| Identification | Back Directory | [Name]
METHYL ALPHA-BROMOACRYLATE 95 | [CAS]
4519-46-4 | [Synonyms]
methyl α-bromoacrylate
Methyl α-bromoacrylate
Methyl 2-bromoprop-2-enoate
Methyl alpha-bromoacrylate 95%
METHYL ALPHA-BROMOACRYLATE 95
2-Bromopropenoic acid methyl ester
2-Propenoic acid, 2-broMo-, Methyl ester | [EINECS(EC#)]
200-258-5 | [Molecular Formula]
C4H5BrO2 | [MDL Number]
MFCD08276754 | [MOL File]
4519-46-4.mol | [Molecular Weight]
164.986 |
| Chemical Properties | Back Directory | [Boiling point ]
70-75 °C48 mm Hg(lit.)
| [density ]
1.556 g/mL at 25 °C(lit.)
| [Fp ]
134 °F
| [storage temp. ]
?20°C | [InChIKey]
HVJXPDPGPORYKY-UHFFFAOYSA-N | [CAS DataBase Reference]
4519-46-4 |
| Hazard Information | Back Directory | [Uses]
Methyl α-bromoacrylate can undergo radical copolymerization with vinyl triacetoxysilane (VTAS) in the presence of azobisisobutyronitrile as the initiator. Dibromocyclopropanation of methyl α-bromoacrylate can yield methyl 1,1,2-tribromocyclopropanecarboxylate. It may be reduced with zinc dust and deuterium oxide to synthesize. Methyl acrylate-α-d with a high isotopic purity. These may undergo conjugate addition with methoxide, thiolates, oxime anions, hydrazones and EtZnCl to afford ester enolates. |
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Sigma-Aldrich
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