| Identification | Back Directory | [Name]
Securinol A | [CAS]
5008-48-0 | [Synonyms]
Securinol
Securinol A
7H-5,10b-Ethano-2H-furo[2,3-a]quinolizin-2-one, 4,5,8,9,10,10a-hexahydro-12-hydroxy-, (5S,10aR,10bR,12R)- | [Molecular Formula]
C13H17NO3 | [MOL File]
5008-48-0.mol | [Molecular Weight]
235.28 |
| Hazard Information | Back Directory | [Description]
One of three closely related alkaloid isolated from Securinega suffructicosa, the base has [α]17D + 58.2° (c 0.14, CHC13) or + 50° (dioxan). It yields a crystalline picrate, m.p. l86-7°C (dec.), and a 3: 5-dinitrobenzoate, m.p. 198-9°C;[α]17D + 55.3° (c 0.10, CHC13). On hydrogenation with Pt02 in AcOH it gives the dihydro derivative, forming a hydrochloride, m.p. 241- 2°C. When treated with methylsulphonyl chloride in pyridine, the base furnishes viroallosecurinine, m.p. 133- 4°C; [α]D + 1200° (c 0.01, EtOH). | [References]
Horii et al., Chern. Pharrn. Bull., 13, 1307 (1965) |
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