Identification | Back Directory | [Name]
tert-Butyl phenyl carbonate | [CAS]
6627-89-0 | [Synonyms]
Einecs 229-601-8 BUTTPARK 52\11-34 t-Butyl phenyl carbonate ert-Butyl phenyl carbonate tart-Butylphenyl carbonate TERT-BUTYL PHENYL CARBONATE (2-tert-butylphenyl) carbonate (tert-Butoxycarbonyloxy)benzene tert-Butyl phenyl carbonate 98% tert-Butyl Phenyl Carbonate > Carbonic acid tert-butylphenyl ester 2-Methyl-2-propanyl phenyl carbonate Carbonicacidtert-butylesterphenylester tert-Butyl phenyl carbonate≥ 98%(HPLC) Carbonic acid O-phenyl O-tert-butyl ester Carbonic acid O-tert-butyl O-phenyl ester Carbonic acid, 1,1-dimethylethyl phenyl ester tert-Butyl phenyl carbonate Carbonic acid tert-butyl phenyl ester | [EINECS(EC#)]
229-601-8 | [Molecular Formula]
C11H14O3 | [MDL Number]
MFCD00008804 | [MOL File]
6627-89-0.mol | [Molecular Weight]
194.23 |
Chemical Properties | Back Directory | [Boiling point ]
83 °C0.6 mm Hg(lit.)
| [density ]
1.05 g/mL at 20 °C(lit.)
| [refractive index ]
n20/D 1.480
| [Fp ]
214 °F
| [storage temp. ]
Inert atmosphere,Room Temperature | [solubility ]
Chloroform (Slightly) | [form ]
Liquid or Low Melting Solid | [color ]
Colorless | [Water Solubility ]
Slightly soluble in water. | [BRN ]
2361602 | [NIST Chemistry Reference]
Carbonic acid 1,1-dimethylethyl ester(6627-89-0) |
Hazard Information | Back Directory | [Chemical Properties]
Clear light yellow liquid | [Uses]
tert-Butyl phenyl carbonate is used in determination of octanol-water partition coefficients by microemulsion electrokinetic chromatography. It is also used in the synthesis of 2-nitroindoles and as a reagent for mono-Boc protection of α,ω-diamines. | [Purification Methods]
If IR is free from OH, then purify it by redistillation; otherwise dissolve it in Et2O, wash it with 5% HCl, then H2O, dry it (MgSO4), evaporate and distil it through a Claisen head under vacuum. Care should be taken as distillation of large quantities can lead to decomposition with liberation of CO2 and isobutylene; use the necessary precautions. [Carpino J Am Chem Soc 79 98 1957, Beilstein 6 IV 629.] |
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