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ChemicalBook--->CAS DataBase List--->598-62-9

598-62-9

598-62-9 Structure

598-62-9 Structure
IdentificationMore
[Name]

Manganese carbonate
[CAS]

598-62-9
[Synonyms]

MANGANESE(+2)CARBONATE
MANGANESE CARBONATE
MANGANESE(II) CARBONATE
MANGANESE(II) CARBONATE N-HYDRATE
MANGANOUS CARBONATE
RHODOCHROSITE
Carbonicacid,manganese(2+)salt(1:1)
carbonicacid,manganese(2++)salt(1:1)
manganese(2+)carbonate(1:1)
manganesecarbonate(1:1)
manganesecarbonate(mnco3)
naturalrhodochrosite
mangane carbonate
MANGANESE(II) CARBONATE, 99.9+%
MANGANESE(II) CARBONATE, 99.99%
MANGANESE(II) CARBONATE TECHNICAL
MANGANESE(II) CARBONATE EXTRA PURE
MANGANESE CARBONATE 44+% MN TECH GARDE
MANGANESE CARBONATE, FOR ANALYTICAL PURPOSE
ManganeseCarbonateAr
[EINECS(EC#)]

209-942-9
[Molecular Formula]

CMnO3
[MDL Number]

MFCD00011116
[Molecular Weight]

114.95
[MOL File]

598-62-9.mol
Chemical PropertiesBack Directory
[Appearance]

Brown powder
[Melting point ]

350°C (dec.)
[density ]

3.12 g/mL at 25 °C(lit.)
[solubility ]

dilute aqueous acid: slightly soluble(lit.)
[form ]

Powder
[color ]

Light brown to violet
[Specific Gravity]

3.125
[Stability:]

Stable. Incompatible with strong acids, strong oxidizing agents. May be moisture senstive.
[Water Solubility ]

Soluble in water(0.065g/L), dilute inorganic acids. Insoluble alcohol.
[Merck ]

14,5726
[Solubility Product Constant (Ksp)]

pKsp: 10.63
[Exposure limits]

ACGIH: TWA 0.02 mg/m3; TWA 0.1 mg/m3
OSHA: Ceiling 5 mg/m3
NIOSH: IDLH 500 mg/m3; TWA 1 mg/m3; STEL 3 mg/m3
[LogP]

-0.809 (est)
[CAS DataBase Reference]

598-62-9(CAS DataBase Reference)
[EPA Substance Registry System]

598-62-9(EPA Substance)
Safety DataBack Directory
[Safety Statements ]

S22:Do not breathe dust .
S24/25:Avoid contact with skin and eyes .
[WGK Germany ]

3
[RTECS ]

OM2470000
[TSCA ]

Yes
[HS Code ]

2836991780
[Hazardous Substances Data]

598-62-9(Hazardous Substances Data)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Sulfuric acid-->Ammonia-->FUMING SULFURIC ACID-->Manganese dioxide-->Ammonium bicarbonate-->Hydrogen Sulfide-->Manganese(II) sulfate monohydrate-->Manganese-->Manganese sulfate-->MANGANESE (II) OXIDE
[Preparation Products]

Manganese dioxide-->Manganese-->Mancozeb-->Manganous dihydrogen phosphate-->Manganese nitrate-->LITHIUM MANGANESE OXIDE-->Electrolytic manganese bioxide-->Manganese chloride-->LITHIUM MANGANITE-->Manganese chloride tetrahydrate-->MANGANESE(II) HYPOPHOSPHITE MONOHYDRATE-->Dodecyl aldehyde-->Manganese(II) citrate
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Manganese carbonate(598-62-9).msds
Questions And AnswerBack Directory
[Description]

Manganese Carbonate is a water-insoluble manganese source which occurs naturally in the form of mineral rhodochrosite. It can easily be converted to other manganese compounds, such as the oxide by heating.
Manganese carbonate can be widely applied in various fields. In the field of agriculture, it is commonly used as an additive to plant fertilizers, which is effective to cure the crops with manganese deficiency. It can also be applied in ceramics as a porcelain glaze, glaze colorant and flux and it serves as a catalyst in viscose process. Besides, it has been proved to be used as a hematinic in the field of medicine. Other applications of manganese carbonate involve in health foods, chemical industry and etc.
[References]

https://en.wikipedia.org/wiki/Manganese(II)_carbonate
https://pubchem.ncbi.nlm.nih.gov/compound/11726#section=Use-and-Manufacturing
http://www.chemicalland21.com/industrialchem/inorganic/MANGANESE%20CARBONATE.htm
Hazard InformationBack Directory
[Chemical Properties]

Brown powder
[Application]

Manganese carbonate is extensively utilized as an additive to plant fertilizers to treat manganese deficient crops. It is also employed in health foods, in ceramics as a glaze colorant and flux, and in concrete stains. It is utilized in medicine as a hematinic (a nutrient required for the formation of blood cells in the process of haematopoiesis. The main hematinics are iron, B12, and folate).
[General Description]

Manganese(II) carbonate is a chemical compound that has a structure similar to calcite, with octahedral co-ordination symmetry. It is a carbonate that is insoluble in water and on treatment with acid it gives water soluble salts. It is a widely used material in plant fertilization as an additive that cures the magnesium deficiency in crops.
[Flammability and Explosibility]

Nonflammable
Questions and Answers (Q&A)Back Directory
[Uses]

Manganese(II) carbonate occurs in nature as the mineral rhodochrosite [14476-12-1] (manganese spar). This ore also is used to produce manganese dioxide (by electrolytic process). The pure compound is used as gemstones; and as a pigment (manganese white).
[Preparation]

Manganese(II) carbonate is mined from its naturally occurring mineral rhodochrosite. The compound may be prepared in the laboratory as a palepink precipitate by adding sodium bicarbonate to a solution of manganese(II) salt saturated with carbon dioxide. The product obtained is monohydrate, MnCO3•H2O. However, if the carbon dioxide-saturated solution, together with the above monohydrate precipitate, is heated in the absence of atmosphere oxygen, the monohydrate MnCO3•H2O is converted into the anhydrous MnCO3.
Spectrum DetailBack Directory
[Spectrum Detail]

Manganese carbonate(598-62-9)IR1
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

Manganese(II) carbonate, Puratronic, 99.985% (metals basis)(598-62-9)
[Sigma Aldrich]

598-62-9(sigmaaldrich)
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