Identification | Back Directory | [Name]
(R)-(+)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS(DI(3,5-XYLYL)PHOSPHINO)-3,3'-BIPYRIDINE | [CAS]
442905-33-1 | [Synonyms]
(R)-Xyl-P-Phos (R)-XYLYL-P-PHOS (S)-XYLYL-P-PHOS CTH-(R)-XYLYL-P-PHOS CTH-(S)-XYLYL-P-PHOS min.cth-(r)-xylyl-p-phos (R)-(+)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS& (R)-(+)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS(DI(3,5-XYLYL)PHOSPHINO)-3,3'-BIPYRIDINE (S)-(-)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS(DI(3,5-XYLYL)PHOSPHINO)-3,3'-BIPYRIDINE (3R)-4,4'-Bis[bis(3,5-dimethylphenyl)phosphino]-2,2',6,6'-tetramethoxy-3,3'-bipyridine (R)-(+)-2,2',6,6'-Tetramethoxy-4,4'-bis(di(3,5-xylyl)phosphino)-3,3'-bipyridine,min.95%CTH-(R)-Xylyl-P-Phos (R)-(+)-2,2',6,6'-Tetramethoxy-4,4'-bis(di(3,5-xylyl)phosphino)-3,3'-bipyridine Application:Asymmetric hydrogenation Store N2Ar | [Molecular Formula]
C46H50N2O4P2 | [MDL Number]
MFCD04974235 | [MOL File]
442905-33-1.mol | [Molecular Weight]
756.85 |
Chemical Properties | Back Directory | [Appearance]
White solid | [Melting point ]
190-194°C | [form ]
Powder | [color ]
white to pale yellow | [Water Solubility ]
Sparingly soluble in water. |
Questions And Answer | Back Directory | [Reactions]
- Chiral ligand for ruthenium- catalyzed asymmetric hydrogenation of aromatic ketones.
- Chiral ligand for iridium-catalyzed asymmetric hydrogenation of quinolines.
- Chiral ligand for copper- catalyzed asymmetric hydrosilylation of ketones.
- Synthesis of new chiral 2-functionized-1,2,3,4-tetrahydroquinoline derivatives via asymmetric hydrogenation of substituted quinolines.
- Rhodium-biphosphine-catalyzed asymmetric, intermolecular hydroheteroarylation of α-substituted acrylate derivatives.
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