| Identification | Back Directory | [Name]
ALLYL BENZOATE | [CAS]
583-04-0 | [Synonyms]
ALLYL BENZOATE
Allylbenzoate,97%
2-Propenyl benzoate
prop-2-enyl benzoate
BENZOIC ACID ALLYL ESTER
benzoicacid,2-propenylester | [EINECS(EC#)]
209-494-4 | [Molecular Formula]
C10H10O2 | [MDL Number]
MFCD00026104 | [MOL File]
583-04-0.mol | [Molecular Weight]
162.19 |
| Hazard Information | Back Directory | [Chemical Properties]
Colorless liquid. (Yellowish if made by old cross-esterification method). B.P. 230℃. Sp.Gr. 1.058. Insoluble in water.
| [Uses]
Allyl Benzoate is a versatile reactant used in the preparation of stable potassium alkyltrifluoroborates for Suzuki-Miyaura cross-coupling reactions with aryltriflates and arylhalides. | [Definition]
ChEBI:Allyl benzoate is a benzoate ester. | [Preparation]
Allyl benzoate is produced by direct esterification (azeotropic) of Allyl alcohol and Benzoic acid.
| [Synthesis Reference(s)]
The Journal of Organic Chemistry, 57, p. 2166, 1992 DOI: 10.1021/jo00033a048
Tetrahedron Letters, 29, p. 4513, 1988 DOI: 10.1016/S0040-4039(00)80534-1
Synthetic Communications, 5, p. 213, 1975 DOI: 10.1080/00397917508064112 | [Solubility in organics]
Allyl Benzoate is miscible with alcohol, perfume oils. Poorly soluble in Propylene glycol. |
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