Identification | Back Directory | [Name]
(S)-TCFP-RH | [CAS]
705945-68-2 | [Synonyms]
(S)-TCFP-RH R[Rh(cod)TCFP]BF4 (S)-[Rh COD TCFP]BF4 (S)-[Rh COD TCFP]BF4, Rh 18.4% (S)-(+)-T-BUTYLMETHYL(DI-T-BUTYLPHOSPHINOMETHYL)PHOSPHINO(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRAFLUOROBORATE R-(tert-Butylmethylphosphino-di-tert-butylphosphinomethane)-eta4-(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate R-(tert-Butylmethylphosphino-di-tert-butylphosphinomethane)-η4-(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
(S)-(+)-t-ButylMethyl(di-t-butylphosphinoMethyl)phosphino(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate,97% (S)-TCFP-Rh (S)-(+)-t-Butylmethyl(di-t-butylphosphinomethyl)phosphino(1,5-cyclooctadiene) rhodium(I) tetrafluoroborate, min. 97% (S)-TCFP-Rh | [Molecular Formula]
C14H32P2.C8H12.BF4.Rh | [MDL Number]
MFCD11973806 | [MOL File]
705945-68-2.mol | [Molecular Weight]
560.251 |
Hazard Information | Back Directory | [Uses]
R-(tert-Butylmethylphosphino-di-tert-butylphosphinomethane)-η4-(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate can be used:
- In the asymmetric reduction of amines, ketones and unsaturated acids.
- As a hydrogenation catalyst in the preparation of diastereomers of trifluorovaline.
- As a catalyst in the olefin asymmetric hydrogenation.
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