| Identification | Back Directory | [Name]
(S)-(-)-1,1'-BINAPHTHYL-2,2'-DIAMINE | [CAS]
4488-22-6 | [Synonyms]
BINAM
S(-)-DABN
R(+)-DABN
1,1-BINAPHY1-2,2'-DIAMINE
1,1'-Bi(2-naphthalenamine)
1,1'-Bi[2-naphthalenamine]
1,1'-Bi[naphthalene-2-amine]
1,1'-Bi(naphthalene-2-amine)
1,1'-BINAPHTHYL-2,2'-DIAMINE
(±)-1,1'-Bi(2-naphthylamine),
2,2-DIAMINO-1,1'-BINAPHTHALENE
1-(1-Naphtyl)naphthalen-2-amine
1,1'-Binaphthyl-2,2'-diamine 96%
(+/-)-2,2'-Diamino-1,1'-binaphthyl
(S)-(-)-2,2'-DIAMINO-1,1'-BINAPHTHYL
S(-)-1,1'-BINAPHTHALENE-2,2'-DIAMINE
R(+)-1,1'-BINAPHTHALENE-2,2'-DIAMINE
(R)-(+)-2,2'-DIAMINO-1,1'-BINAPHTHYL
RACEMIC-2,2'-DIAMINO-1,1'-BINAPHTHYL
(+/-)-1,1'-BINAPHTHALENE-2,2'-DIAMINE
(+/-)-2,2'-DIAMINO-1,1'-BINAPHTHALENE
(±)-2,2'-Diamino-1,1'-binaphthalene,98%
racemic-2,2'-Diamino-1,1'-binaphthyl,min.96%
RACEMIC-2,2'-DIAMINO-1,1'-BINAPHTHYL, MIN. 96% | [Molecular Formula]
C20H16N2 | [MDL Number]
MFCD00145204 | [MOL File]
4488-22-6.mol | [Molecular Weight]
284.35 |
| Chemical Properties | Back Directory | [Appearance]
off-white to beige-pink powder | [Melting point ]
242-244 °C(lit.)
| [Boiling point ]
416.85°C (rough estimate) | [density ]
1.249 | [refractive index ]
1.6450 (estimate) | [storage temp. ]
Keep in dark place,Sealed in dry,Room Temperature | [form ]
powder to crystal | [pka]
3.79±0.10(Predicted) | [color ]
slightly beige
| [Water Solubility ]
Insoluble in water | [λmax]
355nm(neat)(lit.) | [InChIKey]
DDAPSNKEOHDLKB-UHFFFAOYSA-N |
| Hazard Information | Back Directory | [Chemical Properties]
off-white to beige-pink powder | [Uses]
Novel axially chiral Rh N-heterocyclic carbene complexes were prepared from axially dissymmetric 1,1?-binaphthalenyl-2,2?-diamine and applied in the Rh-catalyzed enantioselective hydrosilylation of methyl ketones. The enantioselective direct aldol reaction, organocatalyzed by recoverable BINAM- prolinamide derivatives can be highly accelerated by a catalytic amount of a carboxylic acid without a detrimental of the obtained enantioselectivities. | [Safety Profile]
Questionable carcinogen withexperimental tumorigenic data. When heated todecomposition it emits toxic fumes of NOx. |
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