6180-21-8

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6180-21-8 Structure

Identification	Back Directory
[Name] lithium chloroacetylide
[CAS] 6180-21-8
[Synonyms] lithium chloroacetylide
[Molecular Formula] C2ClLi
[MOL File] 6180-21-8.mol
[Molecular Weight] 66.41

Chemical Properties	Back Directory
[Boiling point ] 101°C

Hazard Information	Back Directory
[Uses] Lithium chloroacetylide is a nucleophilic organolithium reagent that reacts with a variety of electrophiles.
[Preparation] Lithium chloroacetylide is prepared in ether solution under anhyd conditions by treatment of cis- or trans-1,2- dichloroethylene with 2 equiv Methyllithium at 0 °C under N2.
[storage] Dry lithium chloroacetylide is explosive (as are the other metal haloacetylides), but may be safely handled and kept in the solution in which it is prepared under N2.

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