45°C (rough estimate)
[density ]

1.3406 (rough estimate)
[vapor pressure ]

13 at 30 °C (Wescott et al., 1981)
[refractive index ]

1.6000 (estimate)
[Fp ]

11 °C
[storage temp. ]

APPROX 4°C
[solubility ]

ethanol: soluble
[form ]

neat
[color ]

White, crystalline, odorless powder
[Stability:]

Stable, but light-sensitive. Incompatible with strong bases, strong oxidizing agents.
[Water Solubility ]

292mg/L(25 ºC)
[BRN ]

1913355
[Henry's Law Constant]

0.33 at 25 °C (gas stripping-GC, Jantunen and Bidleman, 2006)
[EPA Substance Registry System]

Hazard InformationBack Directory
[Chemical Properties]

white crystalline powder
[Definition]

ChEBI: A chlorophenylethylene that is ethylene substituted by two 4-chlorophenyl groups at position 1 and two chlorine atoms at position 2.
[General Description]

White crystalline solid or white powder.
[Air & Water Reactions]

Insoluble in water.
[Reactivity Profile]

4,4'-DDE is sensitive to exposure to light. 4,4'-DDE is incompatible with strong oxidizing agents and strong bases. Oxidation is catalyzed by UV radiation.
[Fire Hazard]

Flash point data for 4,4'-DDE are not available. 4,4'-DDE is probably combustible.
[Uses]

1,1-Dichloro-2,2-bis(4-chlorophenyl)ethane(DDE) has been used to study the ability of Pseudomonas acidovorans M3GY to transform DDE and its unchlorinated analog, 1,1-diphenylethylene (DPE).It has been used to investigate the role of incubation time, solvent type, yeast inoculum growth stage and concentration on the results of yeast assay for estrogenic compounds.
[Uses]

Military product; chemical research. Degradation product of p,p′-DDT.
[Health Hazard]

A derivative of DDT; structurally and toxicproperties are similar to those of DDT;however, the acute effects are somewhatmilder; moderately toxic by ingestion; ateratogenic substance; adequate evidence ofcarcinogenicity in experimental animals
LD50 oral (rat): 880 mg/kg
LD50 oral (mouse): 700 mg/kg.
[Safety Profile]

Suspected carcinogen withexperimental carcinogenic and neoplastigenic data. Poisonby ingestion. Experimental reproductive effects. Mutationdata reported. An insecticide. When heated todecomposition it emits very toxic fumes of Cl-.
[Source]

Agricultural runoff degradation of p,p′-DDT (quoted, Verschueren, 1983).
[Environmental Fate]

Biological. In four successive 7-day incubation periods, p,p′-DDE (5 and 10 mg/L) was recalcitrant to degradation in a settled domestic wastewater inoculum (Tabak et al.,1981).
Photolytic. When an aqueous solution of p,p′-DDE (0.004uM) in natural water samples collected from California and Hawaii was irradiated (maximum λ= 240 nm) for 120 hours, 62% was photooxidized to p,p′-dichlorobenzophenone (Ross and Crosby, 1985).
When p,p′-DDE in water was irradiated at 313 nm, a quantum yield of 0.3 was achieved. A photolysis half-life of 0.9 days in summer and 6.1 days in winter by direct sunlight at 40° latitude was observed. Photolysis products included DDMU (yield 20%), o-chl
When p,p′-DDE in a methanol solvent was photolyzed at 260 nm, a dichloro-benzophenone, a dichlorobiphenyl, DDMU and 3,6-dichlorofluorenone (yield 10%) formed as the major products (Plimmer et al., 1970). Chemical/Physical. May degrade to bis(chlorophenyl)acetic acid (DDA) and hydrochloric acid in water (Verschueren, 1983) or oxidize to p,p′-dichlorobenzophenone using UV light as a catalyst (U.S. Department of Health and Human Services, 1989).
[Purification Methods]

Crystallise DDE from MeOH or EtOH and dry it in vacuo. The purity is checked by TLC. [G.tzi & Stammbach Helv Chim Acta 28 569 1946, Beilstein 5 H 639, 5 III1891.] POSSIBLE CARCINOGEN.
Safety DataBack Directory
[Hazard Codes ]

Xn,N,T,F
[Risk Statements ]

22-40-50/53-52/53-39/23/24/25-23/24/25-11-67-65-38-51/53
[Safety Statements ]

36/37-60-61-45-16-7-62-33-29-9
[RIDADR ]

UN 3077 9/PG 3
[WGK Germany ]

3
[RTECS ]

KV9450000
[HazardClass ]

9
[PackingGroup ]

III
[HS Code ]

29036990
[Hazardous Substances Data]

72-55-9(Hazardous Substances Data)
[Toxicity]

Acute oral LD50 for rats 880 mg/kg (RTECS, 1985).
Spectrum DetailBack Directory
[Spectrum Detail]

4,4'-DDE(72-55-9)MS
4,4'-DDE(72-55-9)1HNMR
4,4'-DDE(72-55-9)13CNMR
4,4'-DDE(72-55-9)IR1
4,4'-DDE(72-55-9)IR2
4,4'-DDE(72-55-9)Raman
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