| Identification | Back Directory | [Name]
TERT-BUTYL N-(2-THIENYL)CARBAMATE | [CAS]
56267-50-6 | [Synonyms]
AKOS 92405
NSC 263609
BUTTPARK 97\57-48
2-(N-Boc-amino)thiophene
TERT-BUTYL 2-THIENYLCARBAMATE
tert-Butyl thien-2-ylcarbamate
2-Aminothiophene, 2-BOC protected
tert-Butyl thiophen-2-ylcarbaMate
TERT-BUTYL N-(2-THIENYL)CARBAMATE
2-Aminothiophene, N-BOC protected
2-(N-tert-Butoxycarbonylamino)thiophene
tert-ButylN-(2-thienyl)carbamate≥ 96% (NMR)
THIOPHEN-2-YL-CARBAMIC ACID TERT-BUTYL ESTER
CarbaMic acid, N-2-thienyl-, 1,1-diMethylethyl ester
TERT-BUTYL N-(2-THIENYL)CARBAMATE ISO 9001：2015 REACH
tert-Butyl (thien-2-yl)carbamate, 2-[(tert-Butoxycarbonyl)amino]thiophene | [Molecular Formula]
C9H13NO2S | [MDL Number]
MFCD02677742 | [MOL File]
56267-50-6.mol | [Molecular Weight]
199.27 |
| Chemical Properties | Back Directory | [Melting point ]
151 °C | [Boiling point ]
238.1±13.0 °C(Predicted) | [density ]
1.186±0.06 g/cm3(Predicted) | [storage temp. ]
2-8°C(protect from light) | [pka]
13.63±0.70(Predicted) |
| Questions And Answer | Back Directory | [Structure]
Tert-butyl thiophen-2-ylcarbamate, C9H13NO2S, is a precursor in synthesising diimine ligands suitable for metal complex formation. This compound exhibits intramolecular methyl C7—H···O1 and C8—H···O1 interactions [2.938 (4) and 3.109 (4), respectively] in addition to bulky tert -butyl groups. These two features in tandem allow the packing in the crystal to be nearly perpendicular [the angle between adjacent thiophene rings = 74.83 (7)°]. An intermolecular N1—H···O1i hydrogen bond gives a one-dimensional chain which extends along [0 0 1].
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