| Identification | Back Directory | [Name]
methyl 2-(chlorocarbonyl)benzoate | [CAS]
4397-55-1 | [Synonyms]
Methyl 2-chloroformylbenzoate
Methyl phthaloyl chloride 97%
o-Carbomethoxybenzoyl chloride
o-Methoxycarbonylbenzoyl chloride
2-METHOXYCARBONYLBENZOYL CHLORIDE
methyl 2-(chlorocarbonyl)benzoate
Phthalic acid monochloride monomethyl ester
phthalic monoacid monomethyl ester chloride
Benzoic acid, 2-(chlorocarbonyl)-, methyl ester | [Molecular Formula]
C9H7ClO3 | [MDL Number]
MFCD11656039 | [MOL File]
4397-55-1.mol | [Molecular Weight]
198.6 |
| Hazard Information | Back Directory | [Uses]
Methyl 2-(chlorocarbonyl)benzoate can be used for N-phthalylation of α-amino acids and preparation of isocoumarins. | [Preparation]
Heat o-methoxycarbonylbenzoic acid (methyl hydrogen phthalate) with Thionyl Chloride for 1 h on a steam bath (eq 1).
 | [storage]
Corrosive and moisture sensitive; reacts with protic solvents; use in a fume hood; do not breathe vapors and avoid contact with skin, eyes, and clothing; causes burns and irritation of the respiratory system; lachrymator; use immediately after preparation. |
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