| Identification | Back Directory | [Name]
BORON DICHLORIDE-METHYL SULFIDE COMPLEX | [CAS]
63462-42-0 | [Synonyms]
Dichloroborane dimethyl sulfide
Dichloro(dimethyl sulfide)borane
DICHLOROBORANE-METHYL SULFIDE COMPLEX
Dichloro(dimethyl sulfide)(hydro)boron
BORON DICHLORIDE-METHYL SULFIDE COMPLEX
Dichloroborane methyl sulfide complex in excess methyl sulfide | [Molecular Formula]
C2H7BCl2S | [MDL Number]
MFCD00013209 | [MOL File]
63462-42-0.mol | [Molecular Weight]
144.86 |
| Hazard Information | Back Directory | [Uses]
Reactant for:
- Hydroboration reactions
- Pyrolysis reactions
- Addition reactions
- Preparation of unsymmetrical borafluorenes
- Cyclization reactions
- Dismutation followed by haloboration of azadiboriridine to give boron-nitrogen clusters
- Markovnikov hydroboration
| [reaction suitability]
reagent type: reductant | [Synthesis]
Dichloroborane methyl sulfide complex is synthesized by redistribution of Borane-Dimethyl Sulfide (BMS) and BCl3.SMe2. A mixture containing BHCl2.SMe2 (73%) and BMS, BH2Cl.SMe2, and BCl3.SMe2 is obtained by the reaction of BMS with Ph3CCl.
| [storage]
Dichloroborane methyl sulfide complex is corrosive, air- and moisture-sensitive, flammable liquid; stench. Reacts violently with water. Handle and store under nitrogen or argon. Stable indefinitely when stored under nitrogen at 25 °C. Destructive to upper respiratory tract, eyes, and skin. Handle in a fume hood.
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Sigma-Aldrich
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Energy Chemical
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SIGMA-RBI
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